Comparing Heat Capacities of Glasses and Crystals
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Questions and Answers

What is the kinetic energy per degree of freedom for each particle in a structure?

  • $kB$
  • $2kB$
  • $4kB$
  • $0.5kB$ (correct)

In what scenario does the law of Dulong and Petit apply as a good approximation for the molar heat capacity?

  • For complex structured solids at high temperatures
  • For mono-atomic metals at any temperature
  • For crystalline solids at high temperatures (correct)
  • For glasses at low temperatures

What happens to the heat capacity of solids at low temperatures according to the text?

  • It increases
  • It decreases (correct)
  • It oscillates
  • It remains constant

How many degrees of freedom are considered when a solid has a complex structure?

<p>3 degrees of freedom (A)</p> Signup and view all the answers

Which law deviates from the experimental results at low temperatures for heat capacity?

<p>Law of Dulong and Petit (A)</p> Signup and view all the answers

What does the heat capacity of solids tend towards as temperature approaches zero?

<p>$0$ (B)</p> Signup and view all the answers

What does the Debye model take into account for better predictions of heat capacities in solids?

<p>Elastic vibrations of the whole body (B)</p> Signup and view all the answers

What is the significance of the Debye temperature (θD) in relation to heat capacities of solids?

<p>A lower θD implies more vibrational modes are excited at lower temperatures (B)</p> Signup and view all the answers

How does the heat capacity behavior of electron conductors differ from isolators at extremely low temperatures?

<p>Electron conductors show a T1-law while isolators exhibit a T3-law (D)</p> Signup and view all the answers

How do monoatomic metals align with the Dulong-Petit Law in terms of heat capacities?

<p>They fully comply with the Dulong-Petit Limit (A)</p> Signup and view all the answers

How does the metallic bond impact the heat capacity of metals compared to what might be initially expected?

<p>Most electrons cannot contribute to heat capacity due to already occupied energy states below the Fermi distribution (D)</p> Signup and view all the answers

How do the heat capacities of a glass and its iso-chemical crystal usually compare below the glass transition temperature (Tg)?

<p>The heat capacities are identical for both materials directly below Tg (B)</p> Signup and view all the answers

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