Classification of Types of Solids

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Questions and Answers

Which of the following characteristics would you expect for a solid with the formula P₄?

  • High electrical conductivity
  • Poor thermal conductivity (correct)
  • Low melting point (correct)
  • Very hard

Given an unknown substance with a melting point of 962 °C, insoluble in water, and conducts electricity as a solid, which of the following could be its identity? Check all that apply.

  • Zn
  • H₂O
  • Ag (correct)
  • NaCl

Given an unknown substance with a melting point of 872 °C, soluble in water, and does not conduct heat as a solid, which of the following could be its identity? Check all that apply.

  • ZnF₂ (correct)
  • H₂O
  • NaCl
  • Ag

Why do molecular solids differ greatly in their hardness and melting points?

<p>The molecules in molecular solids are held together by weak intermolecular interactions.</p> Signup and view all the answers

What kinds of attractive forces may exist between particles in molecular crystals?

<p>London dispersion forces (C)</p> Signup and view all the answers

What kinds of attractive forces exist between particles in covalent-network crystals?

<p>Covalent chemical bonds</p> Signup and view all the answers

What kinds of attractive forces exist between particles in ionic crystals?

<p>Electrostatic/Coulombic forces</p> Signup and view all the answers

What kinds of attractive forces exist between particles in metallic crystals?

<p>Metallic bonds</p> Signup and view all the answers

Indicate the type of crystal for CaCO₃.

<p>Ionic</p> Signup and view all the answers

Indicate the type of crystal for Pt.

<p>Metallic</p> Signup and view all the answers

Indicate the type of crystal for ZrO₂ (melting point, 2677°C).

<p>Ionic</p> Signup and view all the answers

Indicate the type of crystal for Table sugar (C₁₂H₂₂O₁₁).

<p>Molecular</p> Signup and view all the answers

Indicate the type of solid for benzoic acid, C₆H₅COOH.

<p>Molecular</p> Signup and view all the answers

Indicate the type of solid for I₂.

<p>Molecular</p> Signup and view all the answers

Which type of solid might a white substance be if it sublimes at 3000°C, is a nonconductor of electricity, and is insoluble in water?

<p>Covalent-network</p> Signup and view all the answers

Which type of solid might a substance be if it melts with some decomposition at 730 °C, is a nonconductor of electricity, but dissolves in water to form a conducting solution?

<p>Ionic</p> Signup and view all the answers

Is Si a molecular, metallic, ionic, or covalent-network solid?

<p>Si is a covalent-network solid.</p> Signup and view all the answers

Is SiO₂ most likely a molecular, metallic, ionic, or covalent-network solid?

<p>SiO₂ is a covalent-network solid.</p> Signup and view all the answers

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Study Notes

Classification of Types of Solids

  • P₄ is characterized by poor thermal conductivity and low melting point but not by high electrical conductivity or hardness.
  • A substance with a melting point of 962 °C, insoluble in water, that conducts electricity as a solid and is hard could possibly be silver (Ag).
  • A substance with a melting point of 872 °C, soluble in water, that does not conduct heat as a solid and is hard may be zinc fluoride (ZnF₂).
  • Hardness and melting point differences between types of solids are attributed to molecular interactions; molecular solids have weak intermolecular forces.

Types of Attractive Forces

  • Molecular crystals can exhibit:
    • London dispersion forces
    • Hydrogen bonding
    • Dipole-dipole forces
  • Covalent-network crystals are held together by covalent chemical bonds.
  • Ionic crystals feature electrostatic or coulombic forces between particles.
  • Metallic crystals have metallic bonds that hold their particles together.

Types of Crystals

  • Calcium carbonate (CaCO₃) is identified as an ionic crystal.
  • Platinum (Pt) is classified as a metallic crystal.
  • Zirconium dioxide (ZrO₂), with a melting point of 2677 °C, is an ionic crystal.
  • Table sugar (C₁₂H₂₂O₁₁) is categorized as a molecular crystal.
  • Benzoic acid (C₆H₅COOH) is also classified as a molecular solid.
  • Iodine (I₂) is recognized as a molecular crystal.

Special Cases

  • A white substance that sublimes at 3000 °C, is a nonconductor of electricity, and is insoluble in water is likely a covalent-network solid.
  • A white substance that melts with some decomposition at 730 °C, nonconductive in solid form but forms a conducting solution in water, suggests it is an ionic solid.
  • Silicon (Si) is classified as a covalent-network solid.
  • Silicon dioxide (SiO₂) is another example of a covalent-network solid, known for its hardness and insolubility in water.

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