DAT Nomenclature Flashcards
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Questions and Answers

What does methyl refer to?

One line

What are alkenes?

Carbon carbon double bonds

When numbering, the double bond needs to receive the __________ # possible

lowest

What are alkynes?

<p>Carbon carbon triple bonds</p> Signup and view all the answers

Haloalkanes and alcohols receive ________ # and have priority over bonds

<p>lowest</p> Signup and view all the answers

What are diols?

<p>Alcohols with 2 hydroxy groups</p> Signup and view all the answers

What are geminal alcohols?

<p>Hydroxyl groups on same carbon</p> Signup and view all the answers

What are vicinal alcohols?

<p>Hydroxyl groups on adjacent carbons</p> Signup and view all the answers

What is an ether?

<p>Derivatives of alkanes</p> Signup and view all the answers

Study Notes

Alkanes and Nomenclature

  • Alkanes consist of carbon (C) and hydrogen (H) atoms connected solely by single bonds.
  • IUPAC naming process involves finding the longest carbon chain, numbering it, naming substituents with the -yl suffix, assigning numbers to each substituent, and completing the name.

Substituents

  • Methyl refers to a one-carbon substituent.
  • Isopropyl is a three-carbon substituent with a specific branching structure.

Alkenes and Alkynes

  • Alkenes are characterized by the presence of carbon-carbon double bonds.
  • Alkynes feature carbon-carbon triple bonds.

Numbering in Nomenclature

  • The double bond in alkenes receives the lowest possible number during chain numbering.
  • Haloalkanes and alcohols also receive the lowest numbering and take precedence over other functional groups.

Alcohols

  • Diols indicate alcohols that contain two hydroxyl (-OH) groups.
  • Geminal alcohols have hydroxyl groups attached to the same carbon atom.
  • Vicinal alcohols possess hydroxyl groups on adjacent carbon atoms.

Other Functional Groups

  • Ethers are derivatives of alkanes.
  • Formaldehyde and acetaldehyde are examples of aldehydes, which contain a carbonyl group (C=O) with the carbon also bonded to a hydrogen atom.
  • Carboxylic acids contain a carboxyl group (-COOH) and are important in organic chemistry.
  • Esters are derived from acids, where the hydroxyl group is replaced with an alkoxy group.
  • Acyl halides contain a carbonyl group attached to a halogen.
  • Amides consist of a carbonyl group attached to a nitrogen atom.
  • Nitriles have a carbon atom triple-bonded to a nitrogen atom.
  • Ketones have a carbonyl group located within the carbon chain.
  • Alcohols pertain to compounds containing one or more hydroxyl (-OH) groups.
  • Thiols are similar to alcohols but contain a sulfur atom instead of an oxygen atom.
  • Amines are organic compounds derived from ammonia, containing nitrogen atoms.

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Test your knowledge on organic chemistry nomenclature with these flashcards. Focus on understanding the IUPAC naming steps, types of hydrocarbons, and specific functional groups like alkenes and alkane. Perfect for DAT preparation!

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