Ass 17 - Diamond Treatments Overview

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Questions and Answers

What is the effect of color zoning in a cyclotron-irradiated diamond?

  • It causes an umbrella-shaped color zone around the culet. (correct)
  • It leads to increased fluorescence.
  • It creates a uniform color throughout the diamond.
  • It enhances the diamond's clarity.

How is half-life relevant to understanding radioactivity in materials?

  • It shows the average stability of radioactive isotopes.
  • It defines the lifespan of gemstones.
  • It measures the time required for half of the radioactive atoms to become nonradioactive. (correct)
  • It indicates the time taken for all radioactive atoms to decay.

What happens to carbon atoms when a diamond is irradiated?

  • They become entirely nonradioactive immediately.
  • They transform into nitrogen atoms.
  • They increase the diamond's hardness.
  • They are displaced and create vacancies in the crystal lattice. (correct)

Which type of diamond has nitrogen impurities that can lead to a yellow bodycolor?

<p>Type I diamonds (C)</p> Signup and view all the answers

What is the primary result of irradiating Type IIa diamonds?

<p>They create a GR1 defect without yellow bodycolor. (C)</p> Signup and view all the answers

What role does annealing play in the treatment of diamonds after irradiation?

<p>It redistributes vacancies and impurities in the crystal lattice. (D)</p> Signup and view all the answers

Which instrument is commonly used to detect moderate to high levels of radioactivity?

<p>Geiger counter (D)</p> Signup and view all the answers

What characteristic distinguishes Type II diamonds from Type I diamonds?

<p>Type II diamonds have negligible nitrogen impurities. (C)</p> Signup and view all the answers

What is the primary visual evidence of fracture filling in diamonds?

<p>Flash effect (A)</p> Signup and view all the answers

Which of the following colors is most commonly seen in darkfield lighting when observing fracture-filled diamonds?

<p>Orange (D)</p> Signup and view all the answers

Why do gemological laboratories like GIA not grade fracture-filled diamonds?

<p>The process of filling is semipermanent. (D)</p> Signup and view all the answers

What is the main goal of diamond color treatments?

<p>To create or remove color in lower-value diamonds (D)</p> Signup and view all the answers

Which range of the D-to-Z color scale is typically chosen for color treatments?

<p>Brown or light yellow (C)</p> Signup and view all the answers

What is the process called when a material is exposed to radiation?

<p>Irradiation (B)</p> Signup and view all the answers

What makes irradiation considered a permanent treatment for diamonds?

<p>The color cannot revert to its original state. (A)</p> Signup and view all the answers

What major advancement in irradiation treatment occurred shortly after World War II?

<p>Development of the cyclotron (D)</p> Signup and view all the answers

What typically occurs to diamonds due to natural radiation in the ground?

<p>They turn green. (D)</p> Signup and view all the answers

Which characteristic is NOT typically associated with fracture-filled diamonds?

<p>Iridescence (B)</p> Signup and view all the answers

What primary colors can type Ia irradiated blue-green diamonds be transformed into?

<p>Yellow, orangy yellow, yellow-green, or brown (C)</p> Signup and view all the answers

Which of the following best describes type Ib diamonds?

<p>Extremely rare with a strong brown component (D)</p> Signup and view all the answers

How can the color of green diamonds be classified?

<p>Natural or artificial, often indistinguishable with tests (A)</p> Signup and view all the answers

What significant effect does HPHT treatment have on diamonds?

<p>Reorganizes defects within the diamond's crystal lattice (A)</p> Signup and view all the answers

What is the primary method for detecting color treatments in diamonds?

<p>Microscopic examination with diffused lighting (D)</p> Signup and view all the answers

What specific change occurs to diamonds after HPHT treatment?

<p>They exhibit significant etching and pitting (B)</p> Signup and view all the answers

What color change did the Deepedene Diamond undergo after being treated?

<p>From light yellow to green (C)</p> Signup and view all the answers

Which defects are commonly created in type Ia diamonds through irradiation and annealing?

<p>H3 and H4 defects (B)</p> Signup and view all the answers

Which statement about color treatment in diamonds is FALSE?

<p>Color changes are always permanent (C)</p> Signup and view all the answers

Why is the Deepedene Diamond historically important?

<p>It has a notable ownership lineage and transformation (B)</p> Signup and view all the answers

What is the primary purpose of fracture filling in diamonds?

<p>To improve the diamond's apparent clarity (D)</p> Signup and view all the answers

How does the refractive index (RI) of a filler used in fracture filling compare to that of air?

<p>It is closer to that of diamond than air (B)</p> Signup and view all the answers

What effect can common jewelry repair procedures have on filled diamonds?

<p>They can damage the filler used in the fractures (A)</p> Signup and view all the answers

What characteristic of diamonds that have undergone laser drilling may be observed under magnification?

<p>A step- or worm-like series of channels (A)</p> Signup and view all the answers

Which type of dark inclusion is best suited for internal laser drilling?

<p>Surface-near dark inclusions (D)</p> Signup and view all the answers

What is the primary effect of HPHT treatment on type I diamonds?

<p>It induces new color centers and removes undesirable hues. (D)</p> Signup and view all the answers

Which laboratory technique is essential for detecting HPHT-treated diamonds?

<p>Photoluminescence spectroscopy (D)</p> Signup and view all the answers

What is a common outcome of irradiation as part of a multi-step treatment on diamonds?

<p>It creates GR1 defects, which affect color. (C)</p> Signup and view all the answers

What color is best achieved through LPHT treatment in diamonds?

<p>Black (A)</p> Signup and view all the answers

Which treatment method is specifically associated with the creation of highly valued pink diamonds?

<p>Combination of HPHT and irradiation (A)</p> Signup and view all the answers

What effect does the formation of graphite around a diamond's inclusions indicate?

<p>It has undergone HPHT treatment. (B)</p> Signup and view all the answers

What combination of treatments is typically used for achieving a blue diamond color?

<p>HPHT treatment followed by irradiation (B)</p> Signup and view all the answers

Which statement about coatings on diamonds is true?

<p>Coatings can be composed of various trace elements like silver and gold. (B)</p> Signup and view all the answers

What is the function of annealing in diamond treatments?

<p>To stabilize color changes caused by irradiation. (A)</p> Signup and view all the answers

What outcome does HPHT treatment have on type IIa diamonds?

<p>It releases vacancy clusters causing brown bodycolor. (C)</p> Signup and view all the answers

Flashcards

Cyclotron-irradiated diamond

A diamond that has been exposed to radiation from a cyclotron, resulting in color zoning patterns.

Half-life (radioactivity)

The time it takes for half of the radioactive atoms in a substance to decay.

Geiger counter

A device used to detect and measure radioactivity.

Irradiated diamond color change (vacancies)

Radiation displaces carbon atoms creating vacancies in the crystal structure, absorbing red light and transmitting blue/green, causing a blue/green color.

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Type I diamond colour (Nitrogen)

Nitrogen atoms replace carbon atoms, leading to blue or yellow coloration in diamonds based on nitrogen arrangement.

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Type II diamond (Nitrogen Impurities)

Diamonds with negligible nitrogen impurities resulting in a pure blue color after irradiation. (Most often type IIa).

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Annealing (Diamonds)

A process of controlled heating and cooling to modify a diamond's color, by causing vacancies and impurities to rearrange.

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GR1 Defect

A specific defect created when type IIa diamonds are irradiated similar to that observed in type I diamonds.

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Irradiation-Annealing Color Changes

Irradiation and annealing of diamonds can create various colors, like yellow, orange-yellow, yellow-green, or brown, from blue-green diamonds.

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Type Ia Diamond Mixture

Type Ia diamonds are a mix of IaA and IaB types, which when irradiated and annealed create H3 and H4 defects.

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Type Ib Diamond Treatment

Type Ib diamonds, rare in nature, are often treated to produce a specific color, usually pink, depending on the starting brown color and irradiation duration.

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Irradiation Treatment Detection

Identifying irradiation treatments in diamonds is challenging, but advanced labs use specialized equipment to determine its origin.

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Color Concentration in Treated Diamonds

Treated diamonds may exhibit concentrated color around the culet (bottom) or on surface facets.

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Green Diamond Origin Uncertainty

Determining if a green diamond is natural or artificially treated can be very complex, even with the best technology.

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High Pressure/High Heat (HPHT) Treatment

Scientists use this process to alter a diamond's color by moving and rearranging defects within its crystal structure.

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HPHT Surface Effects

HPHT treatment causes noticeable surface etching and pitting, requiring repolishing afterwards.

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Deepdene Diamond History

A famous diamond, treated multiple times, has a recorded history through different owners and treatments dating far back.

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Color Stability

Heat is usually unlikely to change the color of most irradiation-annealing color treatments

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Flash Effect

A rapid change in color observed when a fractured diamond is viewed under a gemological microscope, indicating the presence of fracture-filling materials.

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Fracture Filling

The process of filling cracks or fractures in a diamond with materials to improve its appearance, often using glass or resin.

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Darkfield Lighting

A technique used in gemological microscopes where light is directed from the sides, highlighting surface features and revealing subtle color changes.

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Brightfield Lighting

A gemological lighting technique using direct illumination from above, highlighting interior features and revealing internal colors.

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Diamond Color Treatment

Modifying the color of a diamond through various processes to enhance its attractiveness or achieve desirable hues.

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Irradiation Treatment

Exposing diamonds to high-energy radiation to create or enhance their color.

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Linear Accelerator

A machine used in irradiation treatment to accelerate atomic particles along a straight path, bombarding diamonds with high-energy electrons.

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Cyclotron

A device that accelerates atomic particles along a circular path, used for nuclear research and irradiation treatments.

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Permanent Color Treatment

A treatment that permanently alters the diamond's color, meaning it cannot be reversed to its original state.

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Color Zoning

Irradiation can create uneven color distribution within a diamond, resulting in distinct color zones.

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HPHT Treatment

A high-pressure, high-temperature process used to change the color of diamonds by rearranging their crystal structure. This involves moving existing vacancies and nitrogen atoms within the diamond.

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Type I Diamond

Diamonds containing nitrogen impurities, which can be manipulated by HPHT treatment to create various bodycolors, like yellow, orange, or green.

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Type IIa Diamond

Diamonds with almost no nitrogen impurities. HPHT treatment can remove brown color, but does not create new bodycolors.

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Graphitization

A process where carbon atoms in a diamond rearrange into a graphite structure, often seen as a sign of HPHT treatment.

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Multi-step Treatment

A process using a combination of HPHT, irradiation, and annealing to achieve a desired bodycolor in a diamond.

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LPHT Treatment

A lower-pressure, high-temperature process similar to HPHT, but primarily used to create black color by inducing graphitization in surface fractures of diamonds.

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Coated Diamonds

Diamonds that have been coated with various materials, such as fluorides and silica, to alter their color.

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Diamond Color Modification

The process of altering the natural color of a diamond using various treatments, including HPHT, irradiation, annealing, and coating.

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How are HPHT-treated diamonds identified?

Advanced techniques such as photoluminescence spectroscopy are used to detect HPHT treatments. Additionally, signs like graphitization around inclusions and etched or frosted naturals can indicate treatment.

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Laser Drilling

A treatment that uses a laser to create a tiny tunnel in a diamond, allowing for acid to bleach or etch out inclusions, or for the laser to vaporize them.

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Internal Laser Drilling

A treatment that uses a laser to heat an inclusion near the surface, causing cleavages to expand and form channels for acid or bleach to lighten the inclusion.

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How to Detect Laser Drilling

Laser drilling creates permanent changes in the diamond, visible under magnification as tiny feathers or channels with a sugary or frosted appearance.

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Effects of Fracture Filling

Fracture filling can slightly lower a diamond's color grade and can be damaged by common jewelry repair procedures.

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Study Notes

Diamond Treatments - Clarity

  • Laser Drilling: Used since the 1970s to mask or remove inclusions. A carbon dioxide laser drills tiny tunnels to allow acid to remove or vaporize inclusions. This process leaves channels.
  • Laser Drilling Detection: Drill holes are typically located on crown facets and appear as tiny channels/feathers (black or white) under magnification.
  • Fracture Filling: Introduced in the 1980s, fracture fillings infuse a molten glass into diamond fractures to reduce visibility. The refractive index of the filling is close to that of a diamond.
  • Fracture Filling Detection: The flash effect, a change in color (orange, pink, purple, violet, or bluish-green-to-greenish-yellow) is often visible. Other signs include flattened gas bubbles, flow-like structures, or a crackled texture.

Diamond Treatments - Color

  • Goal: To improve the appearance of lower-value diamonds by mimicking higher-value colors. Value declines as color increases on the D-to-Z scales.
  • Irradiation: A process where diamonds are exposed to high-energy electrons (linear accelerators). This treatment is permanent (color doesn't revert). Color results depend on the initial diamond's material
  • Cyclotron Irradiation: A large machine that accelerates atomic particles in a circular path, enabling laboratory diamond irradiation at a commercial level. Evidence is color zoning parallel to facet junctions.
  • Half-Life: Time required for half of a radioactive substance to decay. Useful for measuring the period of radioactivity in materials.
  • Geiger Counter: A device for measuring radioactivity. Used to estimate amounts in a material.
  • HPHT (High-Pressure/High-Temperature): A treatment that moves and rearranges colour defects in a diamond's crystal structure, potentially creating or removing color. This technique can cause etching and pitting on the surface which requires repolishing. Can create yellow, orange, or yellow-green hues in Type Ia. It does not create new colours in Type IIa.
  • Annealing (Post-Irradiation): Controlled heating and cooling to allow vacancies and impurities to move in the crystal lattice, which modifies the color from irradiation.
  • Multi-Step Treatments: Combine HPHT, irradiation, and annealing to achieve specific colours like pink or blue.
  • LPHT (Low-Pressure/High-Temperature): Similar to HPHT but used to create a specific black colour through graphitization.

Detection Methods

  • Gemological Microscopy: Helps in identifying treatment by detecting visible treatment signs under magnification.
  • Advanced Laboratory Techniques: Photoluminescence spectroscopy can identify HPHT treatments.
  • Color Concentration: Can be unevenly distributed, concentrated around the culet or confined to the surface of a facted diamond, suggesting treatment.
  • Microscopic Examination: Necessary for finding treatment evidence, combined with diffused lighting and immersion.

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