Conductometry and Ohm's Law Definitions
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Questions and Answers

What is the meaning of the term 'specific conductance' or 'conductivity' denoted by the symbol K?

  • The conductance when the length (L) is unity (1 cm) and the area (A) is unity (1 cm²) (correct)
  • The conductance of a solution at a specific concentration and temperature
  • The conductance of a cubic centimeter of liquid (1 cm³)
  • The ratio of conductance to cell constant (L/A)

What is the relationship between the observed conductance (G), specific conductance (K), and the cell constant (L/A)?

  • G = (L/A) × K
  • G = K × A / L (correct)
  • G = K / (L/A)
  • G = (L/A) / K

Why is it important to use platinum (Pt) electrodes in conductometric measurements?

  • Pt electrodes are more stable and do not undergo redox reactions (correct)
  • Pt electrodes have a higher conductivity than other metals
  • Pt electrodes are more sensitive to changes in conductance
  • Pt electrodes are more widely available and cost-effective

Why are conductometric determinations carried out using alternating current (AC) instead of direct current (DC)?

<p>AC reduces the polarization of the electrodes (C)</p> Signup and view all the answers

Why are conductometric determinations typically carried out using diluted solutions?

<p>Diluted solutions minimize the effect of ion interactions and complexation (C)</p> Signup and view all the answers

What is the purpose of maintaining a constant cell constant (L/A) during conductometric determinations?

<p>To ensure a consistent relationship between conductance and specific conductance (D)</p> Signup and view all the answers

Why are conductometric determinations typically carried out under thermostatically controlled conditions?

<p>To ensure accurate and reproducible measurements (B)</p> Signup and view all the answers

What is the main advantage of using electrochemical methods of analysis, such as conductometry, over other analytical techniques?

<p>Simpler sample preparation (A)</p> Signup and view all the answers

Which of the following is not a key factor that affects the specific conductance (K) of a solution?

<p>pH of the solution (A)</p> Signup and view all the answers

What is the main reason for using solutions of known conductivity to determine the cell constant (L/A) of a conductometric measurement system?

<p>To establish the relationship between conductance and specific conductance (C)</p> Signup and view all the answers

How does the choice of cell constant (L/A) affect the conductometric measurements of solutions with different conductivity levels?

<p>Cells with higher L/A are used for solutions with higher conductivity (B)</p> Signup and view all the answers

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