Corrosion and Passivity in Metals
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Questions and Answers

Driving force = ______ – elastomer becomes warmer when stretched

entropy

Criteria for polymer to be elastomeric: Not crystallize easily and have ______ rotations relatively free

chain bind

Vulcanization is a nonreversible reaction involving ______ in which crosslinks are formed.

sulphur

Adjacent lamellae chains ______ past each other and the chain folds become more aligned with the tensile axis.

<p>slide</p> Signup and view all the answers

Because they are crosslinked, elastomers are ______.

<p>thermosetting</p> Signup and view all the answers

Whiskers are thin single crystals with large length to diameter ratios and are exceptionally strong with high crystalline perfection, but very ______.

<p>expensive</p> Signup and view all the answers

The matrix phase generally consists of ______, polymer, or ceramic materials.

<p>metals</p> Signup and view all the answers

Fibre continues deforming ______, while the matrix yields plastically.

<p>elastically</p> Signup and view all the answers

The modulus of elasticity in the transverse direction is important for understanding the elastic behavior under ______ loading.

<p>transverse</p> Signup and view all the answers

Fibre materials commonly used in composites include glass, carbon, and ______.

<p>aramid</p> Signup and view all the answers

The compressive stresses exerted by the rolls results in a reduction of ______.

<p>thickness</p> Signup and view all the answers

When fibres fracture, the load is transferred fully to the ______.

<p>matrix</p> Signup and view all the answers

During ______, a bar of metal is forced through a die orifice by a ram.

<p>extrusion</p> Signup and view all the answers

Composite tensile strength is represented by the stress in the matrix at fibre ______.

<p>failure</p> Signup and view all the answers

In the drawing process, metal is pulled through a die having a tapered ______.

<p>bore</p> Signup and view all the answers

Ceramic-matrix composites are ideal for ______ temperature applications.

<p>high</p> Signup and view all the answers

The greatest diversity of applications is seen in ______-matrix composites.

<p>polymer</p> Signup and view all the answers

______ processes are heat treatments in which material is exposed to elevated temperatures.

<p>Annealing</p> Signup and view all the answers

Hybrid composites often combine different fibres, such as glass and ______ fibres in a single matrix.

<p>carbon</p> Signup and view all the answers

Annealing may be accelerated at higher temperatures because ______ is involved.

<p>diffusion</p> Signup and view all the answers

Casting involves pouring molten metal into a mold cavity, and upon solidification, metal assumes the shape of the ______.

<p>mold</p> Signup and view all the answers

Process annealing is used to negate the effects of cold work, to soften and increase ______ of previously strain-hardened metal.

<p>ductility</p> Signup and view all the answers

If the rate of temperature change during annealing is too great, internal ______ may occur.

<p>stresses</p> Signup and view all the answers

Secondary creep becomes ______ -> rate is constant.

<p>linear</p> Signup and view all the answers

Corrosion is the deteriorative loss of a metal as a result of ______.

<p>dissolution</p> Signup and view all the answers

Oxidation results in the formation of a non-metallic scale or ______.

<p>film</p> Signup and view all the answers

Stainless steel is highly corrosion resistant in a variety of ______.

<p>atmospheres</p> Signup and view all the answers

A protective film normally re-forms ______ if it is damaged.

<p>rapidly</p> Signup and view all the answers

Increasing temperature generally increases the rate of ______ reactions.

<p>chemical</p> Signup and view all the answers

A galvanic couple involves the connection of two metals in a liquid ______.

<p>electrolyte</p> Signup and view all the answers

Uniform attack occurs in equivalent intensity over the entire exposed ______.

<p>surface</p> Signup and view all the answers

Cold working a metal makes it more susceptible to ______.

<p>corrosion</p> Signup and view all the answers

The metal becomes positively charged as it loses ______ electrons.

<p>valence</p> Signup and view all the answers

Used when the finished shape is large or complicated, recovery and recrystallization are allowed to occur, but heat treatment is usually terminated before grain growth as fine ______ are sometimes preferable.

<p>grains</p> Signup and view all the answers

In sand casting, ordinary sand is used as the mold material, and a ______ system is incorporated to expedite metal flow and minimize defects.

<p>gating</p> Signup and view all the answers

In die casting, liquid metal is forced into a mold under ______ at a high velocity.

<p>pressure</p> Signup and view all the answers

Stress relief is used to eliminate residual stresses that developed as a result of machining or ______.

<p>grinding</p> Signup and view all the answers

In annealing of ferrous alloys, normalizing is used to refine the irregular grain shapes produced by plastic ______.

<p>deformation</p> Signup and view all the answers

Full anneal involves allowing the metal to turn into ______ then cooled in air after reaching a specific temperature.

<p>austenite</p> Signup and view all the answers

Precipitation heat treating involves heating the supersaturated alpha solid solution to an intermediate ______ within the two-phase region.

<p>temperature</p> Signup and view all the answers

In precipitation heat treating, diffusion rates become ______ at certain elevated temperatures.

<p>appreciable</p> Signup and view all the answers

Study Notes

Corrosion

  • Corrosion is the deterioration of metals as a result of dissolution due to environmental reactions.
  • Oxidation is the formation of non-metallic scale or film.
  • Degradation is the deteriorative process that occurs with polymers.

Passivity

  • Passivity is the loss of chemical reactivity. Under some environmental conditions, some metals and alloys become extremely inert. This behavior occurs due to the formation of a protective film.
  • Passivity is exhibited by Cr, Ni, Ti, and their alloys.
  • Stainless steel (Fe alloyed with at least 11% Cr) is highly corrosion-resistant in various atmospheres.
  • Passive behavior results from the formation of a thin, adherent oxide film on the metal surface, which acts as a barrier against corrosion.
  • If damaged, the protective film usually reforms rapidly.
  • Changes in the environment might cause the metal to revert to an active state, leading to increased corrosion rates.

Environmental Effects

  • Increasing fluid velocity enhances corrosion due to erosive effects.
  • Increasing temperature increases the rate of chemical reactions.
  • Increasing corrosion concentration increases the corrosion rate.
  • For materials capable of passivation, raising corrosion content may result in a transition from an active to a passive state, significantly reducing corrosion.
  • Cold working or plastically deforming a metal makes it more susceptible to corrosion.

Forms of Corrosion

  • Uniform attack occurs with equivalent intensity over the exposed surface, often leaving behind a scale or deposit.

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Description

This quiz explores the concepts of corrosion, passivity, and their environmental effects on metals. You will learn about the deterioration processes, the formation of protective films on metals like stainless steel, and how environmental changes can affect metal reactivity. Test your understanding of these important topics in materials science.

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