Chemistry Quiz: Reactions and Electron Configurations

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Questions and Answers

Which statement is true regarding chemical reactions?

  • Each type of atom is conserved in a reaction. (correct)
  • Atoms can be destroyed in a chemical reaction.
  • Only certain types of atoms are conserved.
  • Each type of atom is created during a reaction.

What determines the maximum yield of a product in a chemical reaction?

  • The limiting reactant available. (correct)
  • The excess reactant used.
  • The temperature of the reaction.
  • The pressure during the reaction.

Which of the following statements accurately describes the oxidation agent?

  • The oxidizing agent gains electrons and is reduced. (correct)
  • The oxidizing agent solely facilitates the reaction without changing.
  • The oxidizing agent loses electrons and is oxidized.
  • The oxidizing agent is not involved in the reaction.

What is true about the oxidation state of manganese in $KMnO_4$?

<p>It is +7. (D)</p> Signup and view all the answers

Which term describes reactions that do not involve electron transfer?

<p>Non-redox reactions. (A)</p> Signup and view all the answers

What is the wavelength of the light emitted when an electron falls from the n = 3 to the n = 1 state in a hydrogen atom?

<p>122 nm (B)</p> Signup and view all the answers

Which of these orbital designations is correct for n = 4, l = 0?

<p>4s (B)</p> Signup and view all the answers

What type of orbital is indicated by the quantum numbers n = 5, l = 1, m_l = 0?

<p>5p (A)</p> Signup and view all the answers

What is the correct ground-state electron configuration for the element with atomic number 42 (Mo)?

<p>[Kr] 5s^1 4d^5 (C)</p> Signup and view all the answers

Which of the following elements is a metalloid?

<p>Ge (D)</p> Signup and view all the answers

Which option contains the largest number of $H_2O$ molecules?

<p>1 kg of $H_2O$ (A)</p> Signup and view all the answers

What is the formula mass of $Ca_3(PO_4)_2$?

<p>310 (B)</p> Signup and view all the answers

When comparing one mole of two different substances A and B, what do they have in common?

<p>Number of particles (D)</p> Signup and view all the answers

How many grams of oxygen can be produced from the decomposition of 12 grams of mercury (II) oxide?

<p>8 g (D)</p> Signup and view all the answers

What is the percent yield when 40 g of $N_2O_5$ decomposes to form 4.5 g of $O_2$?

<p>24.5% (A)</p> Signup and view all the answers

Which statement correctly identifies a characteristic of a Brønsted-Lowry acid?

<p>It is a proton donor. (A)</p> Signup and view all the answers

Among the following options, which represents a strong base?

<p>KOH (A)</p> Signup and view all the answers

What is the conjugate base of the weak acid HNO₂?

<p>NO₂⁻ (D)</p> Signup and view all the answers

Which of the following pairs is correctly identified as a conjugate acid-base pair?

<p>NH₄⁺ and NH₃ (A)</p> Signup and view all the answers

Which of the listed acids is classified as a weak acid?

<p>HF (B)</p> Signup and view all the answers

What is the pH when [H+] = 4.0 × 10⁻⁹ M in water at 25°C?

<p>9.40 (C)</p> Signup and view all the answers

If a solution has an [OH⁻] concentration of 1.20 × 10⁻⁷ M, what are its corresponding pOH and pH values?

<p>7.08 and 6.92 (D)</p> Signup and view all the answers

What is the correct value of the acid ionization constant, Ka, for acetic acid based on a vinegar pH of 2.4?

<p>2.5 × 10⁻⁵ (C)</p> Signup and view all the answers

Given a hydroxide ion concentration of 1.0 × 10⁻¹⁰ M, what is the pH of coffee?

<p>4 (C)</p> Signup and view all the answers

Which of the following statements about Lewis bases is incorrect?

<p>Lewis bases are cationic in nature (A)</p> Signup and view all the answers

Which coefficients correctly balance the equation $P_4 + H_2O \rightarrow PH_3 + H_3PO_4$?

<p>1, 4, 1, 1 (C)</p> Signup and view all the answers

What is the balanced form for the reaction $H_2SO_4 + HBr \rightarrow SO_2 + Br_2 + H_2O$?

<p>$1H_2SO_4 + 2HBr \rightarrow 1SO_2 + 1Br_2 + 2H_2O$ (B)</p> Signup and view all the answers

Identify the correct coefficients for balancing the equation $H_2S + HNO_3 \rightarrow S + NO_2 + H_2O$.

<p>1, 6, 1, 3 (D)</p> Signup and view all the answers

What coefficients balance the equation $KMnO_4 + HCl \rightarrow MnCl_2 + Cl_2 + KCl + H_2O$?

<p>1, 8, 1, 3, 1 (D)</p> Signup and view all the answers

What does the atomic number of an element indicate?

<p>The number of protons in the nucleus (A)</p> Signup and view all the answers

Which of the following subshells has three orbitals?

<p>p subshell (B)</p> Signup and view all the answers

When l = 1, which of the following values of m_l is not possible?

<p>+2 (D)</p> Signup and view all the answers

How many neutrons are present in the isotope $$^{199}_{79}Au$$?

<p>120 (C)</p> Signup and view all the answers

Which statement is true regarding the isotopes of iridium?

<p>They differ in the number of neutrons (B)</p> Signup and view all the answers

What is the correct interpretation of the quantum number l = 2?

<p>d subshell (B)</p> Signup and view all the answers

For the electron transitions resulting in photon emission, which wavelength corresponds to the highest energy photon?

<p>$1.0 imes 10^{-10}$ m (A)</p> Signup and view all the answers

What is the relationship between the velocity of a photon and its wavelength?

<p>Higher velocity means shorter wavelength (A)</p> Signup and view all the answers

Which scientist is recognized for contributing to the atomic structure theory?

<p>Thomson (B)</p> Signup and view all the answers

What is the frequency in Hz of gamma radiation with a wavelength of $1.0 \times 10^{-9}$ nm?

<p>$3.0 \times 10^{18}$ Hz (C)</p> Signup and view all the answers

What is the energy associated with an electronic transition for a wavelength of 589 nm?

<p>$3.38 \times 10^{-19}$ J (B)</p> Signup and view all the answers

Which of the following colors has the highest frequency of light?

<p>Violet (D)</p> Signup and view all the answers

Which of the following orbital designations is valid?

<p>3d (B)</p> Signup and view all the answers

Which quantum number set is forbidden for a hydrogen atom?

<p>n = 4, l = 3, ml = 4 (A)</p> Signup and view all the answers

Which of the following ions has the same electron configuration as $^{32}S$?

<p>$^{31}Cl$ (C)</p> Signup and view all the answers

Which element has the lowest electronegativity in this set?

<p>Magnesium (B)</p> Signup and view all the answers

Flashcards

Balancing Chemical Equations

A chemical equation is balanced when the number of atoms of each element on the reactant side equals the number of atoms of that element on the product side. This ensures that the law of conservation of mass is upheld during a chemical reaction.

How to Balance Equations

To balance an equation, you adjust the stoichiometric coefficients, which are the numbers before each chemical formula, until the number of atoms of each element is identical on both sides.

Balance the equation: H3BO3 → HBO2 + H2O

The equation is balanced when there are 4 hydrogen atoms, 3 boron atoms, and 6 oxygen atoms on both sides.

Balance the equation: P4 + H2O → PH3 + H3PO4

The balanced equation is P4 + 16 H2O → 4 PH3 + 4 H3PO4. This equation has 4 phosphorus atoms, 32 hydrogen atoms, and 16 oxygen atoms on each side.

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The Meaning of Coefficients

The coefficients in a balanced equation represent the number of moles of each reactant and product involved in the reaction.

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Conservation of Atoms

In a chemical reaction, the total number of atoms of each element remains the same on both sides of the equation. This means that atoms are neither created nor destroyed, but rearranged.

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Limiting Reactant

The reactant that is completely consumed first in a chemical reaction, limiting the amount of product that can be formed.

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Redox Reaction

A chemical reaction where electrons are transferred between reactants. It involves changes in oxidation numbers.

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Non-Redox Reaction

Reactions that don't involve the transfer of electrons, they usually involve the formation or breaking of bonds between atoms.

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Molecular Mass

The sum of the atomic masses of all atoms present in a molecule. It represents the mass of one molecule of the compound.

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Brønsted-Lowry Acid

An acid that donates a proton (H+).

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Brønsted-Lowry Base

A base that accepts a proton (H+).

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Relationship Between Acid and Base Strength

The strength of a base is inversely proportional to the strength of its conjugate acid. A stronger acid has a weaker conjugate base.

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Conjugate Acid

A substance formed when a base gains a proton.

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Conjugate Base

A substance formed when an acid loses a proton.

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What does the atomic number tell us?

The atomic number of an element represents the number of protons present in the nucleus of its atom.

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How are electrons and protons related in a neutral atom?

In a neutral atom, the number of negatively charged electrons always equals the number of positively charged protons.

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What are the possible values of 'l' when 'n' is 2?

The principal quantum number (n) determines the energy level of an electron, while the angular momentum quantum number (l) specifies the shape of the electron's orbital. For n = 2, the possible values of l are 0 and 1, corresponding to an s orbital (l = 0) and a p orbital (l = 1).

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What are the possible values of 'ml' when 'l' is 1?

The magnetic quantum number (ml) describes the orientation of an electron orbital in space. For l = 1 (p orbital), the possible values of ml are -1, 0, and +1, indicating three different spatial orientations of the p orbital.

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What is the subshell named when 'l' is 1?

The p subshell is characterized by its shape, which is dumbbell-like. It is characterized by 'l' being equal to 1.

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How many orbitals are in a p subshell?

A p subshell consists of three orbitals, each with a different spatial orientation, characterized by the ml values of -1, 0, and +1.

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How many orbitals are in an f subshell?

An f subshell comprises seven orbitals, each with a unique spatial orientation, as indicated by ml values of -3, -2, -1, 0, +1, +2, and +3. Each orbital has a distinct and complex shape.

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How is the average atomic mass of an element calculated?

The atomic mass of an element is the weighted average of the atomic masses of its naturally occurring isotopes. The percent natural abundance of each isotope is used as the weighting factor in this calculation.

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pH Scale

The pH scale is logarithmic, meaning each unit change represents a tenfold difference in hydrogen ion concentration. A pH of 7 is neutral, below 7 is acidic, and above 7 is basic. [H+]=1 x 10^-7 = neutral.

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Kw Constant

The product of the hydrogen ion concentration [H+] and the hydroxide ion concentration [OH-] in water is always equal to a constant value, Kw, which is 1.0 x 10⁻¹⁴ at 25°C. This relationship helps us understand the balance between acidity and basicity in aqueous solutions.

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pOH

The pOH of a solution is the negative logarithm of the hydroxide ion concentration. [OH⁻]

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Ka Constant

The acid ionization constant (Ka) is a measure of the strength of an acid. A larger Ka value indicates a stronger acid that ionizes more in solution. Ka = [H+][A-] / [HA].

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Lewis Base

A Lewis base is a species that donates a pair of electrons, forming a covalent bond with an electron-deficient species (Lewis acid).

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What is Avogadro's number?

The number of atoms in one mole of any substance is constant, known as Avogadro's number ($6.02 \times 10^{23}$). This means 1 mole of any substance contains the same number of particles.

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What is molar mass?

The mass of one mole of a substance is called its molar mass. It is expressed in grams per mole (g/mol) and can be determined by adding the atomic masses of all atoms in the chemical formula.

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What is the limiting reactant?

The limiting reactant is the reactant that gets completely consumed first in a reaction, determining the amount of product that can be formed.

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What is percent yield?

The percentage yield is the actual amount of product obtained in a reaction compared to the theoretical maximum amount expected, expressed as a percentage. It reflects the efficiency of the reaction.

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What is the difference between empirical and molecular formula?

The empirical formula shows the simplest whole-number ratio of atoms in a compound. The molecular formula represents the actual number of atoms of each element in a molecule.

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Calculate the wavelength of light emitted when an electron falls from n = 3 to n = 1 in a hydrogen atom.

The wavelength of light emitted during an electron transition from a higher energy level (n=3) to a lower energy level (n=1) in a hydrogen atom.

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What type of orbital (i.e., 3s, 4p,...) is designated by these quantum numbers: n = 5, l = 1, ml = 0?

The set of three quantum numbers (n, l, ml) uniquely identifies an atomic orbital. n represents the principal quantum number, determining the energy level. l refers to the angular momentum quantum number, characterizing the shape of the orbital. ml, the magnetic quantum number, describes the spatial orientation of the orbital.

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Write the ground-state electron configuration for Br (Z = 35) and Mo (Z = 42).

The ground-state electron configuration of an element describes the arrangement of electrons in its lowest energy state. It follows specific rules like the Aufbau principle, Hund's rule, and the Pauli exclusion principle.

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Write the period number for P, Ge, F, and W. State if they are metal, non-metal, or metalloid.

Elements in the periodic table are categorized into periods and groups. Periods represent horizontal rows, signifying the same principal quantum number (n). Groups, the vertical columns, designate elements with similar chemical properties due to the same number of valence electrons.

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Write the number and the letter for the orbital that corresponds to the following pairs of n and l quantum numbers: n=3, l=1; n=4, l=0; n=3, l=2; n=5, l=3.

The orbital designation depends on the values of n and l. n dictates the energy level, and l describes the shape of the orbital (s, p, d, or f). For example, n=3, l=1 corresponds to a 3p orbital.

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Atomic Number

The positive charge of an atom's nucleus, equal to the number of protons.

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Oxidation State

The number of electrons an atom gains or loses to achieve a stable, noble gas configuration.

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Ionization Energy

Energy required to remove one electron from a gaseous atom in its ground state.

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Electronegativity

Ability of an atom to attract electrons in a covalent bond.

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Orbital

The region around the nucleus where an electron is most likely to be found.

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Quantum Numbers

A set of four quantum numbers that describe the state of an electron in an atom.

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Electron Cloud

A region of space around the nucleus where there is a high probability of finding an electron.

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Electronic Configuration

The arrangement of electrons in different energy levels and sublevels within an atom.

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Study Notes

Part I: True-False Type Questions

  • In any chemical reaction, each type of atom is conserved.
  • In a balanced chemical equation, both sides of the equation have the same number of moles.
  • The oxidizing agent is oxidized by the reducing agent.
  • Most metallic elements are strong reducing agents, whereas most non-metallic elements are strong oxidizing agents.
  • The higher the percentage yields of a chemical reaction, the more efficient the reaction.

Part II: Write the Missing Words

  • The oxidation number of manganese in KMnO₄ is +7.
  • The maximum yield of product is determined by the limiting reactant.
  • Reactions which do not involve electron transfer are known as redox reactions.
  • The sum of the masses of all the atoms present in a molecule is the molecular mass.
  • The sum of the atomic masses of all atoms present in the formula unit of an ionic compound is the formula mass.
  • (Molecular number) is the formula of a substance written with the smallest integer (whole number) subscripts.
  • The actual formula that tells you the exact number of atoms of different elements present in a molecule is the molecular formula.

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