Chemistry Solubility Concepts
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Questions and Answers

What is the iodine number calculated from a 100 g sample of fat, given that the mass of the product after reaction with iodine is 320 g?

  • 220 g
  • 320 g
  • 420 g (correct)
  • 501 g
  • How is the iodine number typically defined?

  • The quotient of product mass to reactant mass
  • The weight difference of fat before and after iodine reaction (correct)
  • The total mass of iodine used in the reaction
  • The molar ratio of fat to iodine
  • If the molar mass of a fat is 882 g/mol and 100 g of it is used in a reaction producing 215 g product, what is the iodine number?

  • 215 g
  • 667 g
  • 597 g (correct)
  • 320 g
  • What does a high iodine number generally indicate about a fat or oil?

    <p>High degree of unsaturation</p> Signup and view all the answers

    How can the amount of iodine in moles be determined from the iodine number?

    <p>By dividing the iodine number by the molar mass of iodine</p> Signup and view all the answers

    What is the degree of unsaturation likely to indicate when studying the fat's structure?

    <p>Presence of alternate double bonds across the chain</p> Signup and view all the answers

    What is the type of reaction that alkenes can undergo?

    <p>Addition reaction</p> Signup and view all the answers

    If the iodine number is calculated to be 501 g for a fat sample, what does this imply?

    <p>501 g of iodine reacted with 100 g of fat</p> Signup and view all the answers

    What happens to the color of bromine liquid when it is added to an alkene?

    <p>It turns colorless</p> Signup and view all the answers

    Can alkanes undergo addition reactions?

    <p>No, never</p> Signup and view all the answers

    Which of the following correctly describes how the iodine number can be used in food science?

    <p>It assesses the quality of oils regarding their health aspects</p> Signup and view all the answers

    What is the saturation level of alkenes?

    <p>Unsaturated</p> Signup and view all the answers

    Which halogen can be used to test for C=C double bonds?

    <p>Bromine (Br2)</p> Signup and view all the answers

    What indicates the formation of an ester during a reaction with ethanol?

    <p>A fruity smell</p> Signup and view all the answers

    Which test can determine the presence of propanoic acid without relying on smell?

    <p>Carbonate test</p> Signup and view all the answers

    What is the main characteristic of a compound that indicates it is an alkene?

    <p>Presence of C=C double bonds</p> Signup and view all the answers

    What is produced when ethanoic acid reacts with sodium carbonate?

    <p>Carbon dioxide gas, water, and sodium acetate</p> Signup and view all the answers

    What observation confirms the presence of double bonds in a molecule after adding a halogen?

    <p>Color change occurs</p> Signup and view all the answers

    If a substance remains brown after adding bromine, what does this indicate?

    <p>It is an alkane</p> Signup and view all the answers

    What should be observed during the carbonate test if an acid is present?

    <p>Bubbles forming</p> Signup and view all the answers

    Why is a carbonate test not exclusive to carboxylic acids?

    <p>Other acids also produce gas.</p> Signup and view all the answers

    What does the formation of bubbles during the carbonate test indicate?

    <p>The presence of carbon dioxide</p> Signup and view all the answers

    What is one limitation of the carbonate test?

    <p>Any acid can react in the test.</p> Signup and view all the answers

    In the context of the carbonate test, what does the presence of bubbles signify?

    <p>An acid present</p> Signup and view all the answers

    Which of the following alcohols is not oxidized by acidified potassium dichromate?

    <p>2-Methyl-propan-2-ol</p> Signup and view all the answers

    What color change occurs when acidified MnO4− is reduced to Mn2+?

    <p>From Purple to Pale pink/colourless</p> Signup and view all the answers

    What is the color change observed when Cr2O7 2− is converted to Cr3+?

    <p>Orange to Green</p> Signup and view all the answers

    How can one differentiate between propan-1-ol and propan-2-ol using dichromate solution?

    <p>By noting that propan-1-ol changes color, while propan-2-ol does not</p> Signup and view all the answers

    Which oxidation reaction would potentially NOT involve color change?

    <p>Oxidation of tertiary alcohol</p> Signup and view all the answers

    What product is formed when primary alcohol is fully oxidized?

    <p>Carboxylic Acid</p> Signup and view all the answers

    Which oxidizing agent is commonly used in the oxidation of alcohols?

    <p>Acidified Potassium Dichromate</p> Signup and view all the answers

    During the oxidation of secondary alcohols, which of the following is typically produced?

    <p>Ketone</p> Signup and view all the answers

    Which type of molecules will dissolve in water?

    <p>Polar molecules</p> Signup and view all the answers

    Why won't polar and non-polar molecules dissolve in each other?

    <p>They undergo different types of intermolecular bonding.</p> Signup and view all the answers

    Which of the following types of compounds is generally soluble in water?

    <p>Alcohols</p> Signup and view all the answers

    What is the main factor that determines the solubility of a substance in water?

    <p>The type of intermolecular forces it experiences.</p> Signup and view all the answers

    Which of the following is a characteristic of non-polar molecules?

    <p>They rely on dispersion forces.</p> Signup and view all the answers

    Which of the following substances is likely to be insoluble in water?

    <p>Hexane</p> Signup and view all the answers

    In terms of solubility, what does the phrase 'like dissolves like' mean?

    <p>Polar substances dissolve in polar substances.</p> Signup and view all the answers

    Which intermolecular force is primarily responsible for the solubility of alcohols in water?

    <p>Hydrogen bonding</p> Signup and view all the answers

    What type of intermolecular force do carboxylic acids predominantly exhibit with water?

    <p>Hydrogen bonds</p> Signup and view all the answers

    Which type of molecule is characterized by the presence of a carbonyl group?

    <p>Aldehyde</p> Signup and view all the answers

    What is a defining feature of polar molecules?

    <p>They contain charges or partial charges.</p> Signup and view all the answers

    In terms of solubility in water, which functional group provides strong compatibility?

    <p>Hydroxyl group</p> Signup and view all the answers

    Which of the following statements about polar and non-polar substances is incorrect?

    <p>Non-polar substances can dissolve in water.</p> Signup and view all the answers

    Which molecule is an example of a non-polar solvent?

    <p>Hexane</p> Signup and view all the answers

    What occurs during solubility when polar and non-polar molecules are mixed?

    <p>No interaction occurs.</p> Signup and view all the answers

    Study Notes

    Solubility Concepts

    • Polar molecules dissolve in polar solvents due to dipole-dipole and hydrogen bonding.
    • Non-polar molecules dissolve in non-polar solvents through dispersion forces.
    • Polar and non-polar molecules do not mix, as polar molecules engage stronger interactions with themselves compared to non-polar counterparts.
    • The principle of "like dissolves like" is key in solubility.

    Intermolecular Forces and Solubility

    • Alkanes: Non-polar, soluble in non-polar solvents, insoluble in water.
    • Alkenes: Non-polar, similar solubility characteristics as alkanes.
    • Haloalkanes: Generally insoluble in water due to non-polar characteristics.
    • Alcohols: Polar, soluble in water due to hydrogen bonding.
    • Ketones: Polar, also soluble in water due to hydrogen bonding.
    • Carboxylic Acids: Polar and soluble, can form strong hydrogen bonds in water.
    • Amines: Polar compounds, soluble in water due to hydrogen bonding.
    • Amides: Polar, soluble in water through hydrogen bonding.
    • Aldehydes: Polar and generally soluble in water.
    • Ethers: Polar but may have varying solubility in water depending on structure.
    • Benzene: Non-polar and insoluble in water.

    Alkene vs Alkane Reactions

    • Alkenes are unsaturated and can undergo addition reactions.
    • When bromine (Br₂) is added to alkenes, the solution turns colorless, indicating a reaction.
    • Alkanes are saturated and do not undergo addition reactions like alkenes.

    Iodine Number

    • The Iodine number indicates the mass of iodine that reacts with a fat or oil sample, reflecting its degree of unsaturation.
    • Calculation example: If 100 g of fat reacts with iodine to yield a product mass of 320 g, the Iodine number is determined using the formula.

    Oxidation Tests

    • Dichromate (Cr₂O₇²⁻) and Permanganate (MnO₄⁻) are common oxidizing agents.
    • Color changes indicate reactions:
      • Purple to pale pink/colourless for MnO₄⁻.
      • Orange to green for Cr₂O₇²⁻.
    • Propan-1-ol oxidizes, while propan-2-ol and 2-methyl-propan-2-ol show different reactivities.

    Carbonate Test

    • Carbonate test confirms acidity through the reaction of acids with sodium carbonate or sodium hydrogen carbonate.
    • Observations include gas bubbles (CO₂) formation for acids.
    • This test is non-specific as it can yield positive results for various acids, not solely carboxylic acids.

    General Chemistry Notes

    • Oxidation reactions vary by alcohol type (primary, secondary, tertiary).
    • Unsaturated compounds exhibit unique chemical behaviors versus saturated ones, crucial for understanding organic reactions.
    • When testing for functional groups, utilizing color change indicators can provide visual confirmations of chemical transformations.

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    Description

    This quiz explores the principles of solubility in chemistry, including the interactions between polar and non-polar molecules. Test your understanding of how different compounds, such as alkanes, alcohols, and carboxylic acids, behave in various solvents. Learn about the fundamental concept of 'like dissolves like' and the associated intermolecular forces.

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