Coordination Chemistry and Central Atoms

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Questions and Answers

What defines a coordination entity?

  • A central metal atom or ion bonded to a fixed number of ions or molecules. (correct)
  • A group of ions that do not have a central atom.
  • A central metal atom or ion surrounded by a variable number of ions or molecules.
  • An ionic compound formed between two nonmetals.

Which of the following is an example of a coordination entity?

  • H2O
  • [Ni(CO)4] (correct)
  • NaCl
  • [Cl2]

What role does the central atom/ion play in a coordination entity?

  • It is the atom or ion to which fixed numbers of other ions are bound. (correct)
  • It serves as a stabilizing agent.
  • It primarily exists in a gaseous state.
  • It forms covalent bonds only with nonmetals.

Which of the following central atoms/ions is incorrectly matched with its coordination entity?

<p>Fe2+ in [Fe(CN)6]3– (D)</p> Signup and view all the answers

Which of the following statements about central atoms/ions is true?

<p>They are referred to as Lewis acids when they form coordination entities. (A)</p> Signup and view all the answers

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Study Notes

Coordination Entity

  • A central metal atom or ion is bonded to a fixed number of ions or molecules.
  • The metal atom or ion is surrounded by the ions or molecules in a specific arrangement.
  • Examples include: [CoCl3(NH3)3], [Ni(CO)4], [PtCl2(NH3)2], [Fe(CN)6]4–, [Co(NH3)6]3+

Central Atom/Ion

  • The atom/ion in the center of a coordination entity is called the central atom or ion.
  • The central atom/ion has a fixed number of ions or groups bound to it in a specific geometric arrangement.
  • Examples include: [NiCl2(H2O)4], [CoCl(NH3)5]2+ and [Fe(CN)6]3–
  • The central atoms/ions in these examples are Ni2+, Co3+ and Fe3+, respectively.
  • Central atoms/ions are also referred to as Lewis acids.

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