Chitin Structure and Properties
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Chitin Structure and Properties

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Questions and Answers

What is the origin of the name 'chitin'?

  • Originates from the French word for 'covering' (correct)
  • Derived from a Latin term meaning 'shell'
  • Named after a novel protein in crustaceans
  • Based on an ancient Greek term for 'skin'
  • Which of the following organisms is NOT mentioned as having chitin?

  • Moss (correct)
  • Fungi
  • Mollusks
  • Arthropods
  • What is the primary structural feature that differentiates the allomorphs of chitin?

  • Type of organism producing it
  • Chemical composition
  • Degree of hydration (correct)
  • Color of the biopolymer
  • What is the most abundant allomorph of chitin?

    <p>Alpha chitin</p> Signup and view all the answers

    How does the chitin content in cockroaches compare to that in grasshoppers?

    <p>Higher in cockroaches than in grasshoppers</p> Signup and view all the answers

    In which structure is chitin NOT primarily found?

    <p>Hair of mammals</p> Signup and view all the answers

    What percentage of chitin content is commonly found in the dry weight of crustacean shells?

    <p>15% to 30%</p> Signup and view all the answers

    Which scientist first extracted chitin from fungus, referring to it as 'fungine'?

    <p>Henri Braconnot</p> Signup and view all the answers

    Which characteristic primarily differentiates the allomorphs of chitin?

    <p>Orientation of microfibrils and unit cell size</p> Signup and view all the answers

    What is the significance of chitin's abundance in nature?

    <p>It is the second most abundant natural biopolymer, influencing ecological systems.</p> Signup and view all the answers

    How does the degree of hydration relate to the stability of chitin's allomorphs?

    <p>Decreased hydration can increase the stability of certain allomorphs.</p> Signup and view all the answers

    Which of the following roles does chitin primarily serve in organisms?

    <p>Structural support in cell walls and exoskeletons</p> Signup and view all the answers

    In which organism is the chitin content typically the highest, based on the data provided?

    <p>Cockroaches</p> Signup and view all the answers

    What is the primary chemical transformation that produces chitosan from chitin?

    <p>Deacetylation of chitin</p> Signup and view all the answers

    Which of the following statements about chitin is correct?

    <p>Chitin is found in various organisms, influencing structural integrity.</p> Signup and view all the answers

    What major characteristic differentiates a-chitin from other allomorphs?

    <p>Higher thermal degradation temperature</p> Signup and view all the answers

    What distinguishes the three allomorphs of chitin?

    <p>Differences in hydration levels and microfibril orientation</p> Signup and view all the answers

    Which statement accurately reflects the thermal stability of a-chitin?

    <p>It is the most stable allomorph of chitin</p> Signup and view all the answers

    What is the role of chitin in the structure of fungi?

    <p>It functions as a structural component in the fungal cell wall</p> Signup and view all the answers

    In terms of chitin content by dry weight, how does the chitin in house crickets compare to that in grasshoppers?

    <p>Grasshoppers typically have a higher chitin content than house crickets</p> Signup and view all the answers

    What is the significance of chitin being the second most abundant natural biopolymer?

    <p>It highlights its potential for diverse applications in industries</p> Signup and view all the answers

    What provides the distinct characteristic of chitin being classified as a mucopolysaccharide?

    <p>The presence of amino sugar units in its polymer chain</p> Signup and view all the answers

    Which of the following properties is a function of the crystalline microfibrils of chitin in nature?

    <p>They provide structural support and resistance against physical damage</p> Signup and view all the answers

    What distinguishes the content of chitin in insect cuticles from that in crustacean shells?

    <p>Crustacean shells generally have a lower chitin percentage by dry weight</p> Signup and view all the answers

    What factor primarily contributes to the high thermodynamical stability of a-chitin?

    <p>Crystallinity of the microfibrils</p> Signup and view all the answers

    In which of the following organisms is chitin found as a key structural component, based on its role?

    <p>Mollusk shells</p> Signup and view all the answers

    What is the primary reason chitin is considered the second most abundant biopolymer in nature?

    <p>Its presence in various natural organisms</p> Signup and view all the answers

    Which characteristic is common to all allomorphs of chitin?

    <p>Presence of crystalline microfibrils</p> Signup and view all the answers

    Which aspect primarily differentiates the three allomorphs of chitin?

    <p>Molecular arrangement and stability</p> Signup and view all the answers

    What is the relationship between chitin and chitosan in terms of chemical modification?

    <p>Chitosan is a N-deacetylated form of chitin</p> Signup and view all the answers

    Which of the following statements about the discovery of chitin is true?

    <p>Auguste Odier discovered chitin in 1823.</p> Signup and view all the answers

    Which statement regarding chitin's distribution is accurate?

    <p>Chitin is abundant in various marine and terrestrial species.</p> Signup and view all the answers

    Study Notes

    Chitin Structure and Properties

    • Chitin is a naturally occurring mucopolysaccharide, extracted from fungi by Henri Braconnot in 1811 and called “fungine”.
    • In 1823, Auguste Odier found the same material in insects and called it chitin from the Greek word “chiton” meaning “covering”.
    • Chitin is the second most abundant natural biopolymer after cellulose.
    • Chitin is found in the exoskeletons of arthropods, cell walls of fungi and yeast, teeth of the radula, and shells of mollusks.
    • There are three allomorphs of chitin: a, b, and g, differentiated by hydration, unit cell size and orientation.
    • a-chitin is the most abundant and has high thermodynamical stability.
    • Chitin content in dry weight is: 15%e30% in crustacean shells, 4%e11% in grasshoppers, 1%e2% in house crickets, 38% in cockroaches, 10%e30% in filamentous fungal cell walls, and 1e2% in yeast cell walls.

    Chitin: Structure and Properties

    • Chitin is a naturally occurring mucopolysaccharide found in various organisms.
    • It was first discovered in 1811 by Henri Braconnot as "fungine" in mushroom cell walls.
    • Identified in 1823 by Auguste Odier in insect cuticles.
    • Chitin is the second most abundant natural biopolymer after cellulose.
    • Found in the outer layers of crustaceans, insects, fungi, and fish.
    • Occurs as crystalline microfibrils in the exoskeleton of arthropods.
    • Its significant constituent in the cell walls of fungi and yeast.
    • Present in the teeth of radula, calcified layers of mollusk shells, and pen of squids.
    • Chitin content varies based on the organism, with crustacean shells containing 15-30% by dry weight.
    • Three allomorphs of chitin: α, β, and γ.
    • Allomorphs differ by hydration degree, size of unit cell, number of chains per unit cell, and orientation of microfibrils.
    • α-chitin is the most abundant allomorph, exhibiting high thermodynamical stability.

    Chitin

    • Chitin is a natural mucopolysaccharide.
    • Discovered in 1811 by Henri Braconnot, originally named "fungine".
    • Auguste Odier later renamed it "chitin" in 1823.
    • Found in outer layers of organisms like crustaceans, insects, fungi, and fish.
    • Second most abundant natural biopolymer after cellulose.
    • Exists as crystalline microfibrils.
    • Found in structural components of exoskeletons in arthropods, cell walls in fungi and yeast, teeth of radula, calcified layers of mollusk shells, and gladii (pen) of squids.
    • Chitin content varies by dry weight:
      • Crustacean shells: 15% - 30%
      • Grasshoppers: 4% - 11%
      • House crickets: 1% - 2%
      • Cockroaches: ~38%
      • Filamentous fungal cell wall: 10% - 30%
      • Yeast cell wall: 1% - 2%
    • Three allomorphs of chitin: α, β, and γ.
    • Degree of hydration, size of unit cell, number of chains per unit cell, and orientation of microfibrils differentiate the chitin allomorphs.
    • α-chitin is the most abundant and thermodynamically stable.

    Chitin

    • Chitin is a naturally occurring mucopolysaccharide.
    • Chitin was first discovered by Henri Braconnot in 1811.
    • Chitin was called "fungine" before its name was changed by Auguste Odier in 1823.
    • Chitin is found in the exoskeletons of crustaceans, insects and other organisms including fungi.
    • Chitin is the second most abundant natural biopolymer.
    • Chitin can be found in the form of crystalline microfibrils.
    • Three allomorphs of chitin exist: a, b, and g.
    • a-chitin is the most abundant allomorph and is thermodynamically stable.

    Chitin Content by Dry Weight

    • Crustacean Shells: 15% - 30%
    • Grasshoppers: 4% - 11%
    • House Crickets: 1% - 2%
    • Cockroaches: 38%
    • Filamentous Fungal Cell Wall: 10% - 30%
    • Yeast Cell Wall: 1% - 2%

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    Description

    Explore the fascinating world of chitin, a vital biopolymer found in various organisms. Learn about its discovery, structural allomorphs, and significance in nature. This quiz covers the properties, occurrences, and percentage content of chitin across different species.

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