Corrosion and Fluid Mechanics Quiz

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Questions and Answers

Which of the following correctly defines fuel?

  • A compound composed of Carbon and Hydrogen.
  • A compound composed of Carbon and Hydrogen, easily burn in air. (correct)
  • A compound that produces large amounts of heat. (correct)
  • A chemical that provides energy through combustion.

What is the ideal surface tension of fuel?

  • High
  • Moderate
  • Low (correct)
  • Dependent on specific conditions

To remove dissolved oxygen from feeding water of a boiler at high pressure, which method is appropriate?

  • Filtration method
  • Use of a reducing agent (correct)
  • Chemical oxidation
  • Heating the water

What is the main component used to remove oil and suspended colloids from water?

<p>Alum (D)</p> Signup and view all the answers

What leads to corrosion of zinc metal when immersed in caustic soda?

<p>Electrolytic action (C)</p> Signup and view all the answers

Stress corrosion cracking of alloys is influenced by which factors?

<p>Both B and C (A)</p> Signup and view all the answers

What is the correct definition of pitting corrosion?

<p>Localized corrosion that leads to the formation of small pits (D)</p> Signup and view all the answers

In a galvanic cell involving iron and copper, what is the anodic reaction for iron?

<p>Fe → Fe^+2 + 2e (B)</p> Signup and view all the answers

What is the best method to protect a pipeline carrying crude petroleum oil?

<p>Both cathodic protection and paints. (C)</p> Signup and view all the answers

What is one mechanism through which inhibitors provide protection against corrosion?

<p>Elimination of active corrosive agents. (A)</p> Signup and view all the answers

What is a necessary condition for the impressed current in cathodic protection?

<p>Protection potential must be greater than or equal to corrosion potential. (B)</p> Signup and view all the answers

Which of the following causes corrosion inside boilers?

<p>All of the above. (D)</p> Signup and view all the answers

What is produced when using untreated water that contributes to scale formation?

<p>Dissolved salts forming a dry adhesive layer. (C)</p> Signup and view all the answers

Permanent hardness of water is primarily caused by which of the following?

<p>Calcium and magnesium salts. (D)</p> Signup and view all the answers

Increasing the percentage of paraffins in fuel is associated with which of the following?

<p>both A and B (B)</p> Signup and view all the answers

What is an incorrect option regarding methods of pipeline corrosion protection?

<p>Both A and C are incorrect. (B)</p> Signup and view all the answers

What does the ash content of a fuel refer to?

<p>both A and C (C)</p> Signup and view all the answers

Which of the following does NOT contribute to the effectiveness of cathodic protection?

<p>Electric leakage in the system. (A)</p> Signup and view all the answers

The formation of carbon monoxide during the combustion of fuel is primarily due to which factor?

<p>both B and C (A)</p> Signup and view all the answers

Kinematic viscosity is related to which of the following factors?

<p>all of the above (D)</p> Signup and view all the answers

A decrease in hydrogen content of a fuel is associated with which outcomes?

<p>both A and B (B)</p> Signup and view all the answers

An increase in the hydrogen content of a fuel tends to result in which effect?

<p>all of the above (D)</p> Signup and view all the answers

The dynamic viscosity of a fuel is related to which of the following forces?

<p>both A and C (D)</p> Signup and view all the answers

Good ignition of the fuel is primarily owing to which factor?

<p>all of the above (D)</p> Signup and view all the answers

Which salt is responsible for causing permanent hardness of water?

<p>Magnesium sulfate (A), Calcium sulfate (C)</p> Signup and view all the answers

Which of the following agents can be used to avoid formation of oils and colloids in water?

<p>Alum as a coagulating agent (C)</p> Signup and view all the answers

What role does silver metal play in the electroplating method to protect iron from atmospheric corrosion?

<p>Serves as a cathode in the electroplating cell (A), Acts as an inert barrier (C)</p> Signup and view all the answers

Which condition is crucial for the Impressed current method of Cathodic Protection?

<p>Protection potential must exceed the corrosion potential (A)</p> Signup and view all the answers

What should the pH of feeding water of boilers be maintained at?

<p>pH between 8 and 10 (C)</p> Signup and view all the answers

Which of the following is NOT a method to decrease the corrosion of a corrosive solution inside a metallic pipeline?

<p>Increasing temperature (B)</p> Signup and view all the answers

Which cell converts electrical energy into chemical energy?

<p>Electrolytic cell (C)</p> Signup and view all the answers

What type of corrosion occurs due to the loss of coherence forces between the grains?

<p>Intergranular corrosion (D)</p> Signup and view all the answers

What is the cathodic reaction in a Mg-Fe galvanic cell in a neutral medium?

<p>Fe → Fe^+2^ + 2e (B)</p> Signup and view all the answers

What is the primary concern regarding non-burn compounds during fuel combustion?

<p>They produce ash and residues. (A)</p> Signup and view all the answers

Which conditions apply to the sacrificial anode method of cathodic protection?

<p>Protected metallic structure must be cathode (A)</p> Signup and view all the answers

What type of corrosion occurs when a metal is exposed to acidic vapor?

<p>Chemical corrosion (D)</p> Signup and view all the answers

What is one consequence of scale formation inside boilers?

<p>Decreased heat transfers and increased fuel consumption. (D)</p> Signup and view all the answers

In differential aeration corrosion, what is the cathodic reaction?

<p>H2O + 1/2 O2 + 2e → 2OH^- (D)</p> Signup and view all the answers

Which statement about ash content in fuel is true?

<p>It comprises inorganic compounds (C)</p> Signup and view all the answers

What effect does decreasing the specific gravity of fuel have?

<p>Both A and C. (D)</p> Signup and view all the answers

Which of the following parameters contributes to good ignition in fuel?

<p>Lower viscosity (C)</p> Signup and view all the answers

Which combination of factors tends to promote good combustion of fuel?

<p>Lower specific gravity and surface tension. (D)</p> Signup and view all the answers

What is the main condition for effective sacrificial anode cathodic protection?

<p>The anode must be less noble than the protected metal (C)</p> Signup and view all the answers

What should the pH of water entering an anion exchange resin be?

<p>Less than 7. (B)</p> Signup and view all the answers

What conditions should feeding water for boilers meet?

<p>It must be free from dissolved oxygen. (A), It must be deionized water. (C)</p> Signup and view all the answers

What does the flash point of a fuel indicate?

<p>The minimum temperature required for the fuel to ignite. (D)</p> Signup and view all the answers

What is a significant factor leading to a lowering of the calorific value of fuel?

<p>Water formation during combustion. (D)</p> Signup and view all the answers

How is sludge formed inside water pipes characterized?

<p>As a result of impurities in water. (C)</p> Signup and view all the answers

Flashcards

Oxygen Removal in Boiler Feed Water

The removal of dissolved oxygen from boiler feedwater using a chemical reducing agent like sodium sulfite.

Sedimentation in Water Treatment

The process of removing suspended solids from water by allowing them to settle at the bottom.

pH of Boiler Feedwater

The pH of boiler feedwater should be slightly alkaline (above 7) to prevent corrosion.

Electrolytic Cell

A cell that converts electrical energy into chemical energy.

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Electrode Potential

The tendency of a metal to corrode in a specific environment, measured as a voltage difference between the metal and a standard electrode.

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Acidic Vapor Corrosion

The process of corrosion where metal surfaces are attacked by acids or acidic vapors.

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Higher Calorific Value (HCV)

The measure of a fuel's heating capacity, taking into account the heat released by the combustion of both combustible and non-combustible components.

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Ash Content of Fuel

Inorganic compounds present in fuel that form ash after combustion.

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What is a fuel?

A fuel is a substance that can be burned to release energy. It mainly consists of carbon and hydrogen, which easily react with oxygen in the air to produce heat and light.

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What is a Sacrificial Anode?

Sacrificial Anode is a more active metal connected to the metal to be protected, which corrodes instead of the protected metal.

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What is the ideal surface tension for fuel?

Surface tension is the ability of a liquid to resist an external force, like a drop of water forming a sphere. For efficient fuel combustion, a lower surface tension is essential for proper atomization, allowing the fuel to mix better with air.

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What is the key characteristic of a Sacrificial Anode?

The Sacrificial Anode must be more anodic (more prone to corrosion) than the metal it's protecting.

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How to remove dissolved oxygen from boiler water?

Dissolved oxygen in boiler feed water can cause corrosion. Reducing agents react with oxygen, removing it from the water.

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In electroplating iron with silver, what role does silver play?

Silver acts as the Cathode in electroplating iron. It's the surface where the silver ions are reduced to form a protective layer.

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What do cation exchange resins do?

Cation exchange resins are used to remove positively charged ions (cations) like calcium and magnesium from water. They are used in water softening processes.

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What is the cathodic reaction in Differential Aeration Corrosion?

The cathodic reaction in Differential Aeration Corrosion involves oxygen and water, producing hydroxide ions (OH-) at the cathode.

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What are the key factors for successful coating protection?

Successful coating protection relies on a good barrier, a clean surface, and the formation of an inactive layer.

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What is used to remove oil and suspended particles from water?

Alum is a chemical commonly used in water treatment to remove suspended colloids and oil. It acts as a coagulant, causing tiny particles to clump together for easier removal.

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Why does copper corrode in ammonia?

Metallic copper reacts with ammonia to form a compound that causes corrosion. The ammonia molecules attack the copper atoms, weakening the structure.

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What causes intergranular corrosion?

Intergranular corrosion occurs due to a potential difference between grain boundaries and the bulk metal caused by precipitation of impurities at the grain boundaries.

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How does an inert barrier protect against corrosion?

An inert barrier prevents corrosion by isolating the metal from the corrosive environment.

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What causes galvanic corrosion?

Galvanic corrosion happens when two dissimilar metals are connected in an electrolyte. The metal with a lower potential (more reactive) corrodes faster. This is why different electrolytes (like seawater) can create different corrosion rates.

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What causes stress corrosion cracking?

Stress corrosion cracking occurs when a material is under stress and exposed to a specific corrosive environment. The combination of stress and the corrosive agent weakens the material, leading to cracking.

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What's the main condition for Impressed Current Cathodic Protection?

Impressed current method requires a power source to drive the cathodic protection current.

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Cathodic Protection for Pipelines

Cathodic protection is used to protect pipelines carrying corrosive substances like crude oil. This method involves introducing an electric current to create a protective layer on the pipe's metal surface, preventing corrosion.

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Mechanism of Corrosion Inhibitors

Inhibitors are chemicals added to the corrosive environment to slow down or prevent metal corrosion. They work by creating a protective film, reacting with corrosive agents, or altering the corrosion process.

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Conditions of Impressed Current Cathodic Protection

Impressed current cathodic protection involves using an external power source to create a protective current flow. The system ensures that the metal surface being protected is at a more negative potential than the surrounding environment, thus preventing corrosion.

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Incorrect Cathodic Protection Placement

The placement of anodes around a structure to protect it from corrosion is considered incorrect protection. This method is inefficient because it does not provide uniform protection across the entire surface.

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Causes of Corrosion in Boilers

Corrosion inside boilers can be caused by chloride salts, acidity, dissolved oxygen, and bacteria. These factors create conditions that accelerate the degradation of the boiler's metal components.

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Scale Formation in Boilers

Scale formation in boilers is primarily due to dissolved salts in cold water, which form a dry adhesive layer. This layer can impede heat transfer and lead to overheating.

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Permanent Hardness of Water

Permanent hardness in water is caused by the presence of calcium and magnesium salts, particularly sulfates. These salts cannot be easily removed by boiling and can cause scaling and other problems.

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Decreasing specific gravity of fuel

Decreasing the specific gravity of a fuel usually means an increase in the percentage of paraffin in the fuel. This leads to improved ignition characteristics.

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Factors contributing to good combustion

Good combustion requires high hydrogen content in the fuel and lower specific gravity and surface tension. These factors contribute to a more efficient and complete burning process.

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pH of water entering anion exchange resin

The pH of water entering an anion exchange resin should be less than 7. Anion exchange resins remove negatively charged ions, and water with a pH less than 7 indicates the presence of acidic components that need to be removed.

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Boiler feeding water conditions

The feeding water for boilers should be deionized and free from dissolved oxygen. Deionized water minimizes the formation of scale and corrosion, while the absence of oxygen prevents oxidation and deterioration.

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Flash point of a fuel

The flash point of a fuel refers to the lowest temperature at which the fuel will ignite when exposed to a source of ignition. It's not directly related to density or evaporation but is a significant safety parameter.

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Factors affecting calorific value

Lowering the calorific value of a fuel can be caused by factors like the composition of the fuel, water formation, and the presence of hydrogen (which is a less energy-dense component).

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Sludge in water pipes

Sludge that forms inside water pipes is a result of impurities in the water. These impurities can accumulate and form deposits that hinder water flow and affect the pipes' efficiency.

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What is ash content in fuel?

Refers to the impurities present in the fuel. These impurities can be inorganic substances like ash or mineral content.

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How does increasing Paraffins in fuel affect ignition?

Increasing the percentage of paraffins in the fuel leads to better ignition properties.

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How does Hydrogen content affect Calorific value?

The greater the amount of hydrogen in a fuel, the higher its calorific value, meaning it produces more energy when burned.

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What is Dynamic viscosity related to?

The dynamic viscosity of a fluid is related to the cohesive forces between the fluid molecules.

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What factors affect Kinematic viscosity?

Kinematic viscosity is influenced by factors like the nature of the surface (smooth or rough), the adhesive forces, and the motion of the fluid.

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What happens to calorific value when Hydrogen content decreases?

A decrease in the hydrogen content of a fuel leads to a decrease in its calorific value, meaning it produces less energy.

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What causes Carbon Monoxide formation?

The formation of carbon monoxide during fuel combustion occurs due to incomplete combustion caused by a lack of sufficient air.

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How does increasing Paraffins affect Specific Gravity?

The specific gravity of a fuel tends to decrease as the percentage of paraffins increases because paraffins are less dense than other hydrocarbons.

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Study Notes

Section I - Corrosion

  • Mineral acids are more corrosive than moist air, organic acids, and sea water. All of the above.
  • Iron corrodes easily in the atmosphere due to its high activity and its reaction with oxygen.
  • Passivity to corrosion depends on the metal's resistivity, the type of metal, and the corrosive environment.
  • Pitting corrosion occurs due to non-uniform surfaces and non-uniform corrosive impurities, resulting in localized reactions.
  • Galvanic corrosion involves a reduction reaction in a neutral medium, with the oxidation reaction involving water and oxygen, producing hydroxide ions.
  • Decreasing water velocity in pipelines will decrease pitting corrosion.

Section II - True or False

  • Calorific value is the energy released from completely burning a unit mass of fuel, true.
  • Dynamic viscosity relates to the motion, false.
  • Ion exchange resins remove non-ionized salts; false.
  • Scale is characterized by bad heat conductivity, true.
  • Inert barriers resist corrosion in various environments, false.
  • Corrosion inhibitors are chemical compounds that reduce corrosion, true.
  • Pitting and intergranular corrosion are localized electrochemical reactions, true.
  • Uniform corrosion is localized, false.
  • Non-metallic structures exposed to seawater experience erosion corrosion; false.
  • Ion exchange resins remove all salts from water; false.
  • Inert barriers resist corrosion in specific environments; true.
  • Organic inhibitors' mechanisms involve electron-electron interactions; true.
  • Non-metallic structures corrode when exposed to seawater via erosion corrosion; false.
  • Inhibitors are used in gaseous and liquid mediums to reduce corrosion; true.
  • Sludge's adhesion is higher, and it's dryer than scale; false.
  • Decreasing fuel specific gravity promotes better ignition, true.
  • Metal corrosiveness based on resistivity, primarily depends on the metal type and corrosive environment; false.
  • Hydrazine is an anti-corrosion agent; true.
  • Fuel is the amount of energy released when a unit mass is completely burned in the air, false.
  • Uniform corrosion is chemical, true.
  • Dissolved metals in acidic or alkaline environments are non-uniform corrosion, false.
  • Scale is a good conductor of heat, false.
  • Sacrificial anode corrosion protection works in multiple mediums, false.
  • Impressed current protection method involves the potential protection exceeding corrosion potential, true.
  • Good combustion fuel has low surface tension, and increasing carbon percentage decreases calorific value; true and true.
  • Deionized water is free from ionized and non-ionized salts; false.
  • Feeding water in boilers should be free from oxygen, true.
  • Inhibitors decrease corrosion via chemical compounds, true.
  • Ion exchange resins remove non-ionized salts dissolved in water; false.

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