Electrochemical Cells Quiz

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Questions and Answers

Define what an electrochemical cell is?

A device that converts chemical energy into electrical energy and vice versa. It consists of two electrodes immersed in one or more suitable electrolytes.

What is the function of the anode in an electrochemical cell?

  • At which oxidation occurs (correct)
  • Acts as a medium for ion flow
  • Prevents liquid-to-liquid junction potential
  • At which reduction occurs

What is the role of electrolytes in an electrochemical cell?

Electrolytes are the medium that facilitates the flow of ions between electrodes.

Oxidation and reduction reactions in electrochemical cells occur in separate containers.

<p>True (A)</p> Signup and view all the answers

Which type of electrochemical cell produces electricity as a result of chemical reactions?

<p>Galvanic Cell (A)</p> Signup and view all the answers

Which type of electrochemical cell uses electrical energy to drive chemical reactions?

<p>Electrolytic Cell (D)</p> Signup and view all the answers

Which of the following is NOT a function of a salt bridge in an electrochemical cell?

<p>Provides a pathway for electron flow (B)</p> Signup and view all the answers

What is the standard notation for representing an Electrochemical Cell?

<p>Zn(s) / Zn²⁺(1M) // Cu²⁺(1M) / Cu(s)</p> Signup and view all the answers

The electrode potential of a cell ONLY depends upon the nature of metal and its ions.

<p>False (B)</p> Signup and view all the answers

What is the formula for EMF or cell potential of a cell?

<p>Ecell = Ecathode - Eanode</p> Signup and view all the answers

Electrochemical Series arranges elements in increasing order of oxidation potential values.

<p>False (B)</p> Signup and view all the answers

Which of the following is NOT an application of the Electrochemical Series?

<p>Determining the density of a substance (C)</p> Signup and view all the answers

What is the Nernst Equation and what does it represent?

<p>The Nernst equation relates the electrode potential of a cell to the standard electrode potential, temperature, and concentration of ions in the electrolytic solution.</p> Signup and view all the answers

What is the formula for the Nernst Equation?

<p>E = E° - (0.0591/n)log[Product]/[Reactant]</p> Signup and view all the answers

Which of the following is NOT a factor considered in determining the standard electrode potential?

<p>Density of the solution (B)</p> Signup and view all the answers

What is the Nernst Equation used for in the context of electrochemical cells?

<p>All of the above (D)</p> Signup and view all the answers

Flashcards

Electrochemical Cell

A device that converts chemical energy into electrical energy and vice versa. It typically consists of two electrodes immersed in an electrolyte.

Anode

The electrode where oxidation occurs. It is the negative terminal in a galvanic cell.

Cathode

The electrode where reduction occurs. It is the positive terminal in a galvanic cell.

Electrolyte

A medium that facilitates the flow of ions between electrodes in an electrochemical cell.

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Galvanic Cell

An electrochemical cell that produces electricity as a result of a spontaneous chemical reaction inside the cell, like a battery.

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Electrolytic Cell

An electrochemical cell where electrical energy drives a non-spontaneous chemical reaction. It uses electricity to make a chemical change.

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Daniel Cell

A simple galvanic cell consisting of a zinc electrode in a solution of zinc sulfate and a copper electrode in a solution of copper sulfate.

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Oxidation

The process where electrons are lost, resulting in an increase in oxidation state. It occurs at the anode in a galvanic cell.

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Reduction

The process where electrons are gained, resulting in a decrease in oxidation state. It occurs at the cathode in a galvanic cell.

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Oxidation Half Cell

The half of an electrochemical cell where oxidation occurs.

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Reduction Half Cell

The half of an electrochemical cell where reduction occurs.

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Electron Flow in a Galvanic Cell

The flow of electrons from the anode (negative terminal) to the cathode (positive terminal) in a galvanic cell.

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Salt Bridge

A device that connects the two half-cells of a galvanic cell, allowing the flow of ions without mixing the solutions. It maintains electrical neutrality and prevents liquid junction potential.

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Representation of an Electrochemical Cell

A shorthand representation of an electrochemical cell, where the anode is on the left and the cathode on the right. The metal, electrolyte, and salt bridge are represented by specific symbols.

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Electrode Potential

The potential difference that exists between an electrode and its electrolyte solution. It depends on the nature of the metal, concentration of ions, and temperature.

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EMF or Cell Potential

The potential difference between the two electrodes in an electrochemical cell. It is expressed in volts and represents the maximum electrical work the cell can do.

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Electrochemical Series

A table that lists elements in order of increasing reduction potential values. It helps predict the relative strength of oxidizing and reducing agents, reactivity, and feasibility of redox reactions.

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Standard Electrode Potential

The standard electrode potential of an electrode when the concentration of the electrolyte is 1 M, the temperature is 298 K, and the pressure of gaseous components is 1 atm.

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Nernst Equation

An equation that relates the electrode potential of a half-cell to the standard electrode potential, temperature, and concentrations of reactants and products.

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Equilibrium Constant

The equilibrium constant for a reaction, which can be calculated using the Nernst equation and the standard cell potential.

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Equilibrium

The condition where the chemical potential of all reactants and products in a reaction are equal, leading to no net change in concentration.

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Reaction Quotient

The reaction quotient, which is similar to the equilibrium constant, but it measures the relative amounts of reactants and products at any point during a reaction.

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Gibbs Free Energy Change

A measure of the spontaneity or feasibility of a reaction. A positive value indicates a spontaneous reaction, while a negative value indicates a non-spontaneous reaction.

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Cell Potential at Equilibrium

The potential difference between two half-cells when the cell is at equilibrium. It is zero for any reversible cell at equilibrium.

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pH

A measure of the acidity or alkalinity of a solution. It is defined as the negative logarithm of the hydrogen ion concentration.

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Electric Current

A process that involves the movement of charged particles through a conductor due to a difference in electrical potential. It is the flow of electrical charge.

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Electrical Conductivity

The ability of a substance to conduct electricity. It depends on the concentration of charge carriers and their mobility.

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Redox Reaction

A chemical reaction that involves the transfer of electrons between reactants.

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Oxidizing Agent

A substance that loses electrons in a redox reaction, causing the oxidation of another substance.

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Reducing Agent

A substance that gains electrons in a redox reaction, causing the reduction of another substance.

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Reduction Potential

The tendency of a species to gain electrons and undergo reduction. It is measured in volts and can be used to predict the feasibility of redox reactions.

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Study Notes

Electrochemical Cells

  • Electrochemical cells convert chemical energy into electrical energy, and vice versa.
  • A cell consists of two electrodes immersed in one or more electrolytes.

Electrodes and Electrolytes

  • Anode: The electrode where oxidation occurs.
  • Cathode: The electrode where reduction occurs.
  • Electrolytes: A medium that facilitates the flow of ions between electrodes.

Oxidation and Reduction Reactions

  • Oxidation and reduction reactions happen in separate containers not in direct contact.

Galvanic vs. Electrolytic Cells

  • Galvanic Cell: Produces electricity from spontaneous chemical reactions inside the cell.
  • Electrolytic Cell: Electrical energy drives a chemical reaction (non-spontaneous)

A Simple Galvanic Cell (Daniel Cell)

  • Contains a 1.0 M zinc sulfate solution and a 1.0 M copper sulfate solution.
  • A zinc rod is dipped in the zinc sulfate solution and a copper rod in the copper sulfate solution.

Reactions at the Anode

  • Oxidation occurs at the anode (negative terminal).
  • The half-cell where oxidation occurs is known as the oxidation half-cell.

Reactions at the Cathode

  • Reduction occurs at the cathode (positive terminal).
  • The half-cell where reduction happens is called the reduction half-cell.

Electron Flow in a Galvanic Cell

  • Electrons flow from the negative terminal (anode) to the positive terminal (cathode).
  • The flow of electrical current is opposite to the flow of electrons.

Functions of Salt Bridge

  • Completes the circuit, allowing ions to move between the two half-cells.
  • Prevents the mixing of solutions from both half-cells.
  • Prevents liquid-junction potential (which is harmful for the cell).

Representation of an Electrochemical Cell

  • The anode is written on the left, and the cathode on the right.
  • The order is metal/cation//cation/metal (or solid phase then electrolyte).
  • A vertical line (/) or semicolon (;) separates the metal from the cation.
  • A double line (//) represents the salt bridge.

Electrode Potential and EMF of a Galvanic Cell

  • Electrode potential depends on the nature of the metal, the concentration of ions, and temperature.
  • EMF (electromotive force) is the difference in electrode potentials between the two electrodes in a cell. It is measured in volts (V). Ecell = Ecathode − Eanode

Electrochemical Series

  • An arrangement of elements based on their increasing reduction potential values.
  • Also known as the activity series.
  • Helpful in predicting spontaneity of a reaction and predicting if a metal will react with acids to produce H₂ gas.

Example Calculations and Predictions

  • Examples demonstrate calculating standard EMF of a cell, predicting if reactions are feasible based on electrochemical series, and various applications.

Nernst Equation

  • The Nernst equation relates the electrode potential to the concentration of reactants and products and temperature. It accounts for non-standard conditions.
  • The equation is: E = E° - (0.0591/n) log[Products]/[Reactants].

Application of Nernst Equation

  • Used to calculate cell potentials under non-standard conditions.

Calculation of Cell Potential

  • Examples show calculating cell potentials for specific electrochemical cells.

Calculation of Equilibrium Constant

  • The equilibrium constant is calculated using the cell potential.
  • The equation is K = 10^(nE°/0.0591).

Concentration Determination

  • The concentration of one ionic species can be determined if the concentration of the other is known using the Nernst equation.

pH Determination

  • The Nernst equation can be used to calculate pH of a solution given the relevant electrochemical cell measurements.

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