Electrochemical Equilibria Quiz

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Questions and Answers

What is the overall cell reaction for the given cell?

  • 2Ag+ + Fe → Fe2+ + 2Ag
  • Fe + 2Ag+ → Fe2+ + 2Ag (correct)
  • Fe2+ + Ag → Fe + 2Ag+
  • Fe2+ + 2Ag → Fe + 2Ag+

What is the value of E0cell for the given cell?

  • 0.80V
  • 0.36V
  • 0.44V
  • 1.24V (correct)

What is the potential of the concentration cell Pt/H2 (8atm)/HCl(0.3M)/H2(2atm)/Pt at 250C?

  • 0.36V
  • 0.0591V
  • 1.24V
  • 0.01779V (correct)

What is the anode in the concentration cell Pt/H2 (8atm)/HCl(0.3M)/H2(2atm)/Pt?

<p>H2 (8atm) (A)</p> Signup and view all the answers

What is the cathode in the given cell with the overall reaction Fe + 2Ag+ → Fe2+ + 2Ag?

<p>2Ag (D)</p> Signup and view all the answers

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Study Notes

Cell Reaction and Electrode Identification

  • The overall cell reaction for the given cell is: Fe + 2Ag+ → Fe2+ + 2Ag
  • The anode in the concentration cell Pt/H2 (8atm)/HCl(0.3M)/H2(2atm)/Pt is the electrode with 8atm H2
  • The cathode in the given cell with the overall reaction Fe + 2Ag+ → Fe2+ + 2Ag is where the reduction reaction occurs: 2Ag+ → 2Ag

Cell Potential and Concentration

  • The value of E0cell for the given cell is not specified, but it can be calculated using the standard electrode potentials of the involved half-reactions
  • The potential of the concentration cell Pt/H2 (8atm)/HCl(0.3M)/H2(2atm)/Pt at 250C can be calculated using the Nernst equation, considering the concentration gradient of H2 and H+ ions

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