Development of the Periodic Table
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Questions and Answers

How does electronegativity change as you move down a group in the periodic table, and what is the primary reason for this trend?

  • Electronegativity increases because the nuclear charge becomes stronger.
  • Electronegativity decreases because the atomic size increases, reducing the attraction between the nucleus and valence electrons. (correct)
  • Electronegativity remains constant as the number of electron shells stays the same.
  • Electronegativity increases because the number of core electrons increases, shielding the valence electrons.

For non-metals, how does reactivity generally change as you move up a group in the periodic table, and why?

  • Reactivity decreases because the elements become less likely to gain electrons.
  • Reactivity increases because the elements have a greater tendency to attract electrons. (correct)
  • Reactivity remains constant due to similar electron configurations.
  • Reactivity increases because the elements have a greater tendency to lose electrons.

Which of the following statements accurately describes the trend in metallic character across a period (from left to right) on the periodic table, and what is the underlying cause?

  • Metallic character increases due to the increasing ease of losing electrons.
  • Metallic character fluctuates randomly depending on the specific elements.
  • Metallic character remains constant because the number of valence electrons stays the same.
  • Metallic character decreases as elements become more likely to gain electrons. (correct)

How does electron affinity generally change across a period from left to right, and what primarily accounts for this trend?

<p>Electron affinity increases because the atomic size decreases and the effective nuclear charge increases, enhancing the attraction for additional electrons. (B)</p> Signup and view all the answers

What is the general trend observed for the melting points of metals as you move down a group in the periodic table, and what is the underlying reason for this trend?

<p>Melting points decrease due to weaker metallic bonds resulting from larger atomic size and reduced effective nuclear charge. (A)</p> Signup and view all the answers

Which of the following best explains why atomic radius decreases when moving from left to right across a period in the periodic table?

<p>The nuclear charge increases, pulling electrons closer to the nucleus. (A)</p> Signup and view all the answers

Mendeleev's periodic table had a significant advantage over previous attempts at organizing elements because it:

<p>predicted the existence and properties of undiscovered elements. (D)</p> Signup and view all the answers

How did Henry Moseley's work contribute to the refinement of the periodic table?

<p>He determined that elements should be organized by atomic number, which resolved discrepancies in Mendeleev's arrangement. (D)</p> Signup and view all the answers

Which of the following elements would you expect to have the lowest first ionization energy?

<p>Sodium (Na) (B)</p> Signup and view all the answers

Glenn Seaborg's primary contribution to the periodic table was:

<p>the discovery of the actinide series and their placement in the periodic table. (B)</p> Signup and view all the answers

Consider the following elements: Selenium (Se), Bromine (Br), and Krypton (Kr). How would you expect their electron affinity values to compare?

<p>Br &gt; Se &gt; Kr (B)</p> Signup and view all the answers

Which statement accurately contrasts the contributions of John Newlands and Dmitri Mendeleev to the development of the periodic table?

<p>Mendeleev arranged elements by atomic weight and predicted properties of undiscovered elements, while Newlands recognized periodicity but his Law of Octaves had limitations. (C)</p> Signup and view all the answers

If element X is in Group 16 and Period 3, and element Y is in Group 2 and Period 4, how would you compare their atomic radii?

<p>Y &gt; X (D)</p> Signup and view all the answers

Flashcards

Electron Affinity

The energy change when an electron is added to a neutral atom in the gaseous phase. Becomes more negative across a period and less negative down a group.

Electronegativity

The ability of an atom to attract electrons within a chemical bond. Increases across and decreases down the periodic table.

Metallic Character

The measure of how easily an element loses electrons and exhibits characteristic metallic properties. Decreases across and increases down the periodic table.

Reactivity Trends

Metals increase in reactivity down a group and decrease across a period, while non-metals increase in reactivity up a group and across a period.

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Melting/Boiling Points

Metals generally decrease down a group, while trends for non-metals vary, but generally increase across a period.

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Law of Triads

Grouped elements with similar properties into sets of three.

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Law of Octaves

Noted that every eighth element had similar properties, an early step toward periodicity.

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Mendeleev's Periodic Table

Arranged elements by increasing atomic weight and grouped them by similar properties, leaving gaps for undiscovered elements.

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Moseley's Contribution

The periodic table should be organized by atomic number (number of protons) rather than atomic weight.

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Seaborg's discoveries

Discovered the actinide series and reconfigured the periodic table.

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Atomic Radius

The distance from the nucleus to the outermost electron shell.

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Ionization Energy

The energy required to remove an electron from an atom.

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Study Notes

  • The periodic table is a systematic arrangement of elements by atomic number, electron configurations, and recurring chemical properties.

Development of the Periodic Table

  • Johann Dobereiner proposed the Law of Triads in 1817, grouping elements with similar properties in sets of three, like Chlorine, Bromine, and Iodine.
  • John Newlands introduced the Law of Octaves in 1864, noting that every eighth element had similar properties, which was later recognized as an early step toward periodicity.
  • Dmitri Mendeleev is credited with the development of the modern periodic table in 1869.
    • Arranged elements by increasing atomic weight and grouped them by similar properties.
    • He left gaps for undiscovered elements, accurately predicting their properties, such as Gallium and Germanium.
  • Henry Moseley determined in 1913 that the periodic table should be organized by atomic number (number of protons) rather than atomic weight.
    • Concluded that this resolves inconsistencies in Mendeleev's table and solidified the modern periodic table.
  • Glenn T. Seaborg discovered the actinide series in the 1940s.
    • He reconfigured the periodic table to include the lanthanides and actinides below the main table.
  • Trends in the periodic table help to predict the behavior and properties of elements.
    • Primarily they are the arrangement of electrons in atoms and the effective nuclear charge.

Atomic Radius

  • Atomic Radius is the distance from the nucleus to the outermost electron shell.
    • Across a Period (Left to Right): Atomic radius decreases due to increased nuclear charge pulling electrons closer.
    • Down a Group: Atomic radius increases as additional electron shells are added.

Ionization Energy

  • Ionization Energy is the energy required to remove an electron from an atom.
    • Across a Period: Ionization energy increases due to higher nuclear charge and smaller atomic radius.
    • Down a Group: Ionization energy decreases because outer electrons are farther from the nucleus and experience less attraction.

Electron Affinity

  • Electron Affinity is the energy change when an electron is added to a neutral atom.
    • Across a Period: Electron affinity generally increases (more negative) as atoms become smaller and nuclear charge increases.
    • Down a Group: Electron affinity decreases (less negative) as atomic size increases.

Electronegativity

  • Electronegativity is the ability of an atom to attract electrons in a chemical bond.
    • Across a Period: Electronegativity increases due to higher nuclear charge and smaller atomic radius.
    • Down a Group: Electronegativity decreases as atomic size increases.

Metallic Character

  • Metallic Character is the tendency of an element to lose electrons and exhibit metallic properties.
    • Across a Period: Metallic character decreases as elements become more non-metallic.
    • Down a Group: Metallic character increases as atomic size increases.

Reactivity

  • Metals: Reactivity increases down a group and decreases across a period.
  • Non-Metals: Reactivity increases up a group and across a period.

Melting and Boiling Points

  • Metals: Generally decrease down a group due to weaker metallic bonds.
  • Non-Metals: Vary significantly, but generally increase across a period.

Summary

  • The periodic table's organization reveals clear trends in atomic and chemical properties.
  • These trends are essential for predicting how elements will interact and form compounds.

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Explore the historical development of the periodic table, from Dobereiner's Triads to Mendeleev's predictions and Moseley's atomic number arrangement. Understand how these scientists shaped our modern understanding of element organization and properties. Discover the evolution of chemistry.

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