Electrochemistry: Electrode Potential and Reference Electrodes
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Questions and Answers

What is the primary function of the B-Reference electrode in a pH meter?

  • To amplify the electrical charge
  • To adjust the pH meter before taking the reading
  • To complete the electrical circuit (correct)
  • To control the temperature
  • What would happen if the electrodes are not cleaned?

  • The pH meter would break down
  • The pH meter would not be affected
  • The pH meter would be more accurate
  • The pH meter would be less accurate (correct)
  • What is the purpose of the Temperature knob in a pH meter?

  • To control the temperature (correct)
  • To amplify the electrical charge
  • To complete the electrical circuit
  • To adjust the pH meter before taking the reading
  • In which industry is the pH meter particularly used for dairy products?

    <p>Food</p> Signup and view all the answers

    Why is it essential to keep the probes moist when not in use?

    <p>To prevent them from getting dry</p> Signup and view all the answers

    What is an advantage of pH meters?

    <p>pH Calibration is low-priced and robust</p> Signup and view all the answers

    What is a disadvantage of pH meters?

    <p>Heat affects the output readings</p> Signup and view all the answers

    What is necessary for the accuracy and precision of the pH meter?

    <p>To clean lines of the probes</p> Signup and view all the answers

    What is the primary function of a pH meter?

    <p>To determine the acidity or alkalinity of a solution</p> Signup and view all the answers

    What is the symbol 'P' in pH derived from?

    <p>The mathematical symbol for negative logarithm</p> Signup and view all the answers

    What is the pH value of a solution with equal concentrations of hydrogen and hydroxyl ions?

    <p>Exactly 7</p> Signup and view all the answers

    What is the purpose of the silver wire coated with silver chloride in a glass electrode?

    <p>To carry current through the half-cell reaction</p> Signup and view all the answers

    What type of pH meter is ideal for laboratory use?

    <p>Desktop pH meter</p> Signup and view all the answers

    What is the typical measurement range of a pen pH meter?

    <p>A conventional range for easy and handy equipment</p> Signup and view all the answers

    What is the result of a pH meter measurement displayed in terms of?

    <p>The pH value of the solution</p> Signup and view all the answers

    What is the pH scale range?

    <p>0 to 14</p> Signup and view all the answers

    Study Notes

    pH Meter

    • The electrode potential is constant due to the constant chloride ion concentration (0.1 M).

    Reference Electrode (Calomel Electrode)

    • It is used to complete the electrical circuit.
    • A common reference electrode is another Ag/AgCl electrode.
    • The Ag/AgCl electrode is immersed in a 0.1 M KCl solution, making contact with the test solution through a porous fiber.

    Components of pH Meter

    • Electrode holder
    • Amplifier: amplifies the electrical charge from the electrode and passes it to the galvanometer as readable current.
    • Galvanometer or Digital display
    • Temperature knob: controls the temperature.
    • Adjustment knob: adjusts the pH meter before taking readings.

    Advantages of pH Meter

    • pH calibration is low-priced and robust.
    • Pocket size pH meters are user-friendly.
    • Accounts are reliable and specific.
    • Readings are accurate and precise.

    Disadvantages of pH Meter

    • Heat affects the output readings.
    • pH calibration using glass electrodes requires cleaning to prevent deposition influencing the readings.

    Application of pH Meter

    • In agriculture industries, it measures the pH of soil.
    • In municipal water supplies, it measures water quality.
    • In chemical and pharmaceutical industries, it measures the pH value of solutions.
    • In the food industry, it is used for dairy products like cheese, curds, and yogurts.

    Maintenance of pH Meter

    • Cleaning lines of the probes is essential for accuracy and precision.
    • Probes are kept moist when not in use with a medium.
    • Electrodes should not be allowed to become dry.
    • Regular calibration of pH meter is essential.

    pH Scale

    • pH is a symbol that describes the degree of acidity or alkalinity.
    • It is measured on a scale of 0 to 14.
    • pH is derived from the negative logarithm (P) and the chemical symbol for Hydrogen (H).

    pH Value

    • It is directly related to the ratio of hydrogen ion (H+) and hydroxyl ion (OH-) concentrations.
    • If H+ concentration is higher than OH- concentration, the material is acidic (pH < 7).
    • If OH- concentration is higher than H+ concentration, the material is basic (pH > 7).
    • If H+ concentration is equal to OH- concentration, the material is neutral (pH = 7).

    Types of pH Meter

    • Portable pH meter: covers an extensive range of regularly employed instruments.
    • Desktop pH meter: ideal for laboratory use.
    • Pen pH meter: composed of a single scale, conventional measurement range for easy and handy equipment.

    Electrode

    • There are two types of electrodes: glass electrode (measuring electrode) and Ag/AgCl electrode.
    • The Ag/AgCl electrode carries current through the half-cell reaction.

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    Description

    This quiz covers the concept of electrode potential in electrochemistry, specifically with regards to the Ag/AgCl electrode and its use as a reference electrode in a KCl solution.

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