Electron Behavior and Covalent Bonds
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Questions and Answers

What is the term applied to any electron that has separated from the fixed lattice structure and has moved to the conduction band?

  • Free electron (correct)
  • Conduction electron
  • Intrinsic carrier
  • Valence electron

What is the term used to describe a semiconductor material that has been carefully refined to reduce the number of impurities to a very low level?

  • Refined semiconductor
  • Pure semiconductor
  • Extrinsic semiconductor
  • Intrinsic semiconductor (correct)

What is the main reason for the difference in the number of intrinsic carriers per cubic centimeter for Ge, Si, and GaAs?

  • Difference in atomic mass
  • Difference in crystal structure
  • Difference in external causes
  • Difference in refining techniques (correct)

What is the main effect of the higher relative mobility of free carriers in GaAs?

<p>Faster response times (D)</p> Signup and view all the answers

What is the relative mobility of free carriers in GaAs compared to Si?

<p>Five times higher (C)</p> Signup and view all the answers

What is the number of intrinsic carriers per cubic centimeter in Si at room temperature?

<p>1.5×10^10 (A)</p> Signup and view all the answers

What is the external cause that can break the covalent bond and free the valence electrons?

<p>Both thermal and light energy (C)</p> Signup and view all the answers

What is the term used to describe the free electrons in a material due only to external causes?

<p>Intrinsic carriers (C)</p> Signup and view all the answers

What is the process of adding impurities to the intrinsic semiconductor material called?

<p>Doping (C)</p> Signup and view all the answers

What is the type of material created by introducing impurity elements having five valence electrons?

<p>n-type material (C)</p> Signup and view all the answers

What is the term used to describe the impurities with five valence electrons in n-type material?

<p>Donor atoms (D)</p> Signup and view all the answers

What is the process by which a valence electron acquires sufficient kinetic energy to break its covalent bond and fills the void created by a hole?

<p>Ionization (A)</p> Signup and view all the answers

In an n-type material, what is the majority carrier?

<p>Electron (D)</p> Signup and view all the answers

What is the term used to describe the impurities with three valence electrons in p-type material?

<p>Acceptor atoms (C)</p> Signup and view all the answers

What is the mobility of GaAs in cm²/V-s?

<p>8500 (A)</p> Signup and view all the answers

In a p-type material, what is the majority carrier?

<p>Hole (C)</p> Signup and view all the answers

Study Notes

Covalent Bonds and Free Electrons

  • Covalent bonds can be broken when valence electrons absorb sufficient kinetic energy from external natural causes.
  • Free electrons are electrons that have separated from the fixed lattice structure and moved to the conduction band.
  • Free electrons are sensitive to applied electric fields and potential differences.

Intrinsic Semiconductors

  • Intrinsic semiconductors are materials refined to reduce impurities to a very low level.
  • Intrinsic carriers are free electrons in a material due only to external causes.
  • Intrinsic carriers per cubic centimeter:
  • Ge: 2.5×10¹³
  • Si: 1.5×10¹⁰
  • GaAs: 1.7×10⁶

Relative Mobility of Free Carriers

  • The relative mobility of free carriers in a material is their ability to move throughout the material.
  • Free carriers in GaAs have more than five times the mobility of those in Si.
  • This results in response times of GaAs electronic devices being up to five times faster than those of Si devices.

Extrinsic Semiconductors

  • Extrinsic semiconductors are materials subjected to the doping process.
  • Doping involves adding impurities to intrinsic semiconductor materials.
  • Doping can significantly alter the characteristics of a semiconductor material.

n-type and p-type Materials

  • n-type materials are created by introducing impurity elements with five valence electrons (e.g., Antimony, Arsenic, Phosphorus).
  • Donor atoms introduce an additional fifth valence electron, which is easily freed for conduction.
  • p-type materials are created by introducing impurity elements with three valence electrons (e.g., Boron, Gallium, Indium).
  • Acceptor atoms create an incomplete bond pair, resulting in a vacancy for an electron (hole).

Electron-Hole Transfer

  • When a valence electron acquires sufficient kinetic energy to break its covalent bond, a hole is created in the covalent bond.
  • The hole can then be filled by another electron, resulting in a transfer of holes to the left and electrons to the right.

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Learn about the behavior of valence electrons in covalent bonds, how they can be freed from the lattice structure, and their sensitivity to electric fields.

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