Chemistry Paper 1 - Exam 9701/11

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Questions and Answers

What is a key distinction between relative isotopic mass and relative molecular mass?

  • Relative isotopic mass applies to molecules, while relative molecular mass applies to individual isotopes.
  • Relative isotopic mass includes the mass of electrons, while relative molecular mass does not.
  • Relative isotopic mass refers to the mass of a specific isotope, while relative molecular mass refers to the mass of a molecule. (correct)
  • Relative isotopic mass is always a whole number, while relative molecular mass is always a decimal.

Considering the reaction $6SrO + 2Al \rightarrow 3Sr + Sr_3Al_2O_6$, what relationship is essential to determine the maximum mass of strontium produced from 100g of strontium oxide?

  • The pressure at which the reaction occurs.
  • The density of strontium metal.
  • The volume of aluminium used.
  • The molar mass ratio between SrO and Sr. (correct)

In the nuclear reaction where $^{32}S$ transforms into $^{32}P$ and emits a proton, what other particle is required?

  • A deuteron, $^2H^+$
  • A neutron (correct)
  • A proton
  • An electron

Which substance relies exclusively on temporary dipole intermolecular forces in its liquid state?

<p>Bromine (A)</p> Signup and view all the answers

What accounts for copper's high melting point?

<p>Strong attractive forces between copper ions and delocalised electrons (C)</p> Signup and view all the answers

Under what circumstances would the standard enthalpy change of combustion of graphite be closest in numerical value to the standard enthalpy change of formation?

<p>Combustion of graphite and formation of $CO_2(g)$ (A)</p> Signup and view all the answers

Given the energy cycle for the reaction $Br_2(l) + 3F_2(g) \rightarrow 2BrF_3(l)$ and its related enthalpy changes, how would you calculate the average bond energy of the Br-F bond in $BrF_3$?

<p>$[698 + 2(-301) + 44] / 6$ (kJ mol$^{-1}$) (A)</p> Signup and view all the answers

In which reaction does the oxidation number of sulfur undergo the greatest change?

<p>$S(s) + O_2(g) \rightarrow SO_2(g)$ (D)</p> Signup and view all the answers

In the reaction $2TiO_2 + 4Cl_2 + 3C \rightarrow 2TiCl_4 + 2CO + CO_2$, what substance is reduced?

<p>Chlorine (B)</p> Signup and view all the answers

Sulfuric acid dissociates in aqueous solution, first completely ($H_2SO_4 \rightarrow HSO_4^- + H^+$) and then partially ($HSO_4^- \rightleftharpoons SO_4^{2-} + H^+$). How would you determine $K_c$ if you know the initial concentration of $H_2SO_4$ and the $HSO_4^-$ concentration?

<p>$(SO_4^{2-} concentration)(H^+ concentration) / (HSO_4^- concentration) (D)</p> Signup and view all the answers

What graphical pattern is characteristic of an autocatalytic reaction, where a product catalyzes its own formation?

<p>A graph that increases to a peak and then decreases. (A)</p> Signup and view all the answers

Elements X and Y are in Period 3. X forms a soluble acidic oxide with an oxidation number of +4, and Y forms an amphoteric oxide. What is a plausible formula for the compound formed between X and Y?

<p>SiS2 (B)</p> Signup and view all the answers

In Group 2, three statements about metal Q are correct, and one about metal R. If R has a lower pH value, smaller atomic radius and reacts slower with cold water then what is a true statement for R?

<p>This metal has a carbonate that is used in agriculture to reduce the acidity of soil. (A)</p> Signup and view all the answers

Given the electronic arrangements for four elements, which is the strongest oxidizing agent?

<p>1s2s2p (B)</p> Signup and view all the answers

In a series of test-tube reactions, which combination will likely produce a white solid product?

<p>2 (D)</p> Signup and view all the answers

Under what conditions does concentrated sulfuric acid act both as a strong acid and an oxidizing agent?

<p>Sodium bromide (C)</p> Signup and view all the answers

What influence does the hydrogen chloride molecule have on the nitrogen atom when ammonia ($NH_3$) reacts with hydrogen chloride (HCl) to generate ammonium chloride ($NH_4Cl$)?

<p>The H-N-H bond angle in ammonia is the same as the H-N-H bond angle in the ammonium ion. (B)</p> Signup and view all the answers

How do the decomposition temperature of Group 2 carbonates and the first ionization energy change as you descend from magnesium to barium?

<p>Decomposition temperature increases, first ionization energy decreases (D)</p> Signup and view all the answers

What is the primary immediate product of the reaction between sulfur dioxide ($SO_2$) and calcium hydroxide in aqueous solution?

<p>CaSO (A)</p> Signup and view all the answers

Flashcards

Temporary Dipoles

Forces between temporary dipoles due to momentary uneven electron distribution.

Autocatalytic Reaction

A reaction where one of the products acts as a catalyst, speeding up the reaction.

Reactions that Produce Water

Reactions that give water as a product, such as esterification or alcohol dehydration.

HX reactions with alcohols

Reactions with concentrated hydrohalic acids (like HBr).

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Alcohol + Carboxylic acid?

Reactions with ethanoic acid

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Alcohol, Heat, and Al2O3

Passing an alcohol vapor over heated aluminum oxide.

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Metallic Bonding

Forces between positive metal ions and the ‘sea’ of delocalized electrons.

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First Ionization Energy

The energy required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions.

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Study Notes

  • This is a Chemistry Paper 1 Multiple Choice exam paper
  • It is for Cambridge International AS & A Level students
  • Exam code is 9701/11
  • The exam is in October/November 2020
  • The exam duration is 1 hour
  • There are 40 questions
  • Each correct answer scores one mark
  • No marks are deducted for wrong answers
  • Candidates need a multiple-choice answer sheet, soft clean eraser, soft pencil (type B or HB), and a data booklet
  • Calculators are permitted

Key Chemistry Concepts and Questions

  • Cl has a relative isotopic mass of 35.5
  • Strontium metal can be extracted from strontium oxide (SrO) by reduction with aluminium
  • A single 32P nucleus is produced when a single 32S nucleus joins with a neutron, emitting a proton in the process
  • Bromine (in liquid form) has only intermolecular forces based on temporary dipoles between the particles
  • Copper has a high melting point due to strong attractive forces between copper ions and delocalised electrons
  • Combustion of graphite and formation of CO2(g) are numerically equal standard enthalpy changes
  • The standard enthalpy of formation of BrF3(l) is -301 kJ mol-1
  • The enthalpy change of BrF3(l) to BrF3(g) is +44 kJ mol-1
  • S(s) + O2(g) → SO2(g) demonstrates the greatest change in oxidation number of sulfur
  • Chlorine is reduced in the chloride process for titanium manufacture
  • In aqueous solution, sulfuric acid dissociates in two stages, the first to completion and the second reaching equilibrium
  • The rate of an autocatalytic reaction, when plotted against time, will show a curve that initially increases then decreases
  • Silicon and Y formulates SiS2
  • Barium is used in agriculture to reduce the acidity of soil
  • 1s²2s²2p⁵ is the strongest oxidising agent
  • Excess calcium (s) + water (I) produces a white, solid product
  • Sodium bromide reacts with concentrated sulfuric acid both as a strong acid and as an oxidising agent
  • The hydrogen atom from HCl donates a lone pair of electrons to the nitrogen atom
  • As Group 2 is descended from magnesium to barium, the first ionisation energy decreases
  • Sulfur dioxide, SO2, reacts with calcium hydroxide in aqueous solution to give CaSO3
  • 2-methylbut-1-ene does not have geometrical isomers
  • 2-methylbut-1-ene reacts with HBr in an addition reaction to give 1-bromo-2-methylbutane as the main product
  • A gas is made which contributes to global warming during the complete combustion of PVC
  • Iodoethane, CH3CH2I, reacts with aqueous silver nitrate at 50 °C through nucleophilic substitution
  • The precipitate that forms during the reaction with Iodoethane, CH3CH2I is yellow
  • The pH in test-tube X is 7
  • The pH in test-tube Y is 2
  • The pH in test-tube Z is 2
  • Methanol, CH3OH, can be produced industrially by reacting CO with H2 with ∆H = -91 kJ mol-1
  • CH3CH(CH3)CH(CH3)2 produced in a termination step during the bromination of propane
  • The process can be carried out at 4 × 103 kPa and 1150K
  • Sodium, Aluminium and sulfur are elements shown correctly
  • The synthesis of 1-iodopropane, C3H7I, into butanoic acid, C3H7CO2H, by a two-stage chemical
  • In the first stage, ethanolic potassium cyanide is reacted with 1-iodopropane
  • Aqueous sulfuric acid, aqueous sodium hydroxide and sodium react with polymer X
  • The molecular formula of compound X is C10H18O
  • Sodium, Aluminium and sulfur are elements shown correctly
  • N2O(g) to N2(g) and O2(g) is exothermic, the reaction between NO and oxygen is exothermic, the decomposition of
  • If N2O(g) is oxidised by O2(g) to NO2(g), 16 kJ is released per mole of N2O
  • Enthalpy of solution of HCl, enthalpy of combustion of H2 = enthalpy of formation of H2O, and enthalpy of hydration of H⁺ + enthalpy of hydration of Cl⁻
  • A(aq) + B(aq) = C(s) + D(aq) has an equilibrium of mol⁻¹ dm³
  • Its only infrared absorption between 2500 and 3000 cm¯¹ is sharp and strong
  • Carvone is found in spearmint oil.
  • The free radical CH3• is generated during the bromination of methane
  • A student converts 1-iodopropane, C3H7I, into butanoic acid, C3H7CO2H, by a two-stage chemical synthesis.
  • Its only infrared absorption between 2500 and 3000 cm¯¹ is sharp and strong.
  • Aqueous sulfuric acid, aqueous sodium hydroxide and sodium react with polymer X.

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