Chemistry: The Mole and Mass Conservation
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Questions and Answers

A solution contains 3 moles of solute in 750 cm³ of solution. What is its concentration in mol/dm³?

  • 0.4 mol/dm³
  • 2.25 mol/dm³
  • 4 mol/dm³ (correct)
  • 0.25 mol/dm³

In a titration, 20 cm³ of 0.2 mol/dm³ hydrochloric acid (HCl) neutralizes 25 cm³ of sodium hydroxide (NaOH). What is the concentration of the NaOH solution?

  • 0.16 mol/dm³ (correct)
  • 0.12 mol/dm³
  • 0.32 mol/dm³
  • 0.25 mol/dm³

A reaction has a theoretical yield of 15 grams, but the actual yield obtained is 12 grams. What is the percentage yield?

  • 88 %
  • 12 %
  • 80 % (correct)
  • 18 %

In a reaction, the desired product has a Mr of 50 and the total Mr of all products is 100. What is the atom economy of this reaction?

<p>50 % (A)</p> Signup and view all the answers

20 cm³ of an unknown concentration of potassium hydroxide (KOH) is titrated with 0.15 mol/dm³ hydrochloric acid (HCl). If 25 cm³ of HCl is needed to neutralise the KOH, what is the concentration of the potassium hydroxide solution?

<p>0.1875 mol/dm³ (A)</p> Signup and view all the answers

What does one mole of a substance always contain?

<p>6.022 × 10²³ particles. (D)</p> Signup and view all the answers

In a chemical reaction, what does the law of conservation of mass state?

<p>The total mass of reactants equals the total mass of products. (D)</p> Signup and view all the answers

In a reaction between 12g of magnesium and 20g of oxygen, what is the first step to determine the limiting reactant?

<p>Calculate the number of moles of each reactant. (D)</p> Signup and view all the answers

If 10g of hydrogen reacts with 32g of oxygen, how many moles of water, $H_2O$ can be formed? The molar mass of hydrogen is 1, oxygen is 16, and water is 18.

<p>2 moles (A)</p> Signup and view all the answers

What does it mean for a reactant to be the 'limiting reactant' in a chemical reaction?

<p>It is the reactant that is completely used up in the reaction. (A)</p> Signup and view all the answers

What is the concentration of a solution that contains 2 moles of solute in 500 cm³ of solution, in mol/dm³?

<p>4 mol/dm³ (D)</p> Signup and view all the answers

Which of these is the correct formula to use when calculating number the of moles of a given substance?

<p>Moles = Mass / Mr (B)</p> Signup and view all the answers

If a solution has a concentration of 5 mol/dm³ and a molar mass of 40 g/mol, what is the concentration of the solution in g/dm³?

<p>200 g/dm³ (D)</p> Signup and view all the answers

Flashcards

Titration

A technique used to find the unknown concentration of a solution by reacting it with a solution of known concentration. This involves carefully reacting an acid and alkali until the indicator changes color, allowing for the calculation of the unknown concentration using the formula C₁V₁ = C₂V₂.

Percentage Yield

The ratio of the actual mass of product obtained in a reaction to the maximum theoretical mass that could be produced, expressed as a percentage. It is calculated by dividing the actual yield by the theoretical yield and multiplying by 100%.

Atom Economy

A measure of how efficiently a reaction converts reactants into desired products. It is calculated by dividing the molecular mass of the desired product by the total molecular mass of all products and multiplying by 100%.

Concentration

The molar concentration of a solution, defined as the number of moles of solute per liter of solvent. It is often measured in units of mol/dm³.

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Balanced Chemical Equation

A chemical equation that represents the stoichiometric ratios of reactants and products involved in a chemical reaction. It provides a quantitative representation of the number of moles of each substance involved.

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What is a mole?

A measure of the amount of substance, equivalent to 6.022 x 10^23 particles. These particles can be atoms, molecules, ions, or even electrons.

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What is molar mass?

The mass of one mole of a substance. It's represented by 'Mr' and is expressed in grams per mole (g/mol).

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What is the Law of Conservation of Mass?

In a chemical reaction, the total mass of the reactants always equals the total mass of the products.

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What are closed and open systems?

A closed system is like a sealed container where no mass can escape or enter. In an open system, mass can be exchanged with the environment, like gases escaping or entering.

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What is a limiting reactant?

The reactant that gets completely used up in a reaction, limiting the amount of product formed.

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What is the concentration of a solution?

The amount of solute dissolved in a given volume of solution. It's usually expressed in moles per cubic decimeter (mol/dm³).

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What is an excess reactant?

The reactant that is not fully used up in a reaction. It's the one that is left over after the limiting reactant is completely consumed.

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What is the mole ratio?

The ratio of the number of moles of each reactant and product in a balanced chemical equation. This ratio tells you how many moles of each substance are involved in the reaction.

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Study Notes

The Mole

  • A mole measures the amount of substance
  • Equivalent to 6.022 × 10²³ particles (Avogadro's constant)
  • Particles can be atoms, molecules, ions, or electrons
  • Molar Mass (Mr): the relative formula mass (Mr) of a substance in grams is equal to 1 mole
  • Units: grams per mole (g/mol)
  • Formula: Moles = Mass (g) / Molar Mass (Mr)

Conservation of Mass

  • Law of Conservation of Mass: the total mass of reactants equals the total mass of products in a chemical reaction.
  • Closed Systems: No mass is lost or gained
  • Open Systems: Apparent mass changes may occur due to gases entering or leaving

Reacting Mass Calculations

  • Steps for reacting mass calculation:
    • Write a balanced chemical equation
    • Identify substances given and required
    • Calculate moles of given substance
    • Find moles of required using mole ratio from balanced equation
    • Convert moles to mass of required substance using: Mass (g) = Moles × Molar Mass (Mr)

Limiting Reactants

  • Limiting Reactant: The reactant completely used up in a reaction and determines how much product is formed.
  • Excess reactants: Not completely consumed.
  • Steps for identifying the limiting reactant:
    • Calculate moles of each reactant.
    • Use balanced equation to find the mole ratio.
    • Identify which reactant is limiting (the one with fewer moles relative to the ratio).

Concentration of Solutions

  • Concentration Formula: Concentration (mol/dm³) = Moles of solute (mol) / Volume of solution (dm³)
  • Units: mol/dm³ or g/dm³
  • Conversion between units: Concentration (g/dm³) = Concentration (mol/dm³) × Molar Mass (Mr)

Titrations

  • Purpose: Determine unknown concentration of an acid or alkali by reacting with a solution of known concentration
  • Key Formula: Moles of acid = Moles of alkali, C₁V₁ = C₂V₂
  • Steps for titration:
    • Measure a known volume of acid/alkali
    • Add indicator (e.g., phenolphthalein or methyl orange)
    • Slowly add the other solution from burette until indicator changes colour
    • Record volume used and repeat for concordant results

Percentage Yield

  • Definition: Compares actual mass of product obtained to maximum theoretical mass
  • Formula: Percentage Yield = (Actual Yield / Theoretical Yield) × 100

Atom Economy

  • Definition: Measures efficiency of a reaction based on how much of reactants become useful products.
  • Formula: Atom Economy = (Mr of desired product / Total Mr of all products) × 100

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Description

This quiz covers essential concepts related to the mole, including its definition, Avogadro's constant, and molar mass calculations. Additionally, it explores the law of conservation of mass and the approach to reacting mass calculations, featuring limiting reactants as well. Test your understanding of these fundamental chemistry principles.

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