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Questions and Answers

Chemical reactions in which reduction and oxidation takes place are known as what?

Redox reactions

Which of these is a classical definition of oxidation?

  • Gain of electrons.
  • Addition of oxygen. (correct)
  • Removal of hydrogen. (correct)
  • Loss of electrons.
  • The modern concept of oxidation and reduction is based on electron transfer.

    True

    What is the oxidation number of an element in a species called?

    <p>Oxidation State</p> Signup and view all the answers

    What is the oxidation number of hydrogen in H₂?

    <p>Zero</p> Signup and view all the answers

    What is the oxidation number of oxygen in H₂O?

    <p>-2</p> Signup and view all the answers

    What is the oxidation number of sulfur in Na2SO4?

    <p>+6</p> Signup and view all the answers

    What is the oxidation number of phosphorus in P4?

    <p>Zero</p> Signup and view all the answers

    What is the oxidation number of chlorine in Cl2?

    <p>Zero</p> Signup and view all the answers

    What is the oxidation number of fluorine in its compounds?

    <p>-1</p> Signup and view all the answers

    What is the general oxidation number of hydrogen in its compounds?

    <p>+1</p> Signup and view all the answers

    What is the general oxidation number of oxygen in oxides?

    <p>-2</p> Signup and view all the answers

    What is the oxidation number of oxygen in peroxides?

    <p>-1</p> Signup and view all the answers

    What is the maximum possible oxidation number of an element in a species?

    <p>+8</p> Signup and view all the answers

    Which element is the most electronegative element and what is its oxidation number?

    <p>Fluorine, -1</p> Signup and view all the answers

    All IA group elements show +1 oxidation number in their compounds.

    <p>True</p> Signup and view all the answers

    The sum of oxidation numbers of all atoms in a compound is always equal to zero.

    <p>True</p> Signup and view all the answers

    What is the process known as, where the oxidation number of an element increases during a chemical reaction?

    <p>Oxidation</p> Signup and view all the answers

    Oxidation and reduction can occur independently of each other.

    <p>False</p> Signup and view all the answers

    What is a substance called that oxidizes another substance by getting reduced itself?

    <p>Oxidizing agent</p> Signup and view all the answers

    What is a substance called that reduces another substance by getting oxidized itself?

    <p>Reducing agent</p> Signup and view all the answers

    What is a chemical reaction called where an element present in a single oxidation state at the reactant side converts into two different oxidation numbers at the product side, showing both oxidation and reduction?

    <p>Disproportion reaction</p> Signup and view all the answers

    What is the reverse reaction of disproportionation called?

    <p>Comproportionation reaction</p> Signup and view all the answers

    What are two methods for balancing redox reactions?

    <p>The ion-electron method and the oxidation number method.</p> Signup and view all the answers

    What is the basic unit of concentration for solutions?

    <p>Normality</p> Signup and view all the answers

    What is the n-factor of a substance called in redox reactions?

    <p>Valency factor</p> Signup and view all the answers

    The n-factor of a substance can have a negative value.

    <p>False</p> Signup and view all the answers

    In a chemical reaction, equivalent of reactants and products are always what?

    <p>Equal</p> Signup and view all the answers

    What is the process called where a solution of known concentration is added to a solution of unknown concentration until the reaction is complete.

    <p>Titration</p> Signup and view all the answers

    What is the point in a titration when the reaction is complete called?

    <p>Equivalence point</p> Signup and view all the answers

    What methods are used to determine the strength of a reducing agent?

    <p>Iodometric and lodimetric titrations</p> Signup and view all the answers

    What is the process called where the excess of a reagent in a reaction is titrated with a standard solution?

    <p>Back titration</p> Signup and view all the answers

    What is the point in a titration when an indicator is added to the solution, signaling the completion of the reaction?

    <p>Endpoint</p> Signup and view all the answers

    What kind of titration involves a process where two different equivalence points are detected by two different indicators?

    <p>Double indicator titration</p> Signup and view all the answers

    Water containing high concentrations of Ca²⁺ and Mg²⁺ ions is called soft water.

    <p>False</p> Signup and view all the answers

    What are the two types of water hardness?

    <p>Temporary and permanent hardness</p> Signup and view all the answers

    What is the process called that removes hardness from water?

    <p>Water softening</p> Signup and view all the answers

    What method can be used to remove temporary hardness?

    <p>Boiling</p> Signup and view all the answers

    Which of the following is the correct equation for the reaction of Ca(HCO₃)₂ with Na₂CO₃?

    <p>Ca(HCO3)2 + Na2CO3 → CaCO3 + 2NaHCO3</p> Signup and view all the answers

    What is the general name for the process of exchanging ions using specific materials to remove hardness?

    <p>Ion exchange</p> Signup and view all the answers

    What is the name of the process that uses sodium zeolite to remove hardness?

    <p>Permutit process</p> Signup and view all the answers

    What is the chemical name for the chemical compound Na₂[Na₄(PO₃)₆]?

    <p>Calgon</p> Signup and view all the answers

    Which of these is NOT a method used to remove hardness from water?

    <p>Adding a large amount of salt</p> Signup and view all the answers

    Study Notes

    Redox Reactions

    • Chemical reactions involving both reduction and oxidation are known as redox reactions.
    • Oxidation traditionally refers to the gain of oxygen or the loss of hydrogen.
    • The modern definition of oxidation and reduction focuses on electron transfer.
    • The oxidation number of an element in a species represents its apparent charge.
    • The oxidation number of hydrogen in H₂ is 0.
    • The oxidation number of oxygen in H₂O is -2.
    • The oxidation number of sulfur in Na₂SO₄ is +6.
    • The oxidation number of phosphorus in P₄ is 0.
    • The oxidation number of chlorine in Cl₂ is 0.
    • The oxidation number of fluorine in its compounds is always -1.
    • The general oxidation number of hydrogen in its compounds is +1, except in metal hydrides where it is -1.
    • The general oxidation number of oxygen in oxides is -2, except in peroxides and superoxides.
    • The oxidation number of oxygen in peroxides is -1.
    • The maximum possible oxidation number of an element in a species is equal to its group number.
    • Fluorine is the most electronegative element, with an oxidation number of -1.
    • All Group 1A elements (alkali metals) exhibit a +1 oxidation number in their compounds.
    • The sum of oxidation numbers of all atoms in a compound is always zero.

    Oxidation and Reduction

    • Oxidation is the process where the oxidation number of an element increases during a chemical reaction.
    • Oxidation and reduction cannot occur independently of each other.
    • A substance that oxidizes another substance by getting reduced itself is called an oxidizing agent.
    • A substance that reduces another substance by getting oxidized itself is called a reducing agent.
    • A chemical reaction where an element present in a single oxidation state at the reactant side converts into two different oxidation numbers at the product side, showing both oxidation and reduction, is called a disproportionation reaction.
    • The reverse reaction of disproportionation is called comproportionation.

    Redox Reaction Balancing

    • Two methods for balancing redox reactions are the half-reaction method and the oxidation number method.

    Concentration and Equivalents

    • The basic unit of concentration for solutions is molarity (M), which represents moles of solute per liter of solution.
    • The n-factor of a substance in redox reactions represents the number of electrons gained or lost per mole of the substance.
    • The n-factor of a substance cannot be negative.
    • In a chemical reaction, the equivalents of reactants and products are always equal.

    Titration

    • The process of adding a solution of known concentration (titrant) to a solution of unknown concentration (analyte) until the reaction is complete is called titration.
    • The point in a titration when the reaction is complete is called the equivalence point.
    • Methods used to determine the strength of a reducing agent include potentiometry and iodometry.
    • The process of titrating the excess of a reagent in a reaction with a standard solution is called back titration.
    • The point in a titration when an indicator is added to the solution, signaling the completion of the reaction, is called the end point.
    • Differential titration involves a process where two different equivalence points are detected by two different indicators.

    Water Hardness

    • Water containing high concentrations of Ca²⁺ and Mg²⁺ ions is called hard water.
    • There are two types of water hardness: temporary hardness (due to bicarbonates of Ca²⁺ and Mg²⁺) and permanent hardness (due to chlorides and sulfates of Ca²⁺ and Mg²⁺).
    • The process of removing hardness from water is called water softening.
    • Boiling can be used to remove temporary hardness.
    • The correct equation for the reaction of Ca(HCO₃)₂ with Na₂CO₃ is: Ca(HCO₃)₂ + Na₂CO₃ → CaCO₃ ↓ + 2NaHCO₃
    • The general name for the process of exchanging ions using specific materials to remove hardness is ion exchange.
    • Zeolite softening uses sodium zeolite to remove hardness.
    • The chemical name for the chemical compound Na₂[Na₄(PO₃)₆] is sodium hexametaphosphate.
    • Methods used to remove hardness from water include:
      • Boiling (temporary hardness)
      • Ion exchange (using zeolite or resins)
      • Calgon process (using sodium hexametaphosphate)
      • Lime-soda process (using lime and soda ash)

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