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Questions and Answers
What is the primary function of an electrochemical cell?
What is the primary function of an electrochemical cell?
What type of electrochemical cell requires a source of electricity to drive a chemical reaction?
What type of electrochemical cell requires a source of electricity to drive a chemical reaction?
What is the purpose of the salt bridge in an electrochemical cell?
What is the purpose of the salt bridge in an electrochemical cell?
What is a characteristic of metals used as electrodes in an electrochemical cell?
What is a characteristic of metals used as electrodes in an electrochemical cell?
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What is the name of an electrochemical cell that generates electricity from a spontaneous redox reaction?
What is the name of an electrochemical cell that generates electricity from a spontaneous redox reaction?
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What is the function of the anode and cathode in an electrochemical cell?
What is the function of the anode and cathode in an electrochemical cell?
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What is the purpose of the electrolyte solution in an electrochemical cell?
What is the purpose of the electrolyte solution in an electrochemical cell?
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What is the direction of electron flow in an electrochemical cell?
What is the direction of electron flow in an electrochemical cell?
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What is the reaction that occurs at the anode in an electrochemical cell?
What is the reaction that occurs at the anode in an electrochemical cell?
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What is the purpose of the salt bridge in an electrochemical cell?
What is the purpose of the salt bridge in an electrochemical cell?
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What is the electrochemical potential of a cell a measure of?
What is the electrochemical potential of a cell a measure of?
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How do you determine the electrochemical potential of a cell?
How do you determine the electrochemical potential of a cell?
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What is the anode in a Galvanic cell?
What is the anode in a Galvanic cell?
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What is the reaction that occurs at the cathode in an electrochemical cell?
What is the reaction that occurs at the cathode in an electrochemical cell?
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What is the significance of the double line in cell notation?
What is the significance of the double line in cell notation?
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Study Notes
Electrochemical Cells
- An electrochemical cell is a device that generates electricity from a chemical reaction or uses electrical energy to drive a chemical reaction.
- Electrochemical cells can be classified into two types: voltaic (Galvanic) cells, which generate electricity from a spontaneous redox reaction, and electrolytic cells, which require a source of electricity to drive a chemical reaction.
Components of an Electrochemical Cell
- The main components of an electrochemical cell are the anode, the cathode, and the electrolyte.
- The anode and cathode are separated into two half-cells and connected by a metal wire.
- A salt bridge allows ions to flow between the two half-cells to complete the electrical circuit.
- The electrolyte solution provides ions or charged particles for the chemical reaction.
Anode and Cathode
- The anode and cathode are electrodes, typically made of metal conductors like Zinc and Iron.
- In a voltaic cell, the anode is negative and the cathode is positive, while in an electrolytic cell, the anode is positive and the cathode is negative.
- The anode is the site of oxidation, where electrons are lost, and the cathode is the site of reduction, where electrons are gained.
Half-Cell Reactions
- The reaction at the anode is an oxidation reaction, represented by the equation: Ox + ne- → Red
- The reaction at the cathode is a reduction reaction, represented by the equation: Ox + ne- → Red
- Using Zinc as the anode, the anode reaction is: Zn → Zn2+ + 2e-
- Using copper as the cathode, the cathode reaction is: Cu2+ + 2e- → Cu
Cell Notation
- Cell notation is a simplified way to represent the two half-reactions.
- The single lines represent a change between the solid and liquid or aqueous phase, and the double line represents the salt bridge that connects the half-cells.
- The anode is always written on the left of the double lines, and the cathode is always written on the right.
Electrochemical Potential (E cell)
- E cell is shorthand for the electrochemical potential of the cell, which is a measure of the energy the cell can produce.
- The electrochemical potential is a result of the difference in the number of charges of the anode and the cathode.
- The electrochemical potential can be calculated by finding the difference in the electrochemical potential of the cathode and anode.
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Description
Learn about electrochemical cells, including voltaic and electrolytic cells, and how they generate electricity or drive chemical reactions.