Colorimetry Overview

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Questions and Answers

What is the primary purpose of using filters in a colorimetry experiment?

  • To select light radiation of a specific wavelength (correct)
  • To enhance the color of the solution
  • To increase the amount of light transmitted
  • To decrease the absorption of the solution

Which equation represents Beer-Lambert's law?

  • A = ν / λ
  • A = ε c t (correct)
  • A = I0 / It
  • A = λ c t

How is wave number defined in relation to wavelength?

  • It is directly proportional to wavelength
  • It is half the wavelength
  • It is the reciprocal of wavelength (correct)
  • It is the average wavelength in a spectrum

What does transmittance measure in a colorimetry experiment?

<p>The ratio of light transmitted to light absorbed (B)</p> Signup and view all the answers

Which of the following correctly defines colorimetry?

<p>A technique to determine the concentration by measuring absorbance (D)</p> Signup and view all the answers

In the context of colorimetry, what does the term 'wavelength' refer to?

<p>The distance between two successive peaks or troughs of waves (A)</p> Signup and view all the answers

What can be inferred if the intensity of transmitted light decreases as the concentration of the absorbing substance increases?

<p>The solution is absorbing light energy (B)</p> Signup and view all the answers

What instrument is primarily used to measure the absorbance of a colored solution in colorimetry?

<p>Photoelectric colorimeter (C)</p> Signup and view all the answers

Flashcards

Colorimetry

A method to figure out the amount of a substance in a solution by measuring how much light is absorbed by the solution.

What is a Photoelectric Colorimeter?

An instrument used to measure the amount of light absorbed by a colored solution using a light-sensitive cell.

Why are filters used in Colorimetry?

Filters are made of thin film or glass with a specific color. They are used to select light with a specific wavelength, making the measurement more precise.

What is wavelength?

The distance between any two successive peaks or troughs in a wave. It's represented by λ and measured in nanometers.

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What is wave number?

The reciprocal of wavelength, meaning 1 divided by the wavelength. It is represented by ν (nu).

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What is frequency?

The number of waves passing through a point in one second. It's represented by ν (nu).

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What is Beer's Law?

The amount of light that passes through a solution is related to the concentration of the substance absorbing the light. As concentration increases, the light passing through decreases.

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What is a Calibration Curve?

A graph showing the relationship between the amount of light absorbed (optical density) and the concentration of a substance in a solution.

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Study Notes

C-Structured Enquiry: Sensor(Colorimetry)

  • Colorimetry: A method for determining the amount of a substance by measuring the absorbance of a solution containing that substance.

  • Colorimeter: A device used in colorimetry to measure the amount of light absorbed by a colored solution. Specifically, a photoelectric colorimeter uses a photocell to measure light absorption.

  • Filters: Substances (thin film, gelatin, or colored glass) used in colorimetry to select specific wavelengths of light.

  • Wavelength: The distance between successive peaks or troughs of a wave. Measured in nanometers (nm).

  • Wave Number: The reciprocal of wavelength.

  • Frequency: The number of waves passing a point per second.

  • Beer's Law: The intensity of transmitted light decreases exponentially with increasing concentration of the absorbing substance.

  • Lambert's Law: The intensity of transmitted light decreases exponentially with increasing thickness of the absorbing medium.

  • Beer-Lambert Law: The absorbance of light is directly proportional to both the concentration of the absorbing substance and the path length of the light through the substance. Mathematically: A = e c t, where A = absorbance, e = molar extinction coefficient, c = concentration, and t = path length.

  • Calibration Curve: A graph plotting optical density (absorbance) against a series of solutions with known concentrations. This allows for determination of unknown concentrations.

  • Transmittance: The ratio of transmitted light (It) to the initial amount of light (I0).

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