Electrochemistry Basics Quiz
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Questions and Answers

What does the electrochemical series indicate about elements at the top of the list?

  • They lose electrons more easily. (correct)
  • They cannot conduct electricity.
  • They are all metals.
  • They are less reactive than those lower down.

Why is it necessary for lead bromide to be in a molten state during electrolysis?

  • To increase the boiling point of the solution.
  • To allow for the preservation of gas emissions.
  • So that the ions are free to move. (correct)
  • To prevent the electrodes from corroding.

Which of the following materials is a suitable electrode for the electrolysis of lead bromide?

  • Platinum (correct)
  • Copper
  • Iron
  • Graphite

What is the balanced half equation for the reduction reaction occurring at the cathode during the electrolysis of molten lead bromide?

<p>Pb^2+ + 2e^- → Pb (B)</p> Signup and view all the answers

Which metal, besides lead, can be extracted from its compound through electrolysis, and what is the compound?

<p>Sodium from sodium chloride (D)</p> Signup and view all the answers

What is the primary purpose of electrolysis in the context of copper purification?

<p>To separate impure copper from pure copper (D)</p> Signup and view all the answers

How does an electrolyte facilitate electrochemical reactions?

<p>By conducting an electric current when melted or dissolved (C)</p> Signup and view all the answers

Which of the following statements about electrodes is true?

<p>Carbon or platinum are typically used for inert electrodes. (C)</p> Signup and view all the answers

What role does the impure copper play in the electrolysis process for copper purification?

<p>It acts as the positive electrode. (C)</p> Signup and view all the answers

Which metal is commonly used as the positive electrode during the electroplating process of silver?

<p>Silver (C)</p> Signup and view all the answers

What is a key benefit of electroplating an object?

<p>To protect against corrosion and improve appearance (B)</p> Signup and view all the answers

Which of the following is NOT a characteristic of electrolysis?

<p>Occurs only in solid state compounds (D)</p> Signup and view all the answers

During electroplating, what happens at the negative electrode?

<p>Metal ions are deposited onto the object. (C)</p> Signup and view all the answers

Flashcards

Electrolysis

Using electricity to cause a chemical reaction in an electrolyte.

Electrolyte

A substance that conducts electricity when molten or dissolved in water.

Electrode (inert)

An electrode that doesn't react with the electrolyte.

Electrode (active)

An electrode that reacts with the electrolyte.

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Copper purification

Using electrolysis to refine copper.

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Electroplating

Applying a thin layer of metal to another using electrolysis.

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Electroplating purpose

To improve appearance or prevent corrosion of a metal.

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Electroplating example

A process of coating a metal object, like a spoon, with silver or other metals.

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Electrochemical Series

A list of elements ordered by standard electrode potentials.

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Molten Lead Bromide

Lead bromide in liquid form, allowing ions to move.

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Electrode Material (Electrolysis)

A material used in an electrolytic cell to conduct electricity.

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Electrolysis Extraction (Example)

Extracting a metal by using electrolysis.

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Study Notes

Electrochemistry

  • Electrochemistry is the use of an electric current to bring about chemical reactions, and the use of chemical reactions to produce an electric current.

Electrolysis

  • Definition: Electrolysis is the use of electricity to bring about a chemical reaction in an electrolyte. A chemical reaction is produced when an electric current is passed through an electrolyte.
  • Definition: An electrolyte is a compound which when molten or dissolved in water will conduct an electric current.

Electrodes

  • Two electrodes are used to make contact with the electrolyte.
  • Electrodes are usually made of carbon or platinum since they are unreactive and do not react with the electrolyte.
  • Some electrodes do not react with the electrolyte, these are called inert electrodes.
  • Some electrodes react with the electrolyte, these are called active electrodes.

Purification of Copper

  • The electrolysis of copper sulfate solution using copper electrodes is used to purify copper for the electronics industry.
  • The impure copper is used as the positive electrode.
  • A thin sheet of very pure copper is used as the negative electrode.
  • As a current is passed through the cell, pure copper is plated onto the negative electrode.
  • The impurities fall to the bottom of the cell.

Electroplating

  • Definition: Electroplating is a process where electrolysis is used to put a layer of one metal on the surface of another.

Electrochemical Series

  • Definition: The electrochemical series is a list of elements in order of their standard electrode potentials.
  • Elements at the top of the list lose electrons more easily than elements further down. Elements at the top are more reactive than elements further down.
    • The table shows the most electropositive to least electropositive elements.

Exam Questions (2013 HL Section B Question 11)

  • Electrolysis: Electrolysis is a chemical reaction that occurs when electricity passes through an electrolyte.

  • Molten Lead Bromide: Lead bromide must be molten so that the ions are free to move.

  • Electrode Material: A suitable material for electrodes is platinum.

  • Balanced Half-equations (during electrolysis):

    • Pb2+ + 2e- → Pb
    • 2Br- → Br2 + 2e-
  • Metal Extracted by Electrolysis (other than lead): Sodium.

  • Compound Electrolysed to Produce Sodium: Sodium chloride.

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Test your understanding of electrochemistry concepts, including electrolysis, electrodes, and the purification of copper. This quiz covers the fundamental principles and applications of electrochemical reactions. Challenge yourself and see how well you know this exciting field!

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