Chemistry Unit IV-VI Quiz
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Questions and Answers

What is the expected electron configuration for Copper (Cu)?

  • [Ar] 4s13d10
  • [Ar] 4s23d9 (correct)
  • [Ar] 4s24d9
  • [Ar] 4s23d8

What does Hund's Rule state?

  • Electrons occupy orbitals in pairs before any orbital is singly occupied.
  • Every orbital is singly occupied before any orbital gets doubly occupied. (correct)
  • All orbitals of the same energy must have one electron before any can have two.
  • Electrons fill the lowest available energy levels first.

Electromagnetic waves are classified only based on their energy levels.

False (B)

What happens to an electron when it absorbs light?

<p>It becomes excited and jumps to a higher energy level.</p> Signup and view all the answers

The distance between two successive peaks of a wave is known as its ______.

<p>wavelength</p> Signup and view all the answers

What is the electron configuration for sodium using the shorthand method?

<p>[Ne] 3s1</p> Signup and view all the answers

The shorthand electron configuration can be used for period 1 elements.

<p>False (B)</p> Signup and view all the answers

Elements in family 7A typically gain 1 electron to achieve stability.

<p>True (A)</p> Signup and view all the answers

An element must attain _____ valence electrons to be stable per the octet rule.

<p>8</p> Signup and view all the answers

Which of the following elements follows the duplet rule instead of the octet rule?

<p>Helium (D)</p> Signup and view all the answers

Match the family of elements with their valence electron count:

<p>1A = 1 2A = 2 6A = 6 8A = 8</p> Signup and view all the answers

Match the following types of electromagnetic radiation with their characteristics:

<p>Gamma-ray = Highest frequency and energy Radio waves = Lowest frequency and energy Visible Light = Colors range from violet to red X-ray = Used for medical imaging</p> Signup and view all the answers

When an atom loses an electron, it gains a _____ charge.

<p>positive</p> Signup and view all the answers

How many periods are there in the periodic table?

<p>7 (B)</p> Signup and view all the answers

Family A consists only of transition metals.

<p>False (B)</p> Signup and view all the answers

What is the maximum number of electrons that can occupy an 's' orbital?

<p>2</p> Signup and view all the answers

The ______ state occurs when all energy levels in an atom are full.

<p>ground</p> Signup and view all the answers

Match the following types of orbitals with their maximum electron capacity:

<p>s = 2 electrons p = 6 electrons d = 10 electrons f = 14 electrons</p> Signup and view all the answers

Which group is known as the Noble Gases?

<p>8A (B)</p> Signup and view all the answers

According to the Pauli exclusion principle, two electrons in the same orbital must have the same spin.

<p>False (B)</p> Signup and view all the answers

What principle states that electrons fill the lowest available energy subshells first?

<p>Aufbau principle</p> Signup and view all the answers

What is the electron configuration of Yttrium (39)?

<p>1s22s22p63s23p64s2 3d10 4p6 5s2 4d1 (B)</p> Signup and view all the answers

Yttrium belongs to Group 2B.

<p>False (B)</p> Signup and view all the answers

How many valence electrons does Yttrium have?

<p>3</p> Signup and view all the answers

Yttrium is located in Period __.

<p>5</p> Signup and view all the answers

What is the number of d-orbital electrons in Yttrium?

<p>1 (B)</p> Signup and view all the answers

Match the following properties to their values for Yttrium:

<p>Electron configuration = 1s22s22p63s23p64s2 3d10 4p6 5s2 4d1 Group = 3B Valence electrons = 3 Period = 5</p> Signup and view all the answers

The energy level of Yttrium is determined by its group number.

<p>False (B)</p> Signup and view all the answers

What is the rule to find the Group number for Yttrium?

<p>Add 2 to the number of d-orbital electrons.</p> Signup and view all the answers

Which element has the largest atomic radius?

<p>Francium (B)</p> Signup and view all the answers

The ionic size increases from left to right across a period.

<p>False (B)</p> Signup and view all the answers

Define ionization energy.

<p>The energy needed to remove an electron from an atom.</p> Signup and view all the answers

The distance from the nucleus of a neutral atom to the outermost shell is called the atomic __________.

<p>radius</p> Signup and view all the answers

Match the following ions with their expected size relationship:

<p>Na+ = Smaller than Na Mg2+ = Smaller than Na+ Cl- = Bigger than Na+ Fe2+ = Smaller than Fe</p> Signup and view all the answers

What happens to atomic radius as you move from top to bottom in a group?

<p>It increases. (B)</p> Signup and view all the answers

Anions are always larger than their corresponding neutral atoms.

<p>False (B)</p> Signup and view all the answers

When an atom loses electrons, its ionic size __________.

<p>decreases</p> Signup and view all the answers

Which of the following statements is correct regarding nonmetals?

<p>Nonmetals are good insulators. (D)</p> Signup and view all the answers

The atomic size increases from left to right across the periodic table.

<p>False (B)</p> Signup and view all the answers

What is the charge of a nitride ion?

<p>-3</p> Signup and view all the answers

The formula for sulfate ion is ______.

<p>SO4^2-</p> Signup and view all the answers

Match the following ions with their corresponding formulas:

<p>Ammonium = NH4+ Phosphate = PO4^3- Sulfite = SO3^2- Chloride = Cl-</p> Signup and view all the answers

Which element has the highest electronegativity?

<p>Fluorine (C)</p> Signup and view all the answers

The ionization energy increases as you move down a group in the periodic table.

<p>False (B)</p> Signup and view all the answers

What type of compound is formed when a cation pairs with an anion?

<p>Ionic compound</p> Signup and view all the answers

A binary ionic compound is composed of ______ elements.

<p>two</p> Signup and view all the answers

Which property of metals increases from top to bottom in the periodic table?

<p>Metallic properties (C)</p> Signup and view all the answers

What is the possible range of values for the electron spin quantum number (ms)?

<p>+½, -½ (A)</p> Signup and view all the answers

An electron with a spin quantum number of -½ is said to be spinning in a clockwise direction.

<p>False (B)</p> Signup and view all the answers

What does a positive value of the electron spin quantum number (ms) indicate about the electron's spin?

<p>upward spin</p> Signup and view all the answers

The periodic law states that the physical and chemical properties of an element tend to vary periodically in order of increasing _______.

<p>atomic number</p> Signup and view all the answers

Match the following electron configurations with their corresponding electron spin states:

<p>3s1 = +½ 3p4 = -½ 4d5 = +½ 3p3 = +½</p> Signup and view all the answers

Which scientist is known as the Father of the Periodic Table?

<p>Dmitri Mendeleev (D)</p> Signup and view all the answers

Henry Moseley arranged elements by their atomic mass.

<p>False (B)</p> Signup and view all the answers

What did John Newlands contribute to the development of the periodic table?

<p>Law of Octaves</p> Signup and view all the answers

The average of the atomic masses of the first and third elements in Döbereiner's triads is equal to the atomic mass of the ______ element.

<p>second</p> Signup and view all the answers

Match each scientist with their contribution to the periodic table:

<p>Johann Wolfgang Döbereiner = Law of Triads John Newlands = Law of Octaves Dmitri Mendeleev = First Periodic Table Henry Moseley = Periodic Table Law</p> Signup and view all the answers

What major change did Moseley make to the arrangement of the periodic table?

<p>Arranged by atomic number (C)</p> Signup and view all the answers

Döbereiner’s Law of Triads is based on the atomic number of elements.

<p>False (B)</p> Signup and view all the answers

The periodic table is a tabular arrangement of chemical elements organized according to increasing ______.

<p>atomic number</p> Signup and view all the answers

Which electron configuration corresponds to the element with 8 valence electrons in Group 8A and Period 2?

<p>1s2 2s2 2p6 (A)</p> Signup and view all the answers

The maximum number of electrons that can occupy a p orbital is 8.

<p>False (B)</p> Signup and view all the answers

Identify the element that has the electron configuration 1s2 2s2 2p6.

<p>Neon</p> Signup and view all the answers

In period 2, family 8A, the total number of electrons is _____.

<p>10</p> Signup and view all the answers

Match the following elements with their corresponding group and period:

<p>Magnesium = 2A, 3 Hydrogen = 1, 1 Neon = 8A, 2 Oxygen = 6A, 2</p> Signup and view all the answers

What happens to ionization energy as you move from left to right across a period?

<p>It increases (C)</p> Signup and view all the answers

Electron affinity increases from top to bottom in a group.

<p>False (B)</p> Signup and view all the answers

What is electronegativity?

<p>The ability of an atom to attract electrons and gain a negative charge.</p> Signup and view all the answers

Ionization energy is opposite the atomic _____

<p>radius</p> Signup and view all the answers

Match the following trends with their descriptions:

<p>Ionization Energy = Increases from left to right Electron Affinity = Increases from left to right Electronegativity = Increases from left to right Atomic Radius = Decreases from left to right</p> Signup and view all the answers

Which of the following statements about ionization energy is correct?

<p>It requires more energy to remove an electron from an atom with 8 valence electrons. (D)</p> Signup and view all the answers

Higher electronegativity means an atom is more likely to lose electrons.

<p>False (B)</p> Signup and view all the answers

Explain why it is easier for atoms on the left side of the periodic table to lose electrons.

<p>Atoms on the left have fewer valence electrons and less nuclear attraction, making it easier to lose them.</p> Signup and view all the answers

The Aufbau principle states that electrons fill the highest energy subshells first.

<p>False (B)</p> Signup and view all the answers

How many groups (families) are present in the periodic table?

<p>18</p> Signup and view all the answers

The group of elements known as ______ gases is found in family 8A.

<p>noble</p> Signup and view all the answers

Match the following groups of elements with their corresponding names:

<p>1A = Alkali Metals 2A = Alkaline Earth Metals 7A = Halogens 8A = Noble Gases</p> Signup and view all the answers

Which of the following best describes an excited state of an atom?

<p>Electrons jump to higher energy levels (B)</p> Signup and view all the answers

Which principle states that a maximum of two electrons may occupy an orbital if they have opposite spins?

<p>Pauli exclusion principle</p> Signup and view all the answers

What is the primary factor that determines the charge of an element in family 1A?

<p>The ease of losing one electron (A)</p> Signup and view all the answers

The valence electrons for noble gases like neon are considered when determining their stability.

<p>True (A)</p> Signup and view all the answers

For an atom to be stable, it must follow the octet rule, which states that an element must attain _____ valence electrons.

<p>8</p> Signup and view all the answers

Match the elements to their corresponding group number based on valence electrons:

<p>Hydrogen = 1A Beryllium = 2A Aluminum = 3A Oxygen = 6A</p> Signup and view all the answers

According to Hund’s Rule, how should electrons be filled in the orbitals?

<p>Each orbital must have one electron before any has two (B)</p> Signup and view all the answers

The electron configuration 1s22s22p6 is equivalent to the configuration of Argon.

<p>True (A)</p> Signup and view all the answers

In family 6A, the charge of elements is typically _____ when they attain stability.

<p>-2</p> Signup and view all the answers

Flashcards

Periodic Table Periods

Horizontal rows in the periodic table; there are 7 periods.

Periodic Table Groups/Families

Vertical columns in the periodic table, consisting of representative elements (A) and transition metals (B); total of 18.

Electron Configuration

Arrangement of electrons in atomic orbitals; the most stable state is the ground state.

Atomic Orbital

Region around the nucleus where an electron is likely to be found.

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Ground State

The most stable state of an atom, with all energy levels filled.

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Aufbau Principle

Electrons fill lower energy levels first before higher energy levels.

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Pauli Exclusion Principle

A maximum of 2 electrons can occupy an orbital, and they must have opposite spins.

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Electron Spin

Property of electrons; electrons in the same orbital must have opposite spins to avoid repulsion.

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Electromagnetic Spectrum

The full range of electromagnetic radiation categorized by frequency and wavelength.

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Frequency (EM)

The rate at which a wave completes a cycle.

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Wavelength (EM)

Distance between two successive wave peaks.

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Ground State (Electron)

The most stable energy level of an electron.

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Excited State (Electron)

A temporary higher energy level of an electron.

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Hund's Rule

Each orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied, with all electrons having the same spin.

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Shorthand electron configuration

A method used to represent electron configurations in elements, using the noble gas configuration preceding the element as a short-hand.

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Valence Electrons

Electrons in the outermost energy level of an atom, determining chemical properties and reactivity.

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Octet Rule

Atoms tend to gain, lose or share electrons to achieve a full outer shell (8 electrons) of valence electrons, becoming stable.

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Representative elements

Elements in groups (families) 1A through 7A of the periodic table.

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Valence electron family number

The group number for representative elements corresponds to the number of valence electrons in their atoms.

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Stable configuration

A configuration of atoms having a complete outer electron shell (octet or duplet for certain elements) making them unreactive.

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Electron Configuration Filling Order

A specific sequence for filling atomic orbitals with electrons following the Aufbau principle.

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Electron Configuration of Neon (Ne)

The arrangement of electrons in the different energy levels and sublevels of a neon atom. In this case, 1s22s22p6

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Group of Neon (Ne)

Neon is in group 8A

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Valence Electrons of Neon (Ne)

The number of electrons in the outermost energy level of a Neon atom. In this case, Neon has 8 valence electrons.

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Period of Yttrium (Y)

Yttrium is in period 5, corresponding to its highest energy level.

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Group Determination of Yttrium (Y)

Identify the number of electrons in the 'd' orbital, then add 2 to determine the group number.

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Valence Electrons of Yttrium (Y)

Sum of electrons in the 's' and 'd' orbitals of the outermost energy levels. For Y, it is 3.

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Energy Level of Yttrium (Y)

Yttrium's highest energy level, which is also its period number.

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Electron Configuration for Yttrium (Y)

The arrangement of electrons in Yttrium's energy levels and sublevels.

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Metallic Property

Characteristics of metals, including large atomic size, low ionization energy, low electron affinity, low electronegativity, and good conductivity.

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Nonmetallic Property

Characteristics of nonmetals, including small atomic size, high ionization energy, high electron affinity, high electronegativity, and poor conductivity.

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Trend: Atomic Size in Periodic Table

Atomic size increases from top to bottom within a group and decreases from left to right across a period.

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Trend: Ionization Energy in Periodic Table

Ionization energy increases from left to right across a period and decreases from top to bottom within a group.

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Trend: Electron Affinity in Periodic Table

Electron affinity generally increases from left to right across a period and decreases from top to bottom within a group.

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Trend: Electronegativity in Periodic Table

Electronegativity increases from left to right across a period and decreases from top to bottom within a group.

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Monatomic Ions

Ions formed from single atoms, with a positive or negative charge depending on the loss or gain of electrons.

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Polyatomic Ions

Ions formed from a group of atoms covalently bonded together, carrying a net positive or negative charge.

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Atomic Radius

The distance from the nucleus of a neutral atom to its outermost electron shell.

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Atomic Radius Trend: Downward

Atomic radius increases as you move down a group in the periodic table. This is because atoms in higher periods have more electron shells, causing the outermost electrons to be farther from the nucleus.

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Atomic Radius Trend: Rightward

Atomic radius decreases as you move across a period in the periodic table. This is due to an increase in nuclear charge (more protons) attracting electrons closer to the nucleus.

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Ionic Radius

The distance from the nucleus of an ion to its outermost electron shell.

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Cation vs. Anion

A cation is a positively charged ion formed by the loss of electrons. An anion is a negatively charged ion formed by the gain of electrons.

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Ionic Radius Trend: Downward and Rightward

Ionic radius increases down a group and decreases across a period, similar to atomic radius.

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Ionization Energy

The energy required to remove one electron from a neutral atom in its gaseous state.

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Ionization Energy Trend: Rightward

Ionization energy increases as you move across a period. This is because the attraction between the nucleus and electrons increases, making it harder to remove an electron.

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Periodic Table

A tabular arrangement of chemical elements organized by increasing atomic number, showcasing their properties and relationships.

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Döbereiner's Triads

Grouping elements into sets of three with similar properties, where the middle element's atomic mass is roughly the average of the other two.

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Newlands' Law of Octaves

Every eighth element shares similar properties when arranged by increasing atomic mass, but only true for elements up to Calcium.

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Mendeleev's Periodic Table

The first periodic table, arranging elements by increasing atomic mass, leaving gaps for undiscovered elements.

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Moseley's Periodic Table

The modern periodic table, based on increasing atomic number, explaining the true order of elements.

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Period

A horizontal row in the periodic table that indicates the highest energy level occupied by electrons in the atoms of elements within that row.

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Group

A vertical column in the periodic table that contains elements with similar chemical properties due to the same number of valence electrons.

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How to determine the electron configuration of an element using Group and Period

  1. Identify the energy level using the period number. 2. Determine the total number of valence electrons using the group number. 3. Fill the orbitals in each energy level starting from the lowest energy level, following the Aufbau principle.
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What are periods in the periodic table?

Periods are the horizontal rows on the periodic table. There are 7 periods, each representing a different energy level of the atom.

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What are groups in the periodic table?

Groups, also called families, are the vertical columns on the periodic table. Elements in the same group have the same number of valence electrons and often share similar chemical properties.

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What is the difference between groups A and B?

Group A, also called representative elements, includes elements from groups 1A through 8A. Group B includes transition metals.

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What are valence electrons?

Valence electrons are the electrons in the outermost energy level of an atom. They are the ones involved in chemical bonding.

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What is electron configuration?

Electron configuration describes the arrangement of electrons in an atom's energy levels and sublevels.

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What is the Aufbau principle?

The Aufbau principle states that electrons fill the lowest energy levels first before moving to higher energy levels.

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What is the Pauli Exclusion Principle?

The Pauli Exclusion Principle states that only two electrons can occupy an orbital, and they must have opposite spins.

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What is Hund's Rule?

Hund's Rule states that each orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied, with all electrons having the same spin.

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Electron Spin Quantum Number (ms)

Describes the direction of an electron's spin, either clockwise (+1/2) or counter-clockwise (-1/2).

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What does +1/2 ms value represent?

An electron spinning in an upward direction, visualized as upwards.

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Atomic Size Trend: Rightward

Atomic size decreases as you move across a period in the periodic table. This is due to an increase in nuclear charge (more protons) attracting electrons closer to the nucleus.

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Ionization Energy Trend: Across a Period

Ionization energy, the energy needed to remove an electron, increases as you move from left to right across a period in the periodic table. This happens because the attraction between the nucleus and electrons gets stronger, making it harder to pull an electron away.

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Ionization Energy Trend: Down a Group

Ionization energy decreases as you move down a group in the periodic table. This happens because the outermost electrons are farther from the nucleus and experience less attraction.

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Electron Affinity Trend: Across a Period

Electron affinity, the energy released when an atom gains an electron, generally increases as you move from left to right across a period. Atoms on the right side are closer to having a full outer shell (like a noble gas), so they are more likely to attract an electron.

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Electron Affinity Trend: Down a Group

Electron affinity generally decreases as you move down a group in the periodic table. The outermost energy levels become farther from the nucleus, resulting in a weaker attraction for an incoming electron.

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Electronegativity Trend: Across a Period

Electronegativity, an atom's ability to attract electrons in a bond, increases as you move from left to right across a period. Atoms on the right side are closer to having a full outer shell, making them more likely to attract electrons.

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Electronegativity Trend: Down a Group

Electronegativity decreases as you move down a group in the periodic table. The outermost electrons are farther from the nucleus and experience weaker attraction, reducing the ability to attract electrons in bonds.

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What is Electron Affinity?

Electron affinity is the energy change that occurs when an atom gains an electron in its gaseous state to form a negative ion (anion). It's a measure of how much an atom 'wants' to gain an electron.

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What is Electronegativity?

Electronegativity is an atom's ability to attract electrons towards itself in a chemical bond. It determines how strongly an atom can pull shared electrons in a covalent bond.

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Study Notes

Chemistry Study Notes

  • Q1 9-CONCHEM: This likely refers to a specific unit or chapter in a Chemistry course, within the first quarter
  • Q2 9-CONCHEM: Similar to Q1, this likely refers to a chemistry unit or chapter in the second quarter of the semester
  • UNIT IV: Order Among Elements: This unit covers the development and organization of the periodic table, including chemical symbols, electron configuration, group numbers, valence electrons, and trends in the periodic table
  • UNIT V: Stoichiometry: This unit discusses calculations related to chemical reactions, including chemical formulas, mole concept, molar mass, percentage composition, empirical and molecular formulas, balancing chemical equations, types of chemical reactions, and calculations based on balanced equations
  • UNIT VI: Chemical Bond: This section covers types of chemical bonds (ionic, covalent, metallic), octet rule, Lewis symbols, bond polarity, electronegativity, molecular geometry and intermolecular forces
  • 4.1-3 The Periodic Table: This section of the notes explains how the periodic table is organized and arranged and includes the historical development of the periodic table
  • 1817: Johann Wolfgang Döbereiner's Law of Triads: Döbereiner grouped elements into sets of three exhibiting similar properties. The average of the atomic mass of the first and third element approximates the second element's atomic weight
  • 1865: John Newlands's Law of Octaves: Newlands arranged elements based on increasing atomic mass. Elements with similar properties recurred every eighth element (like an octave in music) (applicable to elements before Calcium).
  • 1869: Dmitri Mendeleev's Periodic Table: Mendeleev's table organized by increasing atomic number. It contained spaces for undiscovered elements
  • 1913: Henry Moseley's Periodic Table: This modern periodic table is organized by atomic number, not atomic mass, leading to a more accurate arrangement.
  • 4.4 Electron Configuration: Explains the distribution of electrons in atomic orbitals, including ground and excited states, and the principles of Aufbau, Hund's rule, and Pauli exclusion to determine the electron configuration
  • 4.5 Valence Electrons and Blocks: This explains valence electrons (electrons in the outermost shell), the octet rule, how to relate valence electrons to the group number, and how they are organized in blocks in the periodic table
  • 4.6 Electromagnetic Radiation and Quantum Numbers: This section covers the structure and properties of electromagnetic waves, the full electromagnetic spectrum, and relationships among energy, wavelength, frequency to understand quantum behavior and properties
  • 4.7 Periodic Trends: This unit addresses how atomic properties like atomic size, ionization energy, electron affinity, electronegativity, metallic, and non-metallic properties change across a period and down a group.
  • UNIT V: Stoichiometry - Monatomic lons: Provides a table for monatomic ions and their charges (e.g. Li+, Na+, Mg2+, Al3+, etc.)
  • UNIT V: Stoichiometry - Polyatomic Ions: Provides a table for polyatomic ions and their formulas (e.g. nitrate, sulfate, phosphate, hydroxide, carbonate, etc.)
  • 5.1 Naming and Writing lonic Formulas: Explains the naming and writing of formulas for ionic compounds. Discusses the relationship between the charge of ions and the formulas of ionic compounds.
  • 5.3 Balancing Chemical Equations: Explains chemical equations, how to balance chemical equations by adjusting coefficients to maintain the law of conservation of mass (the number of atoms of each element must be the same on both sides of the equation).
  • Q3 9-CONCHEM, Q4 9-CONCHEM: These denote third and fourth quarter units or chapters in the 9-CONCHEM course, respectively.

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