Electrochemistry

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Questions and Answers

What is the characteristic of metals with standard reduction potential values near about – 2.0 volt or more?

  • They have high positive reduction potentials
  • They are poor reducing agents
  • They are strongly electropositive (correct)
  • They are highly electronegative

What happens to the tendency of metals to liberate hydrogen gas from dilute acids as you descend in the electrochemical series?

  • It becomes constant
  • It remains the same
  • It decreases (correct)
  • It increases

Which of the following metals can liberate hydrogen from water?

  • Iron and the metals above it (correct)
  • Copper and metals above it
  • Iron and metals below it
  • Mercury and metals below it

What is the direction of the oxidation reaction in the equation Mn → Mn⁺⁺ + ne⁻?

<p>Left to right (D)</p> Signup and view all the answers

What is the relationship between the reduction potential of a metal and its ability to displace hydrogen from dilute acids?

<p>Metals with high negative reduction potentials can displace hydrogen (B)</p> Signup and view all the answers

What happens to the thermal stability of the oxide of a metal as you descend in the electrochemical series?

<p>It decreases (C)</p> Signup and view all the answers

What is the tendency of non-metals with high positive values of standard reduction potentials?

<p>To accept electrons readily (D)</p> Signup and view all the answers

Which of the following metals is a strong reducing agent?

<p>Al (D)</p> Signup and view all the answers

What is the direction of the electrochemical series?

<p>From top to bottom, increasing tendency to lose electrons (A)</p> Signup and view all the answers

What is the relationship between standard free energy change and cell potential?

<p>ΔG = -nF × Ecell (D)</p> Signup and view all the answers

Which of the following metals has a moderate electropositive character?

<p>Al (B)</p> Signup and view all the answers

What is the oxidation reaction in the electrochemical series?

<p>M → M+ + e- (C)</p> Signup and view all the answers

Which of the following metals has a more negative reduction potential?

<p>Sodium (B)</p> Signup and view all the answers

What is the principle behind the extraction of metals like Ag and Au from their salt solutions?

<p>More electropositive metals can displace less electropositive metals (C)</p> Signup and view all the answers

Which of the following metals is NOT an alkali or alkaline earth metal?

<p>Zinc (A)</p> Signup and view all the answers

What happens when metals below copper in the electrochemical series are heated?

<p>They form unstable oxides that decompose on heating (B)</p> Signup and view all the answers

Which of the following is a stronger reducing agent?

<p>Sodium (C)</p> Signup and view all the answers

What is the relationship between the reduction potential of a metal and its reducing power?

<p>More negative reduction potential means stronger reducing power (C)</p> Signup and view all the answers

What is the relationship between the electrochemical equivalent (Z) of an element and its equivalent weight (E)?

<p>E is directly proportional to Z (D)</p> Signup and view all the answers

What is the Faraday constant (F) equivalent to?

<p>Charge on an electron × Avogadro's number (C)</p> Signup and view all the answers

How many moles of electrons are required to liberate one mole of monovalent cation?

<p>One mole of electrons (C)</p> Signup and view all the answers

What is the unit of Faraday constant (F)?

<p>Coulomb per mole (C)</p> Signup and view all the answers

What is the number of Faraday equivalent to?

<p>Number of electrons passed (D)</p> Signup and view all the answers

What type of conductors are copper, silver, and tin?

<p>Metallic conductors (D)</p> Signup and view all the answers

What is the relationship between the mass of a substance deposited or liberated at an electrode and the quantity of electricity passed?

<p>They are directly proportional (C)</p> Signup and view all the answers

What is the charge carried by one mole of electrons?

<p>96,500 Coulombs (C)</p> Signup and view all the answers

What is the electrochemical equivalent (ECE) of an ion?

<p>A constant that depends on the ion (D)</p> Signup and view all the answers

What is the relationship between the amount of electricity involved in a reaction and the number of moles of electrons involved?

<p>Q = nF (B)</p> Signup and view all the answers

What is the quantity of electricity involved in a reaction when one mole of electrons is involved?

<p>96,500 Coulombs (D)</p> Signup and view all the answers

What is the unit of electrochemical equivalent (ECE)?

<p>Grams per Coulomb (C)</p> Signup and view all the answers

What is the unit of electrochemical equivalent?

<p>gram per coulomb (D)</p> Signup and view all the answers

What is the number of electrons in 1 mole of electrons?

<p>6.023 × 10^23 (C)</p> Signup and view all the answers

What is the value of Faraday's constant in Coulombs?

<p>96500 (C)</p> Signup and view all the answers

What is the charge of one electron in Coulombs?

<p>1.6 × 10^-19 (C)</p> Signup and view all the answers

What is the relationship between the amount of substance and the quantity of electricity passed in Faraday's law of electrolysis?

<p>The amount of substance is directly proportional to the quantity of electricity passed (A)</p> Signup and view all the answers

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