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Questions and Answers

What is 'wet' natural gas primarily characterized by?

  • Exclusively consists of carbon dioxide
  • High concentration of methane only
  • Absence of any gaseous compounds
  • Presence of methane and other hydrocarbons (correct)

Which of the following is NOT a use of natural gas?

  • Industrial power generation
  • Source of hydrogen fuel cells
  • Primary feedstock for metals (correct)
  • Fuel for vehicles

What does the Law of Definite and Multiple Proportions state?

  • Compounds have a fixed weight ratio between elements (correct)
  • Elements can combine in any proportions
  • All chemical substances are identical in composition
  • The mass of elements is irrelevant during reactions

What role does stoichiometry play in industrial processes?

<p>It applies the principles of matter conservation to operations (B)</p> Signup and view all the answers

Which chemical reaction is central to modern industrial heat generation?

<p>Combustion reaction (D)</p> Signup and view all the answers

In combustion, which reactant is commonly involved?

<p>Oxygen gas (O2) (C)</p> Signup and view all the answers

Which statement about biogas is accurate?

<p>It is mostly utilized for domestic purposes in rural areas. (B)</p> Signup and view all the answers

What is the primary significance of studying combustion in chemical engineering?

<p>To understand heat generation processes in chemical manufacturing (D)</p> Signup and view all the answers

What is the empirical formula derived from the provided mole ratios?

<p>C3H4O3 (B)</p> Signup and view all the answers

Which operation is required if the lowest number of moles is expressed as a fraction?

<p>Multiply all ratios by the denominator (A)</p> Signup and view all the answers

What is the empirical weight (EW) calculated for the formula C3H4O3?

<p>88.062 g/mol (A)</p> Signup and view all the answers

How is the formula weight ratio (R) determined?

<p>By dividing the molecular weight by the empirical weight (C)</p> Signup and view all the answers

What is the result after multiplying the empirical moles of each element by the formula weight ratio when R equals approximately 2 for C3H4O3?

<p>C6H8O6 (B)</p> Signup and view all the answers

What is the first step to find the empirical formula of a compound from combustion data?

<p>Convert the masses of gases to moles (D)</p> Signup and view all the answers

What does a molecular formula provide that an empirical formula does not?

<p>The total number of atoms in the molecule (A)</p> Signup and view all the answers

In the context of the example provided, what element has a mole ratio that was multiplied by 2 to find the molecular formula?

<p>Carbon (A)</p> Signup and view all the answers

What is the amount of oxygen in the sample after calculating the total weight of carbon and hydrogen?

<p>0.0104 g (D)</p> Signup and view all the answers

How do you calculate the number of moles of carbon in the sample?

<p>Divide the weight of carbon by its molar mass. (C)</p> Signup and view all the answers

What is the mole ratio of hydrogen to oxygen in the given example?

<p>20 (D)</p> Signup and view all the answers

What is the empirical formula determined from the mole ratios of C, H, and O?

<p>C10H20O (C)</p> Signup and view all the answers

In the combustion analysis of the compound, what is the total mass of carbon dioxide produced from the sample?

<p>0.4964 g (D)</p> Signup and view all the answers

What does the precipitation of AgCl indicate about the presence of chlorine in the compound?

<p>Chlorine can be quantitatively measured. (D)</p> Signup and view all the answers

What is the mass of carbon produced from sample 1 based on the amount of CO2 generated?

<p>0.1354 g (B)</p> Signup and view all the answers

How is the amount of hydrogen calculated from sample 1?

<p>Using the mass of water produced (D)</p> Signup and view all the answers

How is the empirical formula derived from the ratios of moles calculated from the combustion?

<p>By simplifying the mole ratios to the smallest integers. (C)</p> Signup and view all the answers

From the produced AgCl in sample 2, what is the mass of chlorine calculated?

<p>0.0468 g (C)</p> Signup and view all the answers

What is the significance of transforming moles to their simplest integer ratio?

<p>It simplifies the chemical formula for additional reactions. (D)</p> Signup and view all the answers

How much chlorine is determined in sample 1 by ratio and proportion given the details from sample 2?

<p>0.0667 g (D)</p> Signup and view all the answers

What step is essential in calculating the mass of hydrogen in sample 1?

<p>Using the molar relationship between water and hydrogen (D)</p> Signup and view all the answers

What is the significance of the molar mass values used in the calculations?

<p>They help convert grams of substances into moles for stoichiometric calculations. (D)</p> Signup and view all the answers

What implies the relationship between the masses of chlorine from samples 1 and 2?

<p>A determined ratio derived from their respective calculations (D)</p> Signup and view all the answers

What is the first step in determining the mass of carbon from carbon dioxide?

<p>Convert grams of CO2 to moles (A)</p> Signup and view all the answers

What is the total amount of oxygen supplied in the flue gas based on the given values?

<p>150 kmol (C)</p> Signup and view all the answers

How much carbon dioxide is produced from 100 kmol of formaldehyde during combustion?

<p>100 kmol (D)</p> Signup and view all the answers

What is the mole ratio of O2 to CH2O based on the balanced chemical equation?

<p>1:1 (C)</p> Signup and view all the answers

Given the supplied oxygen and the stoichiometry, what is the amount of nitrogen present in the flue gas?

<p>564.2857 kmol (A)</p> Signup and view all the answers

What is the total amount of CO2 produced when using 100 kmol of CH2O based on the calculations provided?

<p>25 kmol (A)</p> Signup and view all the answers

If the combustion occurs with 50% excess air, how much theoretical oxygen is required for 100 kmol of formaldehyde?

<p>100 kmol (C)</p> Signup and view all the answers

In the provided Orsat analysis, what percentage of the gas composition is attributed to N2?

<p>79.0000% (C)</p> Signup and view all the answers

Which method is identified as more appropriate for analysis in the flue gas calculations?

<p>Method II (B)</p> Signup and view all the answers

What is the mole ratio of nitrogen to oxygen in the supplied flue gas?

<p>79:21 (C)</p> Signup and view all the answers

What is the remaining oxygen after combustion as indicated by the calculation?

<p>50 kmol (A)</p> Signup and view all the answers

How much water vapor (H2O) is generated from the combustion of 100 kmol of CH2O?

<p>100 kmol (A)</p> Signup and view all the answers

Which component is not part of the flue gas composition after combustion of formaldehyde?

<p>SO3 (D)</p> Signup and view all the answers

What proportion of the total flue gas composition consists of CO based on the calculations?

<p>22.3801% (C)</p> Signup and view all the answers

Based on the calculations of air supplied, what is the amount of nitrogen (N2) present?

<p>235.1190 kmol (D)</p> Signup and view all the answers

What is the total kmol of the flue gas calculated in the second Orsat analysis?

<p>335.1190 kmol (A)</p> Signup and view all the answers

How is the supplied O2 calculated based on the provided data?

<p>62.5 kmol of O2 from CO2 and CO (C)</p> Signup and view all the answers

What is the method used to analyze the gas composition in the Orsat analysis?

<p>Orsat Method (A)</p> Signup and view all the answers

What is the relationship stated between kmol of H2 and kmol of H2O in the calculations?

<p>1 kmol H2 generates 2 kmol H2O (C)</p> Signup and view all the answers

Flashcards

Natural Gas Types

There are two main types of natural gas. Dry natural gas mainly contains methane. Wet natural gas includes methane, but also contains ethane, propane, butane and pentane.

Natural Gas Uses

Natural gas has various uses including domestic (heating, cooking), industrial production, power generation, vehicle fuel, fertilizer production, and hydrogen fuel cells.

Stoichiometry

Stoichiometry is the study of the relationships between amounts of substances involved in chemical reactions. It focuses on mass and volume relationships in unit operations and processes.

Law of Definite & Multiple Proportions

This principle states that a pure chemical substance always contains its elements in the same proportions by weight. It also states that when two elements combine to form different compounds, their weights are always in a simple ratio.

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Industrial Stoichiometry

The application of the laws of conservation of matter, elements, and energy to industrial chemical processes and operations. It helps us understand the efficiency and effectiveness of chemical reactions in industry.

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Fuel Combustion

A chemical reaction involving a fuel reacting with oxygen (usually from air) to release energy in the form of heat. This process is important for heat generation in various industries.

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Importance of Combustion Study

Studying combustion is essential in chemical engineering, as it is a crucial step in many chemical processes where heat is needed. This field focuses on understanding and optimizing the combustion process.

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Combustion - Industrial Process

Combustion is a common and essential industrial process used for heat generation. It involves the reaction between oxygen and a fuel source.

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Empirical Formula

The simplest whole-number ratio of atoms of each element present in a compound.

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Finding the Moles of Each Element

Divide the mass of each element by its molar mass to find the number of moles present.

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How do we get the empirical formula?

  1. Find the moles of each element. 2. Divide each mole value by the smallest mole value. 3. Express the resulting ratios as the smallest whole numbers.
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Calculating Mass of Oxygen in a Sample

Mass of Oxygen = Total sample mass - Mass of Carbon - Mass of Hydrogen

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What is Combustion Analysis?

A technique used to determine the empirical formula of a compound by burning it in oxygen and measuring the masses of CO2 and H2O produced.

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How to Find Cl in a Compound

  1. React the compound with sodium to form a chloride salt. 2. Dissolve the salt and precipitate chloride ions using AgNO3.
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What's the relationship between AgCl and Cl?

The mass of AgCl produced is directly related to the mass of chlorine present in the original compound.

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What does a separate analysis reveal?

A separate analysis using a different method helps confirm the empirical formula found through combustion analysis.

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Molecular Formula

The actual number of atoms of each element in a molecule of a compound.

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Empirical Weight (EW)

The sum of the atomic weights of all the atoms in the empirical formula.

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Formula Weight Ratio (R)

The ratio of the molecular weight (MW) to the empirical weight (EW).

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How to determine the empirical formula?

  1. Find the moles of each element.
  2. Divide each mole value by the smallest mole value to obtain a ratio.
  3. If necessary, multiply the ratios by a whole number to get whole numbers.
  4. Write the empirical formula using the whole number ratios as subscripts.
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How to determine the molecular formula?

  1. Calculate the empirical weight (EW).
  2. Divide the molecular weight (MW) by the empirical weight (EW) to get the formula weight ratio (R).
  3. Multiply the ratio (R) by the subscripts in the empirical formula to get the molecular formula.
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What is the difference between empirical and molecular formula?

The empirical formula shows the simplest whole-number ratio of atoms in a compound, while the molecular formula shows the actual number of atoms of each element in a molecule.

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Why do we need to find both empirical and molecular formulas?

The empirical formula gives us the simplest ratio of atoms in a compound, but it doesn't tell us the actual number of atoms in a molecule. To determine the actual number of atoms, we need to find the molecular formula.

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Calculating Amount of Carbon

To find the amount of carbon in a sample, use the mass of carbon dioxide (CO2) produced and the molar mass of carbon and CO2. Divide the mass of CO2 by its molar mass (44 g/mol), then multiply by the ratio of the molar mass of carbon (12 g/mol) to the molar mass of CO2.

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Calculating Amount of Hydrogen

To find the amount of hydrogen in a sample, use the mass of water (H2O) produced and the molar masses of hydrogen and water. Divide the mass of water by its molar mass (18 g/mol), then multiply by the ratio of twice the molar mass of hydrogen (2 g/mol) to the molar mass of water.

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Calculating Amount of Chlorine

To find the amount of chlorine in a sample, use the mass of silver chloride (AgCl) produced and the molar masses of chlorine and AgCl. Divide the mass of AgCl by its molar mass (143.32 g/mol), then multiply by the ratio of the molar mass of chlorine (35.45 g/mol) to the molar mass of AgCl.

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Ratio and Proportion for Chlorine

To find the amount of chlorine in a sample when given the mass of a second sample and the amount of chlorine in that sample, apply the principle of ratio and proportion. Set up a proportion: the ratio of the mass of chlorine to the mass of the first sample equals the ratio of the mass of chlorine to the mass of the second sample. Solve for the unknown mass of chlorine in the first sample.

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What is the purpose of the calculations?

The calculations are performed to determine the elemental composition of the samples. This information is crucial for understanding the chemical formula of the unknown compound(s) present in the samples.

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Why are the calculated amounts important?

The calculated amounts of each element are used to determine the empirical formula of the unknown compound. The empirical formula represents the simplest whole-number ratio of atoms in the compound.

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What is the relationship between sample mass and element mass?

The mass of an element within a sample is directly proportional to the sample's overall mass. This means that changing the sample size will proportionally change the amount of each element present.

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Orsat Analysis

A method used to analyze the composition of flue gases, excluding water vapor (H2O) and sulfur trioxide (SO3).

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Formaldehyde (CH2O) Combustion

The chemical reaction where formaldehyde reacts with oxygen (O2) to produce carbon dioxide (CO2) and water (H2O).

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Excess Air

The amount of oxygen supplied beyond what is theoretically required for complete combustion of a fuel.

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Theoretical Oxygen (theo, O2)

The ideal amount of oxygen needed for complete combustion of a fuel, based on stoichiometry.

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Percent Excess Air (% x's air)

The percentage of oxygen supplied in excess of the theoretical requirement.

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Flue Gas Composition

The composition of gases released from a combustion process, typically including CO2, N2, O2, and H2O.

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Oxygen-Free (O2-free)

Describes a flue gas composition where all of the available oxygen has been consumed during combustion.

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Nitrogen (N2) in Flue Gas

Nitrogen is a major component of flue gas, originating from the air supplied during combustion.

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Flue Gas

The gas produced by burning a fuel, usually containing carbon dioxide (CO2), nitrogen (N2), and sometimes oxygen (O2).

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What is the purpose of Orsat analysis?

Orsat analysis is used to determine the composition of gases, particularly flue gas, to understand the efficiency of combustion and potential for pollutant emissions.

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How is CO2 produced?

CO2 is produced during complete combustion of carbon-containing fuels, where all the carbon in the fuel combines with oxygen.

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What does 'O2-free' signify in an Orsat analysis?

'O2-free' in an Orsat analysis indicates the volume of oxygen that has been consumed during the combustion process.

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How is CO produced?

Carbon monoxide (CO) is produced during incomplete combustion, where not all the carbon in the fuel has combined with oxygen.

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How is water (H2O) produced during combustion?

Water is produced when hydrogen (H) in the fuel combines with oxygen (O) during combustion.

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Why is method II a better approach for this problem?

Method II is more appropriate for this problem because it directly accounts for the specific fuel being burned, unlike Method I which relies on theoretical values.

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Why is the amount of oxygen supplied different from the amount consumed?

The oxygen supplied is greater than the oxygen consumed because some oxygen is leftover after combustion, while some is used for other reactions.

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What is the purpose of determining the nitrogen content in the air supplied?

The amount of nitrogen in the air supplied is needed to calculate the complete composition of the flue gas, ensuring a balanced chemical equation.

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Study Notes

Unit 3: Fuels

  • Fuels are materials that continue to burn if sufficient oxygen or air is present. The main components are carbon and hydrogen, along with sulfur.
  • Oxidation is a chemical combining process with oxygen. Combustion is rapid oxidation, while detonation is extremely fast.
  • Coal power plants commonly use coal to generate electricity through a process of pulverizing the coal, burning it, and converting the heat into steam. The steam spins turbines that turn generators, converting chemical energy to thermal, mechanical, and finally electrical energy.
  • Fuels are classified as solid (coal), liquid (petroleum), or gaseous (natural gas).

Classification of Fuels

  • Petroleum is a major fuel commonly used today.
  • Natural gas is another major fuel extracted, often found near petroleum wells. It primarily consists of methane.
  • Coal is a black rock composed of carbon, hydrogen, oxygen, nitrogen, and sulfur. Coal is categorized based on hardness and energy content, ranging from anthracite (hardest,highest energy) to bituminous (intermediate), to lignite (softest,lowest energy).

Major Forms of Fuel

  • Petroleum
  • Natural Gas
  • Coal. Coal is generally classified as anthracite, lignite, and bituminous.

Crude Oil

  • Crude oil undergoes fractional distillation to separate various components (petrol, kerosene, diesel, and fuel oil).
  • Petrol vaporizes at low temperatures and is used in cars and bikes. Kerosene is used in jets, and diesel in heavy equipment. Fuel oil is used in ships and power plants.

Natural Gas

  • Natural gas consists mainly of methane, along with ethane, propane, etc.
  • It's used in various applications from domestic heating to industrial processes.

Stoichiometry

  • Stoichiometry is the branch of chemistry that deals with mass and volume relationships in chemical reactions. It's based on the Law of Definite and Multiple Proportions (in pure substances: the elements in fixed proportions by weight).

Fuels and Combustion

  • Combustion is a chemical reaction between a fuel and oxygen that releases heat and light. It's commonly used for heat generation in industry.
  • Combustion can be complete, resulting in only carbon dioxide and water as products, or incomplete, producing carbon monoxide and unburned fuel.
  • Fuels are typically categorized as gaseous, liquid, or solid.

Combustion Analysis

  • Empirical formula represents the simplest whole-number ratio of the elements in a compound.
  • Molecular formula represents the exact number of atoms of each element in a molecule.

Additional Points

  • Light oils include Alcohols, Alcogas, Benzole, Gasoline, Paraffin, Kerosene, and Diesel fuels.
  • Solid fuels include Coal, Wood, and Charcoal.

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