Podcast
Questions and Answers
What gas is predominantly produced when hydrocarbons undergo complete combustion?
What gas is predominantly produced when hydrocarbons undergo complete combustion?
- Sulfur dioxide (SO2)
- Nitric oxide (NO)
- Carbon monoxide (CO)
- Carbon dioxide (CO2) (correct)
At what temperature does nitrogen in the air begin to react and form nitric acid during combustion?
At what temperature does nitrogen in the air begin to react and form nitric acid during combustion?
- 2200 ᵒC
- 2000 ᵒC
- 1500 ᵒC
- 1800 ᵒC (correct)
Which statement correctly describes the composition of dry air as it relates to combustion?
Which statement correctly describes the composition of dry air as it relates to combustion?
- 20.9% argon, 78.1% oxygen
- 100% carbon dioxide
- 78.1% nitrogen, 20.9% oxygen (correct)
- 33.3% nitrogen, 33.3% oxygen
What is the term used for the mixture of gases that leaves a combustion furnace?
What is the term used for the mixture of gases that leaves a combustion furnace?
Which substance is mainly involved in the analysis of environmental pollution from combustion?
Which substance is mainly involved in the analysis of environmental pollution from combustion?
In a combustion reaction involving hydrocarbons, what is the result of incomplete combustion?
In a combustion reaction involving hydrocarbons, what is the result of incomplete combustion?
What component definitions differentiate wet basis from dry basis in gas compositions?
What component definitions differentiate wet basis from dry basis in gas compositions?
What percentage of the available energy in the feed is contained in activated carbon?
What percentage of the available energy in the feed is contained in activated carbon?
What is the primary purpose of coal gasification?
What is the primary purpose of coal gasification?
Which statement is true regarding the water-splitting process for hydrogen production?
Which statement is true regarding the water-splitting process for hydrogen production?
What is required for the storage of hydrogen gas?
What is required for the storage of hydrogen gas?
What occurs after the impurities are removed from the synthesis gas during coal gasification?
What occurs after the impurities are removed from the synthesis gas during coal gasification?
What is the primary source material for charcoal production?
What is the primary source material for charcoal production?
Which characteristic is associated with soft coke?
Which characteristic is associated with soft coke?
What percentage of virgin sugarcane does bagasse represent in weight?
What percentage of virgin sugarcane does bagasse represent in weight?
What temperature range is used for producing soft coke from coal?
What temperature range is used for producing soft coke from coal?
Which manufactured solid fuel is known for leaving a solid residue with no smoke when burned?
Which manufactured solid fuel is known for leaving a solid residue with no smoke when burned?
What is a key characteristic that good briquettes should have?
What is a key characteristic that good briquettes should have?
What is a unique feature of hard coke compared to soft coke?
What is a unique feature of hard coke compared to soft coke?
Which of the following solid fuels is primarily derived from sugarcane?
Which of the following solid fuels is primarily derived from sugarcane?
What is the primary use of charcoal in many countries?
What is the primary use of charcoal in many countries?
What is the main disadvantage of hard coke compared to soft coke?
What is the main disadvantage of hard coke compared to soft coke?
What is the primary purpose of converting gas composition from dry basis to wet basis?
What is the primary purpose of converting gas composition from dry basis to wet basis?
What is the term used to describe the amount of air fed to a reactor that exceeds the theoretical air requirement?
What is the term used to describe the amount of air fed to a reactor that exceeds the theoretical air requirement?
Given 100 mol/h of butane and 5000 mol/h of air, which reactant is in excess?
Given 100 mol/h of butane and 5000 mol/h of air, which reactant is in excess?
What is needed to calculate the theoretical oxygen and air feed rates for combustion?
What is needed to calculate the theoretical oxygen and air feed rates for combustion?
If the percentage of excess air is 50%, what does that signify?
If the percentage of excess air is 50%, what does that signify?
In what scenario would more of a less expensive reactant be fed into a combustion reactor?
In what scenario would more of a less expensive reactant be fed into a combustion reactor?
What is the theoretical oxygen requirement for the complete combustion of the fuel assumed to be oxidized to?
What is the theoretical oxygen requirement for the complete combustion of the fuel assumed to be oxidized to?
How can the air feed rate be calculated from theoretical air and excess percentage?
How can the air feed rate be calculated from theoretical air and excess percentage?
Which factor contributes to the cost when using an excess reactant in combustion reactions?
Which factor contributes to the cost when using an excess reactant in combustion reactions?
What is the primary form of hydrogen produced through steam methane reforming?
What is the primary form of hydrogen produced through steam methane reforming?
What is one major byproduct of steam methane reforming?
What is one major byproduct of steam methane reforming?
At what temperature range does the steam methane reforming process occur?
At what temperature range does the steam methane reforming process occur?
What is the function of the nickel catalyst in steam methane reforming?
What is the function of the nickel catalyst in steam methane reforming?
What is the outcome of the water gas shift reaction?
What is the outcome of the water gas shift reaction?
What is produced as a byproduct in methane pyrolysis?
What is produced as a byproduct in methane pyrolysis?
Which process generates CO2-free hydrogen?
Which process generates CO2-free hydrogen?
What temperature is typically used in the lower-temperature water gas shift reaction?
What temperature is typically used in the lower-temperature water gas shift reaction?
What type of reaction occurs during steam methane reforming?
What type of reaction occurs during steam methane reforming?
What is the role of steam (H2O) in the steam methane reforming process?
What is the role of steam (H2O) in the steam methane reforming process?
Flashcards
Combustion
Combustion
The process of burning fuel to release energy, often used in power plants to generate electricity.
Fuel components
Fuel components
The components of a fuel that react to form combustion products.
Carbon Dioxide (CO2)
Carbon Dioxide (CO2)
The primary product of carbon reacting during combustion.
Carbon Monoxide (CO)
Carbon Monoxide (CO)
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Sulfur Dioxide (SO2)
Sulfur Dioxide (SO2)
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Dry basis composition
Dry basis composition
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Stack gas or flue gas
Stack gas or flue gas
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Theoretical Air
Theoretical Air
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Excess Air
Excess Air
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Theoretical Oxygen
Theoretical Oxygen
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Wet Basis Conversion
Wet Basis Conversion
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Wet Gas Flow Rate
Wet Gas Flow Rate
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Dry Gas Flow Rate
Dry Gas Flow Rate
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Charcoal
Charcoal
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Coke
Coke
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Soft Coke
Soft Coke
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Hard Coke
Hard Coke
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Briquettes
Briquettes
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Bagasse
Bagasse
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Destructive Distillation
Destructive Distillation
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Volatile Matter
Volatile Matter
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Recycling
Recycling
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Thermal Processing
Thermal Processing
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Hydrocarbon Decomposition for Hydrogen Production
Hydrocarbon Decomposition for Hydrogen Production
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Plasma Arc Waste Disposal
Plasma Arc Waste Disposal
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Coal Gasification
Coal Gasification
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Water-Gas Shift Reaction
Water-Gas Shift Reaction
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Electrolysis
Electrolysis
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Steam Methane Reforming (SMR)
Steam Methane Reforming (SMR)
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SMR: The Primary Reaction
SMR: The Primary Reaction
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SMR: The Water Gas Shift Reaction
SMR: The Water Gas Shift Reaction
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CO2 in SMR
CO2 in SMR
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Methane Pyrolysis
Methane Pyrolysis
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Methane Pyrolysis: The Reaction
Methane Pyrolysis: The Reaction
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Methane Pyrolysis: CO2-free Hydrogen
Methane Pyrolysis: CO2-free Hydrogen
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Syngas
Syngas
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Endothermic Reaction
Endothermic Reaction
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Exothermic Reaction
Exothermic Reaction
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Study Notes
Energy Sources
- Stoichiometric Combustion: The theoretical combustion of a fuel when mixed with the correct amount of oxygen (air). The products are only CO2 and H2O.
- Air Required: The net volume of air needed for stoichiometric combustion of different constituents (CO, C2H4, C2H6, CH4) is calculated using different figures for each. Air is primarily oxygen and nitrogen.
- Air Composition: Air is mostly oxygen (20.9%) and nitrogen (79.1%), along with small amounts of other gases. For combustion calculations, nitrogen is included as well.
- Hydrocarbon Fuels: Complete oxidation of a hydrocarbon fuel (CnHm) results in nCO2 + (m/2)H2O.
- Combustion Reactions: The rapid reaction of a fuel with oxygen. The products (carbon dioxide, water, etc.) often have less energy value than the fuel used.
- Combustion Chemistry: Key fuels used in furnaces include coal, fuel oil, gaseous fuels (methane, etc.), and liquefied petroleum gas.
- Incomplete Combustion (Partial Combustion): Fuel burning that produces carbon monoxide (CO) instead of carbon dioxide (CO2). This occurs when there is insufficient oxygen.
- Air Composition Considerations: The composition of air in combustion calculations is frequently simplified to 78.1% nitrogen (N2) and 20.9% Oxygen (O2). Wet and dry basis compositions are used at times.
- Stack Gas (Flue Gas): The product gas leaving a combustion furnace.
- Theoretical Oxygen: The moles of oxygen (or molar flow rate) needed for complete combustion of the fuel.
- Theoretical Air: The quantity of air that contains the theoretical oxygen needed.
- Excess Air The amount by which the air fed to a reactor exceeds the theoretical air required.
- Percent Excess Air: The percent excess is calculated by comparing the air supplied to the hypothetical air needed.
Manufactured Solid Fuels
- Charcoal: A solid residue from the destructive distillation of wood.
- Coke: A solid residue from destructive distillation of coal, categorized as hard or soft.
- Briquettes: Compacted forms of dust, culm, slack, or other small-size waste from coal, peat, coke, etc.
- Bagasse: The residue of sugar cane after sugar extraction. It is fibrous and has a varying moisture content, calorific value as wood.
Hydrogen Energy
- Sources: Natural gas, oil, coal, and electrolysis. Fossil fuels are predominant for industrial hydrogen production.
- Steam Reforming (SMR): A method to produce hydrogen from methane or natural gas by reacting it with steam at high temperatures.
- Methane Pyrolysis: Process of thermal decomposition of methane into hydrogen and carbon.
- Plasma Reforming: A method to produce hydrogen and carbon black from hydrocarbons.
- Coal Gasification: A process that reacts coal with oxygen and steam at high pressure and temperature to create a synthesis gas, primarily carbon monoxide and hydrogen.
- Hydrogen from Water: Electrolysis using an electric current to split water into hydrogen and oxygen.
- Green Hydrogen: Hydrogen produced using renewable energy sources.
Hydrogen Storage
- Hydrogen Storage Methods: Gases (high pressure), liquids (cryogenic temperatures), and surfaces/solids (adsorption/absorption).
- Materials-Based Storage: Hydrides (hydrogen compounds with certain metals), liquid organic hydrogen carriers, and surface storage systems (sorbents). This category includes materials that absorb or chemically bond hydrogen.
- Combined Methods: Storage methods can be combined for improved energy density, such as cooled hydrogen compressed.
Biomass Energy
- Biomass: Organic materials from living things, including plants.
- Photosynthesis: The process plants use to store solar energy as chemical energy in biomass.
- Biogas: Gas produced through anaerobic digestion of organic matter by bacteria.
- Biogas Composition: Methane, carbon dioxide, and trace amounts of other gases.
- Biogas Utilization: Cooking fuel, electricity generation, and a replacement for fossil fuels.
- Sources of Biogas: Agricultural wastes, animal wastes, crop wastes, industrial food processing wastes, and municipal solid wastes.
Biodiesel
- Biodiesel Production: Derived from fats, oils, and other organic materials through a chemical process (transesterification).
- Materials: Soybean oil, recycled cooking oil, animal fats.
- Biodiesel Utilization: Used as a diesel fuel replacement.
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