Electronegativity and Chemical Bonds

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Questions and Answers

Which of the following best describes the trend of electronegativity on the periodic table?

  • Increases from right to left across a period and bottom to top in a group.
  • Increases from right to left across a period and top to bottom in a group.
  • Increases from left to right across a period and bottom to top in a group. (correct)
  • Increases from left to right across a period and top to bottom in a group.

If two atoms have an electronegativity difference of 1.0, what type of bond is most likely to form between them?

  • Metallic bond
  • Polar covalent bond (correct)
  • Nonpolar covalent bond
  • Ionic bond

Which element is considered the most electronegative?

  • Oxygen (O)
  • Fluorine (F) (correct)
  • Chlorine (Cl)
  • Sodium (Na)

What type of bond is formed when sodium (Na) completely transfers an electron to chlorine (Cl)?

<p>Ionic bond (B)</p> Signup and view all the answers

In a water molecule (H₂O), why is the bond between oxygen and hydrogen considered polar covalent?

<p>Oxygen is more electronegative than hydrogen. (C)</p> Signup and view all the answers

What is the primary purpose of a Lewis dot structure?

<p>To visualize how atoms bond and share electrons in a molecule. (C)</p> Signup and view all the answers

According to the octet rule, how many valence electrons do most atoms 'want' in their outer shell to be stable?

<p>8 (C)</p> Signup and view all the answers

What are 'lone pairs' in a Lewis dot structure?

<p>Unshared valence electrons on an atom. (D)</p> Signup and view all the answers

If the electronegativity difference between two bonded atoms is 0.2, what type of bond is most likely to form?

<p>Nonpolar covalent (B)</p> Signup and view all the answers

Which type of bond is characterized by electrostatic attraction between oppositely charged ions?

<p>Ionic bond (C)</p> Signup and view all the answers

How does the sharing of electrons differ between polar and nonpolar covalent bonds?

<p>In polar bonds, electrons are shared unequally; in nonpolar bonds, they are shared equally. (A)</p> Signup and view all the answers

Which of the following pairs of elements is most likely to form an ionic bond?

<p>Potassium (K) and Bromine (Br) (D)</p> Signup and view all the answers

Consider a molecule where one atom has a significantly higher electronegativity than the other. Which property is most likely to be observed in this molecule?

<p>It will have a dipole moment. (B)</p> Signup and view all the answers

Which force is primarily responsible for holding ions together in an ionic bond?

<p>Electrostatic force (A)</p> Signup and view all the answers

If an atom has 7 valence electrons, how many more electrons does it need to satisfy the octet rule?

<p>1 (D)</p> Signup and view all the answers

In a Lewis dot structure, what does a single line between two atoms represent?

<p>Two shared electrons (one bond) (A)</p> Signup and view all the answers

What is the electronegativity difference range generally associated with a polar covalent bond?

<p>0.5 - 1.7 (B)</p> Signup and view all the answers

Which of the following molecules is most likely to have nonpolar covalent bonds?

<p>H₂ (D)</p> Signup and view all the answers

If element X has a low electronegativity and element Y has a high electronegativity, what is the likely outcome when they bond?

<p>They will form an ionic bond, with element X transferring electrons to element Y. (C)</p> Signup and view all the answers

How many lone pairs are present on the oxygen atom in a water molecule (H₂O) according to its Lewis dot structure?

<p>2 (C)</p> Signup and view all the answers

Flashcards

Electronegativity

An atom's measure of its tendency to attract electrons in a chemical bond.

Electronegativity trends

Electronegativity increases from left to right across a period and from bottom to top in a group in the periodic table.

Most electronegative element

Fluorine (F) is the most electronegative element.

Ionic Bond

Formed through the complete transfer of electrons between atoms, typically between a metal and a nonmetal.

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Covalent Bond

Bonds created when atoms share electrons to achieve a stable electron configuration.

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Nonpolar Covalent Bond

A covalent bond where electrons are shared equally between atoms.

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Polar Covalent Bond

A covalent bond where electrons are unequally shared, creating a dipole moment.

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Lewis Dot Structure

Visual representations showing valence electrons as dots around atomic symbols.

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Octet Rule

The principle that atoms 'want' eight valence electrons to achieve stability.

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Study Notes

  • Electronegativity describes an atom's propensity to attract electrons within a chemical bond.
  • Elements increase in electronegativity from left to right across a period.
  • Elements increase in electronegativity from bottom to top within a group.
  • Fluorine (F) stands out as the most electronegative element.

Bond Types

  • Electronegativity differences define bond types.
  • Nonpolar covalent bonds occur when the electronegativity difference is between 0 and 0.4.
  • Polar covalent bonds form when the electronegativity difference is between 0.5 and 1.7.
  • Ionic bonds are likely to form when the electronegativity difference is greater than 1.7.

Ionic Bonds

  • Ionic bonds occur through the complete transfer of electrons from one atom to another.
  • These bonds typically form between a metal with low electronegativity and a nonmetal with high electronegativity.
  • For Example: Sodium (Na) gives an electron to chlorine (Cl) to form Na⁺ and Cl⁻.
  • Electrostatic attraction holds oppositely charged ions together.

Covalent Bonds

  • Covalent bonds arise when atoms share electrons.

Types of Covalent Bonds

  • Nonpolar covalent bonds arise from equal electron sharing due to similar or identical electronegativity.
  • Polar covalent bonds are caused by unequal electron sharing, where one atom attracts electrons more strongly.
  • For Example: In O-H, oxygen's higher electronegativity causes a polar covalent bond.

Lewis Dot Structure

  • Lewis dot structures represent valence electrons as dots surrounding chemical symbols.
  • They are used to illustrate bonding patterns in molecules.
  • Atoms "want" a full outer shell of electrons, often 8, satisfying the octet rule.
  • Shared electron pairs between atoms represent bonds.
  • Unshared electron pairs are represented as dots.
  • For Example: In H₂O, oxygen has 6 valence electrons, shares 2 with hydrogen atoms, and retains 2 lone pairs.

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