Corrosion Resistance Concepts and Material Properties
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What is a key characteristic of high cycle fatigue?

  • Stress remains above the yield stress.
  • Stress levels are consistently high.
  • Fatigue occurs at low stress intervals.
  • Stress is below the yield stress. (correct)
  • In the context of cycle fatigue, what differentiates high from low cycle fatigue?

  • The type of fatigue experienced.
  • The corresponding stress levels relative to yield stress. (correct)
  • The frequency of loading cycles.
  • The excess of temperature influence.
  • Why is an increase in temperature a concern regarding nickel plates?

  • It enhances the diffusion rate of oxygen into the metal. (correct)
  • It increases the weight of the metal structure.
  • It decreases the yield stress of the metal.
  • It makes the plates more malleable.
  • What defines low cycle fatigue compared to high cycle fatigue?

    <p>Fewer loading cycles occur over time.</p> Signup and view all the answers

    Which of the following is true regarding the stress experienced in low cycle fatigue?

    <p>The stress exceeds the yield stress.</p> Signup and view all the answers

    What effect does raising the temperature have on oxygen diffusion into metals?

    <p>It increases the rate at which oxygen diffuses into the metal.</p> Signup and view all the answers

    What is the relationship between cycle fatigue and yield stress?

    <p>Low cycle fatigue occurs when stress is above yield stress.</p> Signup and view all the answers

    What would be the outcome of having a consistently high temperature for nickel plates?

    <p>Increased oxidation due to higher diffusion rates.</p> Signup and view all the answers

    What is formed when cooling hypoeutectoid steel?

    <p>Pearlite</p> Signup and view all the answers

    Where does proeutectoid ferrite form in hypoeutectoid steel?

    <p>Above the eutectoid temperature</p> Signup and view all the answers

    Which of the following statements accurately describes eutectoid temperature in hypoeutectoid steel?

    <p>It is a critical point where phase transformation occurs.</p> Signup and view all the answers

    What distinguishes the entectoid and proeutectoid ferrite phases?

    <p>The temperature at which they form</p> Signup and view all the answers

    What is the relationship between hypoeutectoid steel and pearlite formation?

    <p>Pearlite is a mixture of proeutectoid ferrite and cementite.</p> Signup and view all the answers

    At what point in the cooling of hypoeutectoid steel is proeutectoid ferrite primarily created?

    <p>Just below the eutectoid temperature</p> Signup and view all the answers

    Which phase forms alongside pearlite in hypoeutectoid steel?

    <p>Proeutectoid ferrite</p> Signup and view all the answers

    What phase transformation occurs in hypoeutectoid steel upon cooling?

    <p>Transition from austenite to pearlite</p> Signup and view all the answers

    What characterizes the transformation of martensite?

    <p>It is a diffusion-less transformation.</p> Signup and view all the answers

    How does the transformation of martensite relate to the speed of sound?

    <p>It has no effect on the speed of sound.</p> Signup and view all the answers

    What is the primary driving force for martensite transformation?

    <p>Quenching process.</p> Signup and view all the answers

    Which of the following statements is true regarding the martensite transformation?

    <p>It is a very rapid transformation.</p> Signup and view all the answers

    What condition is NOT necessary for martensite transformation to occur?

    <p>Diffusion of atoms.</p> Signup and view all the answers

    What effect does quenching have on the martensite transformation?

    <p>Helps in achieving the transformation instantaneously.</p> Signup and view all the answers

    Which factor primarily affects the martensite transformation?

    <p>The cooling rate of the material.</p> Signup and view all the answers

    Which of the following best defines the conditions under which martensite forms?

    <p>Is formed due to an instant cooling process.</p> Signup and view all the answers

    What happens to the chains when stress is applied without crosslinking?

    <p>They slide past each other.</p> Signup and view all the answers

    Why is crosslinking important in preventing excessive deformation?

    <p>It provides structural integrity by restricting chain movement.</p> Signup and view all the answers

    What is the consequence of applying too much stress without crosslinking?

    <p>Permanent deformation occurs.</p> Signup and view all the answers

    How does the lack of crosslinking affect the response of the chains to stress?

    <p>They can slide past each other.</p> Signup and view all the answers

    What small amount of deformation can be achieved with appropriate crosslinking?

    <p>Elastic deformation.</p> Signup and view all the answers

    What is the primary goal of applying stress to a material with crosslinking?

    <p>To allow for controlled deformation.</p> Signup and view all the answers

    In the absence of crosslinking, what type of deformation predominantly occurs under stress?

    <p>Permanent deformation.</p> Signup and view all the answers

    What mechanism prevents the chains from sliding past each other in a crosslinked material?

    <p>Chemical bonding.</p> Signup and view all the answers

    What would be the effect of insufficient crosslinking on a material when stress is applied?

    <p>Increased risk of permanent deformation.</p> Signup and view all the answers

    What type of chain behavior occurs when stress is reduced in a crosslinked material?

    <p>The chains resume their original position.</p> Signup and view all the answers

    What is the primary structure of martensite?

    <p>Body-centered tetragonal</p> Signup and view all the answers

    What is the process described that leads to the transformation of martensite?

    <p>Cooperative atomic movement</p> Signup and view all the answers

    What occurs to the crystal structure during martensitic transformation?

    <p>It elongates along one of its dimensions</p> Signup and view all the answers

    What is a significant result of the cooperative movement of atoms in martensite?

    <p>Shear strain in the structure</p> Signup and view all the answers

    What type of transformation does martensite undergo?

    <p>Diffusionless transformation</p> Signup and view all the answers

    Which dimensional change characterizes martensitic structure changes?

    <p>Elongation along one dimension</p> Signup and view all the answers

    What is a characteristic of martensite's atomic arrangement?

    <p>Atoms shift slightly with respect to their neighbors</p> Signup and view all the answers

    What does martensitic transformation primarily influence in metals?

    <p>Mechanical properties</p> Signup and view all the answers

    What happens to the mechanical characteristics of a material during recrystallization?

    <p>The material becomes ductile and softer.</p> Signup and view all the answers

    What occurs during the primary stage of instantaneous deformation?

    <p>Initial dislocations are formed.</p> Signup and view all the answers

    Which stage of creep involves a rapid acceleration in the creep strain rate?

    <p>Tertiary stage.</p> Signup and view all the answers

    What can happen if a material is reheated and held at a certain temperature during the spheroidization process?

    <p>The microstructure is reduced to spheroidite.</p> Signup and view all the answers

    Which condition does not change during the recovery phase of a material's deformation?

    <p>Ductility of the material.</p> Signup and view all the answers

    What does the steady state creep rate indicate?

    <p>It represents a balanced rate of deformation.</p> Signup and view all the answers

    In the context of creep behavior, which characteristic is observed during the secondary stage?

    <p>A plateau in the strain rate.</p> Signup and view all the answers

    What effect does a reduction in the microstructure have on the material's surface?

    <p>It generally enhances the ductility.</p> Signup and view all the answers

    What is an indicator that a material has reached the tertiary stage of creep?

    <p>Damage within the material begins to accumulate.</p> Signup and view all the answers

    Which phenomenon occurs during the dynamic stability of a material under creep conditions?

    <p>Equal rates of strain and dislocation recovery.</p> Signup and view all the answers

    Study Notes

    Corrosion Resistance Concepts

    • Sacrificial anode/galvanic corrosion/cathodic protection: Zinc (Zn) has a lower electrode potential than iron (Fe), preventing Fe corrosion.
    • Role of chloride ions in pitting corrosion: Chloride ions break down the passive chromium oxide layer on stainless steel, initiating pitting.
    • Aluminum reactivity: Aluminum (Al) is reactive but highly resistant due to a large passive region on the Pourbaix diagram.
    • Crack tip stress: A longer crack with a smaller tip radius has a higher maximum stress.
    • Ductile vs. brittle notch sensitivity: Ductile materials absorb more energy due to plastic deformation and crack tip blunting, thus being less sensitive.
    • High vs. low cycle fatigue: High cycle fatigue occurs at stress levels below yield stress, while low cycle is above it.

    Material Properties and Processes

    • Temperature increase in nickel plating: Increased temperature reduces the diffusion rate of oxygen in nickel plate.
    • Cold work and recrystallization: Cold work introduces internal strain energy, requiring cold work for recrystallization, with resulting increase in ductility.
    • Recovery: Internal strain energy is reduced & dislocations rearrange, with no changes in grain structure.
    • Recrystallization: New strain-free grains form the microstructure and lowers yield stress.
    • Interstitial vs. vacancy diffusion: Interstitial diffusion is generally faster for smaller atoms.
    • Bainite: Non-equilibrium/metastable phase, not shown on an iron-iron carbide phase diagram.
    • Eutectoid vs. pro-eutectoid ferrite: Pro-eutectoid ferrite forms above eutectoid temp in hypoeutectoid steel, while pearlite, including eutectoid ferrite, below.
    • Aluminum corrosion resistance: Aluminum's corrosion resistance stems from passivation (oxide layer formation) on the Pourbaix diagram.

    Material Selection and Processing

    • BCC vs. FCC Metals: BCC metals are more brittle at lower temperatures, needing more thermal energy for dislocation movement. FCC metals are close packed, more ductile, and use CPP (close-packed planes) and CPD (close-packed directions).
    • Plastic polymer cross-linking: Cross-linked polymers have higher strength than linear polymers due to stronger covalent bonds reducing sliding.
    • Polymer Brittleness: At lower temperatures, polymers become brittle because thermal energy for rotation around carbon bonds is insufficient.
    • Noble metals: Noble metals (e.g., gold) exhibit high corrosion resistance due to their high oxidizing potential and resistance to oxidation in pure water.
    • Gold-coated steel oxidation: Gold coating protects the underlying steel from oxidation.

    Strengthening Mechanisms

    • Solute atoms stress fields: Larger solute atoms create compressive stress fields, while smaller ones create tension fields, impacting dislocation movement.
    • Recovery, Recrystallization, and Grain Growth: Recovery reduces internal strain energy, recrystallization generates new grains, and grain growth enlarges them.
    • Four Strengthening Mechanisms: Cold work, precipitation, solute, and grain size strengthening all make dislocation motion difficult.
    • Age Hardening: The strength initially increases as particles precipitate and get larger, then decreases due to particle growth and increased spacing.

    Phase Transformations

    • BCC to ductile-brittle transformation: BCC metals lack close-packed planes (CPP).
    • Martensite transformation: Diffusionless, very fast transformation, does not depend on time (horizontal on TTT diagrams).

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    Description

    Test your knowledge on corrosion resistance concepts and material properties involved in engineering. This quiz covers topics ranging from galvanic corrosion to the effects of temperature on nickel plating. Challenge yourself with these key concepts essential for understanding materials science.

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