Chemistry: The Octet Rule and Bonding

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Questions and Answers

What is the octet rule?

  • Atoms seek to have eight valence electrons to achieve stability. (correct)
  • Atoms can only share electrons with other atoms.
  • Atoms always lose all their electrons.
  • All atoms have the same number of valence electrons.

How do ionic bonds typically form?

  • By the sharing of electrons between nonmetals.
  • Through the transfer of valence electrons from metals to nonmetals. (correct)
  • By the loss of protons from an atom.
  • By the gain of neutrons in an atom.

What happens to atoms when they form positively charged ions?

  • They gain electrons.
  • They increase their number of protons.
  • They share their electrons with other atoms.
  • They lose electrons. (correct)

Which statement about covalent bonds is correct?

<p>Covalent bonds occur when nonmetal atoms share electrons. (D)</p> Signup and view all the answers

Which gas has a stable configuration with only 2 valence electrons?

<p>Helium (D)</p> Signup and view all the answers

What is the name of the compound CaO?

<p>calcium oxide (A)</p> Signup and view all the answers

Which of the following correctly identifies the anion in Al2O3?

<p>oxide (A)</p> Signup and view all the answers

What is the ionic charge of magnesium in MgCl2?

<p>+2 (A)</p> Signup and view all the answers

How are transition metals with variable charge named?

<p>by using Roman numerals for ionic charge (A)</p> Signup and view all the answers

What is the correct name for Cu2+?

<p>copper(II) (A)</p> Signup and view all the answers

What is the correct formula for the ionic compound formed from Na+ and O2−?

<p>Na2O (A)</p> Signup and view all the answers

What is the total charge of the ions in MnF2 when accounting for charge balance?

<p>0 (D)</p> Signup and view all the answers

In the compound formed by Al3+ and Cl−, what is the correct formula?

<p>AlCl3 (C)</p> Signup and view all the answers

For the ionic compound Mg2+ and N3−, which formula is correct?

<p>Mg3N2 (B)</p> Signup and view all the answers

Which transition metal forms only one type of ion?

<p>zinc (A)</p> Signup and view all the answers

What is the correct name of the anion Cl−?

<p>chloride (B)</p> Signup and view all the answers

How many chloride ions are needed to balance one barium ion in Ba2+ and Cl−?

<p>2 (C)</p> Signup and view all the answers

Which of the following is true about the charge balance in MgCl2?

<p>One magnesium ion balances with two chloride ions. (A)</p> Signup and view all the answers

What are the charges of the ions in the compound Na2S?

<p>Na+ and S2− (B)</p> Signup and view all the answers

How does a cation differ from a neutral atom?

<p>A cation has more protons than electrons. (C)</p> Signup and view all the answers

What is the correct method to derive the formula for sodium nitride from Na+ and N3−?

<p>Na3N (A)</p> Signup and view all the answers

What is the electron configuration of a sodium ion (Na+)?

<p>11 protons and 10 electrons (B)</p> Signup and view all the answers

Why do metals tend to form positive ions?

<p>They lose valence electrons to achieve electron configuration of the nearest noble gas. (B)</p> Signup and view all the answers

When writing the ionic formula for a compound with barium ions and chloride ions, what relationship must be established for charge balance?

<p>One Ba ion requires two Cl ions. (D)</p> Signup and view all the answers

What is a characteristic of an anion?

<p>It has more electrons than protons. (B)</p> Signup and view all the answers

Which group of metals forms a cation with a charge of 2+?

<p>Group 2A(2) (A)</p> Signup and view all the answers

What happens to the valence electrons of a magnesium atom when it forms an ion?

<p>It loses two valence electrons. (B)</p> Signup and view all the answers

How does the charge of an electron relate to the charge of an ion?

<p>Electrons decrease the charge of the ion. (C)</p> Signup and view all the answers

Which process leads to the formation of an ionic bond?

<p>Transfer of valence electrons from one atom to another. (D)</p> Signup and view all the answers

What is the charge of the ammonium ion (NH4+)?

<p>Positive (C)</p> Signup and view all the answers

Which of the following polyatomic ions has a charge of 2−?

<p>Phosphate (PO43−) (C)</p> Signup and view all the answers

What is the systematic naming convention for polyatomic ions with one less oxygen than the '-ate' ion?

<p>Use the suffix '-ite' (C)</p> Signup and view all the answers

When writing the formula for sodium phosphate, what is the correct subscripts for the sodium cation (Na+)?

<p>3 (B)</p> Signup and view all the answers

Which of the following shows the correct formula for aluminum bicarbonate?

<p>Al(HCO3)3 (A)</p> Signup and view all the answers

The name for the nitrite ion is based on which pattern?

<p>It is the base form of the nitrate (D)</p> Signup and view all the answers

Which of the following correctly represents the bicarbonate ion?

<p>HCO3− (A)</p> Signup and view all the answers

Which cation is paired with the sulfate ion when forming a compound?

<p>Al3+ (D)</p> Signup and view all the answers

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Study Notes

The Octet Rule

  • Atoms tend to gain, lose, or share valence electrons to achieve a stable electron configuration like noble gases, having 8 valence electrons, known as the octet rule.
  • Helium is an exception, being stable with 2 valence electrons.

Ions

  • Ions are formed when atoms gain or lose electrons, resulting in a charge.
  • Cations are positively charged ions formed when atoms lose electrons, having more protons than electrons.
  • Anions are negatively charged ions formed when atoms gain electrons, having fewer protons than electrons.

Ionic Bonds

  • Formed when valence electrons are transferred from a metal atom to a nonmetal atom.
  • Occurs between metals and nonmetals to achieve an octet.

Covalent Bonds

  • Formed when nonmetal atoms share valence electrons to attain noble gas configuration.
  • Occurs between nonmetal atoms to achieve an octet.

Formation of Positive Ions

  • Metals form positive ions by losing their valence electrons.
  • Group 1A(1) metals form ions with a 1+ charge, Group 2A(2) metals form ions with a 2+ charge, and Group 3A(3) metals form ions with a 3+ charge.

Formation of Negative Ions

  • Nonmetals achieve an octet by gaining electrons.
  • Group 17(7) nonmetals form ions with a 1- charge, Group 16(6) nonmetals form ions with a 2- charge, and Group 15(5) nonmetals form ions with a 3- charge.

Charge Balance

  • Ionic compounds are neutral, meaning the positive charges from cations must equal the negative charges from anions.
  • The subscripts in the chemical formula of ionic compounds represent the number of ions needed for charge balance.
  • For example, in MgCl2, 1 Magnesium ion (Mg2+) and 2 Chlorine ions (Cl-) are needed to achieve charge balance.

Naming Ionic Compounds

  • The name of the cation (metal) is written first, followed by the anion (nonmetal) with the ending changed to "-ide."
  • For example, NaCl is named sodium chloride.

Transition Metals and Variable Charge

  • Many transition metals form two or more positive ions, resulting in variable charges.
  • Roman numerals are used in the name to specify the charge of the metal ion.
  • For example, FeCl2 is Iron(II) chloride, indicating the iron ion has a 2+ charge.

Polyatomic Ions

  • Polyatomic ions are groups of atoms that act as a single unit with an overall charge.
  • Many common polyatomic anions end in "-ate" or "-ite," indicating different numbers of oxygen atoms.
  • For example, nitrate (NO3-) has more oxygen atoms than nitrite (NO2-).

Naming Compounds with Polyatomic Ions

  • The name of the cation is written first, followed by the name of the polyatomic anion.
  • For example, Na2SO4 is sodium sulfate.

Writing Formulas for Compounds with Polyatomic Ions

  • Identify the cation and the polyatomic ion.
  • Balance the charges by determining the number of each ion needed.
  • Write the formula with the cation first, followed by the anion, using the subscripts to indicate the number of each ion.
  • For example, aluminum bicarbonate, Al(HCO3)3, has one aluminum ion (Al3+) and three bicarbonate ions (HCO3-).

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