Chemistry: Pyrolysis and Hydrogen Production
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Questions and Answers

What is the primary focus of the Hydrogen Hub?

  • Hydrogen-powered internal combustion engine design
  • Grid-connected fuel cell system development
  • Research and development of hydrogen fuel cells
  • Production, logistics, infrastructure, and final use of hydrogen (correct)
  • What is the primary advantage of using hydrogen fuel cells in mobility?

  • Enhanced infrastructure compatibility
  • Increased energy efficiency (correct)
  • Reduced production costs
  • Improved storage capacity
  • Which of the following is a challenge in hydrogen transportation?

  • Infrastructure compatibility issues
  • Cost reduction in fuel cell production
  • Storage capacity limitations (correct)
  • Electrolysis system efficiency
  • What is the primary goal of the Power-to-Gas Pathway?

    <p>Transitioning the energy system infrastructure</p> Signup and view all the answers

    What is the primary application of hydrogen in the Hamburg Green Hydrogen Hub?

    <p>Mobility and transportation</p> Signup and view all the answers

    What is the primary method of hydrogen production in the Hydrogen Hub?

    <p>All of the above</p> Signup and view all the answers

    What is the primary challenge in reducing the cost of hydrogen production?

    <p>Scaling up electrolysis systems</p> Signup and view all the answers

    What is the primary benefit of grid-connected fuel cell systems?

    <p>Improved energy efficiency</p> Signup and view all the answers

    What is the primary application of hydrogen in industry?

    <p>Process heating</p> Signup and view all the answers

    What is the primary goal of the hydrogen valley concept?

    <p>Breaking the chicken-and-egg deadlock in hydrogen adoption</p> Signup and view all the answers

    Study Notes

    Pyrolysis

    • Pyrolysis is the heating of a solid/liquid/gas fuel, such as hydrocarbon, in the absence of oxygen.

    Hydrogen Production

    • Electrolysis is a process of water energy bonding, producing hydrogen.
    • Types of electrolyzers:
      • Alkaline Electrolysis Water (AEW)
      • Anion Exchange membrane (AEM) Electrolyser
      • Proton Exchange membrane (PEM) Electrolyser
      • Solid Oxide Electrolyser (SOE)

    Electrolyzer Characteristics

    • AEW:
      • 25-30% KOH solution in pure water
      • Separator: Porous Zirconium
      • Electrode material: Cathode: Ni, Co or Fe; Anode: Ni
      • Energy source: 100% electricity
      • Temperature: 100-150°C
      • Pressure: Up to 40 bar
      • Cost: lowest
      • Readiness: mature
    • AEM:
      • 2-5% KOH in pure water
      • Separator: Anion exchange membrane
      • Electrode material: Cathode: Ni or Ni-Alloy; Anode: Ni
      • Energy source: 100% electricity
      • Temperature: 60-90°C
      • Pressure: Up to 35 bar
      • Cost: medium
      • Readiness: big scale demonstration
    • PEM:
      • Ultra pure water
      • Separator: Fluoropolymer sulfonic acid membrane
      • Electrode material: Cathode: Pt; Anode: Ir/Pt
      • Energy source: 100% electricity
      • Temperature: 70-90°C
      • Pressure: Up to 40 bar
      • Cost: higher
      • Readiness: early development
    • SOE:
      • Pure water
      • Separator: Yittra-Zirconium oxide (ceramic)
      • Electrode material: Cathode: Ni; Anode: Ni
      • Energy source: 75% electricity; 25% heat
      • Temperature: 700-850°C
      • Pressure: close to atmospheric pressure
      • Cost: higher
      • Readiness: demonstration

    Hydrogen Transportation and Storage

    • Hydrogen transportation technologies:
      • Compressed hydrogen
      • Liquid hydrogen
      • Hydrogen gas
    • Challenges in hydrogen storage:
      • Low energy density
      • Leakage due to small molecular size
      • Limited availability of geological storage sites
      • Additional cost and low efficiency of conversion and reconversion to electricity or hydrogen-based fuels

    Hydrogen Storage Options

    • Physical storage:
      • Liquid hydrogen
      • Compressed gas tank
    • Material-based storage:

    Hydrogen Combustion

    • Benefits of using hydrogen as a fuel:
      • Reduces air pollution
      • No carbon emissions (CO, CO2, HC, particulate matter)
      • No emissions if reaction with oxygen only
    • Drawbacks:
      • Produces NOx if combustion is not properly controlled and designed

    Hydrogen in Mobility

    • Hydrogen Internal Combustion Engine (ICE) vs. Hydrogen Fuel Cell:
      • H2 ICE: higher efficiency and simpler design
      • H2 Fuel Cell: higher efficiency and cleaner emissions

    Hydrogen Hub

    • Hydrogen Hub:
      • Production technologies (e.g. electrolysis, steam methane reforming, gasification)
      • Logistics (e.g. gaseous, liquid, or delivered through alternative carriers)
      • Infrastructure (e.g. transport by pipe, lorry, shipping, train tanks)
      • Final use (e.g. industry, mobility, residential heating)
    • Example: Hamburg Green Hydrogen Hub (Germany)

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    Description

    This quiz covers the process of pyrolysis, including the heating of fuels in the absence of oxygen, and hydrogen production through electrolysis.

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