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Questions and Answers
What is the formula to calculate Fixed Carbon?
What is the formula to calculate Fixed Carbon?
Which element is primarily responsible for the combustible properties of coal?
Which element is primarily responsible for the combustible properties of coal?
Which analysis provides a precise chemical composition of coal?
Which analysis provides a precise chemical composition of coal?
Which fuel is primarily used in internal combustion engines?
Which fuel is primarily used in internal combustion engines?
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At what temperature range is kerosene collected through fractional distillation?
At what temperature range is kerosene collected through fractional distillation?
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How is the nitrogen content of most coals typically characterized?
How is the nitrogen content of most coals typically characterized?
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What is the relationship between oxygen and carbon content in coal?
What is the relationship between oxygen and carbon content in coal?
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What is a common use of liquefied petroleum gas (LPG)?
What is a common use of liquefied petroleum gas (LPG)?
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Which rank of coal has a fixed carbon content of greater than 98%?
Which rank of coal has a fixed carbon content of greater than 98%?
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Which characteristic describes paraffin wax?
Which characteristic describes paraffin wax?
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What is bitumen also commonly known as?
What is bitumen also commonly known as?
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What does the proximate analysis of coal measure?
What does the proximate analysis of coal measure?
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What is the typical carbon content range for most coals classified as high volatile A?
What is the typical carbon content range for most coals classified as high volatile A?
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How are lubricating oils primarily manufactured?
How are lubricating oils primarily manufactured?
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Which of the following fuels is NOT typically used in portable stoves?
Which of the following fuels is NOT typically used in portable stoves?
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Which of the following is NOT a type of petrochemical?
Which of the following is NOT a type of petrochemical?
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What is a characteristic of petroleum that requires particular considerations for storage?
What is a characteristic of petroleum that requires particular considerations for storage?
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Which type of crude petroleum is mainly composed of saturated hydrocarbons?
Which type of crude petroleum is mainly composed of saturated hydrocarbons?
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What is the typical boiling point range for diesel fuel during its production?
What is the typical boiling point range for diesel fuel during its production?
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What is one of the main uses of asphalt refined from a colloid of asphaltenes and maltenes?
What is one of the main uses of asphalt refined from a colloid of asphaltenes and maltenes?
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Which component is typically produced from the heavier fractions of crude oil during fractional distillation?
Which component is typically produced from the heavier fractions of crude oil during fractional distillation?
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What is the role of the fractional distillation column in refining petroleum?
What is the role of the fractional distillation column in refining petroleum?
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What type of petroleum product is produced from light fractions at lower temperatures?
What type of petroleum product is produced from light fractions at lower temperatures?
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How is asphalt typically hardened after being separated from crude oil?
How is asphalt typically hardened after being separated from crude oil?
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What is the main constituent of natural gas?
What is the main constituent of natural gas?
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What is a significant disadvantage of using gaseous fuels?
What is a significant disadvantage of using gaseous fuels?
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Which characteristic describes the self-ignition temperature of natural gas?
Which characteristic describes the self-ignition temperature of natural gas?
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What process is used to separate methanol from heavier alcohols?
What process is used to separate methanol from heavier alcohols?
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Why is natural gas considered a cleaner fuel compared to other types of fuel?
Why is natural gas considered a cleaner fuel compared to other types of fuel?
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What is a characteristic of liquefied petroleum gas (LPG)?
What is a characteristic of liquefied petroleum gas (LPG)?
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What type of fuel is produced by heating coal in the absence of air?
What type of fuel is produced by heating coal in the absence of air?
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How does natural gas behave in terms of its physical properties?
How does natural gas behave in terms of its physical properties?
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What byproduct gas is produced during the reduction of iron ore by coke in a blast furnace?
What byproduct gas is produced during the reduction of iron ore by coke in a blast furnace?
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Which gas is primarily produced by passing steam and air through a bed of red-hot coal or coke?
Which gas is primarily produced by passing steam and air through a bed of red-hot coal or coke?
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What is the primary component of producer gas?
What is the primary component of producer gas?
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What process is responsible for the production of biogas?
What process is responsible for the production of biogas?
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What is the typical temperature range maintained in digesters for biogas production?
What is the typical temperature range maintained in digesters for biogas production?
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Which gaseous fuel is known for being obtained through low- and medium-temperature coal gasification?
Which gaseous fuel is known for being obtained through low- and medium-temperature coal gasification?
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Which gas is produced industrially by reforming natural gas in the presence of a nickel catalyst?
Which gas is produced industrially by reforming natural gas in the presence of a nickel catalyst?
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What does LHV stand for in terms of heating value for gaseous fuels?
What does LHV stand for in terms of heating value for gaseous fuels?
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Study Notes
Coal Properties
- Coal's heating value is reduced by the presence of moisture and ash.
- The formula to calculate Fixed Carbon: $FC = 100 - N - VCM - Ash$
- Comparing only the combustible part of coals requires knowing the heating value unaffected by moisture or ash.
- Values of fixed carbon, volatile matter, and calorific values are corrected to a moisture and ash-free basis for accurate comparison.
Coal Testing Analysis
- Proximate analysis determines the moisture, volatile combustible matter, fixed carbon, and ash content of coal. This analysis indicates the heating and burning properties of coal.
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Ultimate analysis identifies the chemical composition of coal with respect to elements like carbon, hydrogen, oxygen, nitrogen, sulfur, and ash.
- Carbon and hydrogen are the primary combustible elements in coal, with carbon being the predominant one.
- Nitrogen content is typically in the range of 1-2% for most coals.
- Oxygen content is inversely related to carbon content. Higher oxygen content makes coal easier to ignite.
- Sulfur content varies greatly among coals.
Coal Classification
- Coals are ranked into different classes and groups based on their properties, including fixed carbon, volatile matter, and heating value.
Petroleum
- Petroleum is a mineral oil found deep in the earth's crust and is mainly composed of hydrocarbons.
- An average crude oil can yield to 20 to 30% of gasoline, 30 to 45% of intermediate fractions, and 25 to 50% of residual fuel oil.
Petroleum Classification
- Paraffinic Base Type Crude Petroleum: Primarily composed of saturated hydrocarbons and small amounts of napthenes and aromatics.
- Asphaltic Base Type Crude Petroleum: Primarily contains cycloparaffins or napthenes with smaller amounts of paraffins and aromatic hydrocarbons.
- Mixed Base Type Crude Petroleum: Contains both paraffinic and asphaltic hydrocarbons and are generally rich in semisolid waxes.
Petroleum Products
- Asphalt: A colloid of asphaltenes and maltenes, commonly used in road construction. Separated from crude oil by fractional distillation and hardened through a process called "blowing."
- Diesel: Produced by fractional distillation and has a higher density than gasoline.
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Fuel Oil: Liquid petroleum product burned to generate heat. There are six classes of fuel oil:
- Distillate fuel oil
- Diesel fuel oil
- Light fuel oil
- Gasoil
- Residual fuel oil
- Heavy fuel oil
- Gasoline: A mixture of paraffins, naphthenes, and olefins, with ratios determined by the refinery.
- Kerosene: Collected through fractional distillation. It is a clear, combustible liquid used as jet fuel and heating fuel.
- Liquefied Petroleum Gas (LPG): A mixture of gases like propane and butane used for heating appliances, aerosol propellants, and refrigerants.
- Lubricating Oil: Manufactured through special processes for reducing friction and wear.
- Paraffin Wax: A white, odorless, tasteless solid at room temperature. It is an excellent electrical insulator and used in various applications, including candles and building insulation.
- Bitumen: A thick, black, sticky material used in paving roads, waterproofing, and soundproofing.
- Petrochemicals: Chemical products made from raw materials of petroleum.
- Ethanol: Obtained from the fermentation of sugars, followed by fractional distillation.
Gaseous Fuels
- Advantages of gaseous fuels:
- Easy transportation through pipelines.
- Eliminates manual labor in transportation.
- Light easily.
- Free from impurities found in solid and liquid fuels.
- Disadvantages of gaseous fuels:
- Requires large storage tanks.
- Highly inflammable, increasing fire hazards.
Natural Gas
- Often associated with petroleum deposits and obtained from wells dug in oil-bearing regions.
- Methane is the primary constituent, accounting for about 95% of its volume.
- Other components: Ethane, Propane, Butane, Pentane, Nitrogen, Carbon Dioxide, and traces of other gases.
Natural Gas Characteristics
- Formed millions of years ago from plant and animal remains.
- A hydrocarbon component with methane as the main component.
- Colorless and odorless, with a commercial odorant added for safety.
- Lighter than air and quickly disperses upward.
- Self-ignition temperature of about 537-540 degrees Celsius.
- Considered a clean fuel due to its cleaner burning nature and lower environmental impact compared to other fuels.
Liquefied Petroleum Gas (LPG)
- A byproduct of natural gas processing or crude oil refining.
- Primarily composed of propane but also contains varying amounts of butane, propylene, and butylenes.
Manufactured Gases
- Important manufactured gaseous fuels derived from solid and liquid fuels:
- Coal gas: Obtained from carbonizing coal and used in metallurgical operations for providing a reducing atmosphere.
- Blast furnace gas: Byproduct flue gas obtained during iron ore reduction.
- Water gas: A mixture of CO and H2, made by alternatively passing steam and air through a bed of red-hot coal or coke.
- Producer gas: A mixture of carbon monoxide and hydrogen with non-combustible gases like N2 and CO2.
- Biogas: Obtained from the decomposition of organic matter by bacterial action in closed digesters. It contains a significant percentage of CO2 and is a good fertilizer.
- Town gas: Low-temperature or lighting gas, obtained at low- and medium temperature coal gasification.
- Coke gas: Obtained at the high-temperature coal gasification.
- Hydrogen: Produced by reforming natural gas in the presence of a nickel catalyst.
Properties of Gaseous Fuels
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Heating Value: The heat release per unit mass when the fuel reacts completely with oxygen.
- Higher Heating Value (HHV): When water is condensed.
- Lower Heating Value (LHV): When water is not condensed.
- Formula to calculate LHV: $LHV = HHV - \frac{mh_{fg}}{m_{fuel}}$
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Description
This quiz covers essential concepts related to coal properties, including heating value, moisture, and ash effects. It also explores proximate and ultimate analyses, identifying the key components and burning characteristics of coal. Test your understanding of coal's chemical makeup and its implications on heating performance.