Chemistry: Molarity and Chemical Bonds

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Questions and Answers

What is the relationship between pH and acidity?

  • pH and acidity are directly proportional.
  • Increased pH indicates lower acidity. (correct)
  • Decreased pH indicates lower acidity.
  • pH changes do not affect acidity.

What characterizes a weak acid in terms of pKa?

  • Weak acids do not have a pKa.
  • Weak acids fully dissociate in solution.
  • Weak acids have a low pH.
  • Weak acids have high pKa values. (correct)

Which of the following is a characteristic of a polyprotic acid?

  • It is always a strong acid.
  • It cannot be used in buffers.
  • It can donate only one proton.
  • It has one pKa for each proton it can lose. (correct)

What is the effect of a buffer's maximum buffering capacity?

<p>It can resist changes in pH within a range around pH = pKa. (A)</p> Signup and view all the answers

What is the typical dissociation behavior of a strong acid?

<p>They fully dissociate in solution. (B)</p> Signup and view all the answers

How does an increase of one unit in pH affect hydrogen ion concentration?

<p>It decreases [H+] concentration by 10 times. (A)</p> Signup and view all the answers

What is the formula for the dissociation constant of weak acids (Ka)?

<p>Ka = [H+][A-]/[HA] (A)</p> Signup and view all the answers

Which combination of acids demonstrates monoprotic characteristics?

<p>HCl and CH3COOH (A)</p> Signup and view all the answers

What happens to the pH when acetate salt (CH3COONa) is added to a solution?

<p>It contributes to the formation of a buffer system. (A)</p> Signup and view all the answers

What is the molarity of a solution containing 300 g of NaCl in 700 mL of solution?

<p>7.33 M (A)</p> Signup and view all the answers

Which functional group is characterized by a nitrogen atom bonded to at least one hydrogen atom?

<p>Amino group (B)</p> Signup and view all the answers

What is a correct statement about a buffer solution?

<p>It consists of a weak acid and its conjugate base. (D)</p> Signup and view all the answers

Which of the following statements accurately describes acids and bases?

<p>Acids are proton donors. (B)</p> Signup and view all the answers

If the concentration of H+ ions in a solution increases, what is the effect on pH?

<p>pH decreases (A)</p> Signup and view all the answers

What type of bond is primarily responsible for the interactions in a buffer system?

<p>Hydrogen bonds (A)</p> Signup and view all the answers

What is the correct interpretation of pH = -log[H+]?

<p>pH is inversely proportional to H+ concentration. (D)</p> Signup and view all the answers

In a neutral solution, what is the relationship between [H+] and [OH-]?

<p>[H+] = [OH-] (D)</p> Signup and view all the answers

Which of the following is NOT a functional group found in organic chemistry?

<p>Sodium group (B)</p> Signup and view all the answers

The increase in acidity of a solution corresponds to which change in pH?

<p>Decrease in pH (C)</p> Signup and view all the answers

What does molarity quantify?

<p>The concentration of a solute in a solution (C)</p> Signup and view all the answers

If the molarity of a solution is 2 M, how many moles are there in 1 liter of solution?

<p>2 moles (B)</p> Signup and view all the answers

How is the number of moles calculated from mass?

<p>Mass (g) / Molar mass (g/mole) (A)</p> Signup and view all the answers

What is Avogadro's number?

<p>6.022 × 10²³ (A)</p> Signup and view all the answers

What is the correct formula to calculate molarity?

<p>M = No. of moles / Volume (L) (B)</p> Signup and view all the answers

What unit is used for molar mass?

<p>g/mol (B)</p> Signup and view all the answers

What mass of NaCl is present in 0.3 kg for calculating molarity?

<p>300 g (B)</p> Signup and view all the answers

If 0.3 kg of NaCl is dissolved in 700 mL of water, how many liters does this represent for calculations?

<p>0.7 L (D)</p> Signup and view all the answers

What is the equivalent of one Dalton in terms of molar mass?

<p>1/6 of the mass of 12C (C)</p> Signup and view all the answers

In terms of concentration, what does the term 'molar concentration' refer to?

<p>Amount of solute per volume of solution (C)</p> Signup and view all the answers

What formula represents the calculation of molarity?

<p>Molarity = number of moles / Solution volume (L) (C)</p> Signup and view all the answers

If the mass of a substance is 7.3 kg and its molar mass is 300 g/mol, how many moles does it contain?

<p>24.33 moles (A)</p> Signup and view all the answers

What is the unit of volume used in the molarity formula?

<p>Liters (L) (B)</p> Signup and view all the answers

To find the number of moles using mass and molar mass, which formula is used?

<p>Number of moles = mass / molar mass (B)</p> Signup and view all the answers

If a solution has a molarity of 1 M and a volume of 2 L, how many moles of solute are present?

<p>2 moles (A)</p> Signup and view all the answers

What is the result of dividing mass by molar mass?

<p>Number of moles (B)</p> Signup and view all the answers

Using a molar mass of 300 g/mol, how many grams are in 5 moles of a substance?

<p>1500 g (D)</p> Signup and view all the answers

A solution is prepared with 4 moles of solute in 2 L of solution. What is the molarity of the solution?

<p>2 M (D)</p> Signup and view all the answers

Which of the following could mislead one regarding the definition of molarity?

<p>It should be calculated using mass alone (D)</p> Signup and view all the answers

What does a higher molarity indicate about a solution?

<p>It contains more solute per unit volume (B)</p> Signup and view all the answers

Flashcards

Molarity

A measure of concentration, expressed as the number of moles of solute per liter of solution.

Solution volume

The total volume of the solution, measured in liters.

Number of moles

The amount of a substance contained in a given mass, expressed in moles.

Molar mass

The mass of one mole of a substance, typically measured in grams/mole.

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Solute

The substance that is dissolved in a solution.

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Solvent

The substance that dissolves the solute to form a solution.

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Concentration

A measure of how much solute is present in a given amount of solvent or solution.

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Periodic table

A table of the chemical elements, organized by atomic number.

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Mole

The SI base unit for amount of substance.

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Solution

A homogeneous mixture of two or more substances.

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Molarity

A measure of concentration, expressed as the number of moles of solute per liter of solution.

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Molar Concentration

Another term for molarity, expressing a substance's concentration in moles per liter.

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Moles

A unit of measurement representing 6.022 x 10^23 units of a substance (atoms, molecules, or ions).

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Molar Mass

The mass of one mole of a substance, usually measured in grams/mole.

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Avogadro's Number

The constant 6.022 x 10^23, representing the number of particles in one mole of a substance.

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Solute

The substance being dissolved in a solution.

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Solution

A homogeneous mixture of two or more substances

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Mole Calculation

Calculating the number of moles from mass or vice-versa.

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Unit of Molarity

M (Molar) or mol/L (moles per liter).

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Formula for Moles

Number of Moles = Mass (g) / Molar Mass (g/mol).

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Molarity Definition

Molarity is a measure of substance concentration, calculated by dividing solute moles by solution liters.

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Acid Definition

An acid is a substance that donates a proton (H+).

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Base Definition

A base is a substance that accepts a proton (H+).

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pH Definition

pH measures the concentration of H+ ions in a solution.

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pH Scale

The pH scale measures acidity and basicity ranges from 0-14.

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Buffer Definition

A buffer solution resists changes in pH.

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Hydroxyl Group

A functional group in chemistry containing an oxygen and a hydrogen atom.

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Carbonyl Group

A functional group in chemistry containing a carbon and an oxygen atom forming a double bond.

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Carboxyl Group

A functional group in chemistry containing a carbon, oxygen and hydroxyl functional group.

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Functional Groups

Specific arrangements of atoms within molecules that give characteristic chemical properties.

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Ammonia Buffer

Ammonia (NH3) reacts with water to form ammonium ions (NH4+) and hydroxide ions (OH-), creating a buffer solution. The reaction shows that ammonia acts as a base.

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Buffer Solution

A solution that resists changes in pH when small amounts of acid or base are added.

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Weak Acid Dissociation Constant (Ka)

A measure of the extent to which a weak acid dissociates in water.Indicates how easily an acid releases a proton. Smaller Ka value equals weaker acid.

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pKa

The negative logarithm of the acid dissociation constant (Ka). A measure of how strong or weak an acid is.

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pKa Relationship to Strength

The lower the pKa value, the stronger the acid, and the larger the pKa value, the weaker the acid.

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Monoprotic Acid

An acid that can donate only one proton (H+) per molecule in a reaction.

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Polyprotic Acid

An acid that can donate more than one proton (H+) per molecule in a reaction.

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Buffering Capacity

The ability of a buffer to resist changes in pH.

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pH and [H+]

pH is inversely proportional to the concentration of hydrogen ions ([H+]). A decrease in pH represents a 10-fold increase in [H+].

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Buffer Range

The pH range over which a buffer solution effectively resists changes in pH. pKa ± 1.

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Study Notes

Molarity

  • Molarity is a concentration measure.
  • It's the number of moles of solute per liter of solution.
  • Expressed as M (molar) or mol/L.
  • Formula: Molarity (M) = moles of solute / liters of solution
  • Moles of solute = mass of solute (g) / molar mass (g/mol)

Calculating Molarity

  • Example: Find the molarity of 0.3 kg NaCl dissolved in 700 mL water.
  • Mass of NaCl = 300 g
  • Molar mass of NaCl = 58.44 g/mol
  • Volume of solution = 0.7 L
  • Moles of NaCl = 300 g / 58.44 g/mol = 5.1 moles
  • Molarity = 5.1 moles / 0.7 L = 7.33 M (or 7.33 mol/L)

Types of Chemical Bonds

  • Ionic Bond: Bond formed by transferring electrons.
  • Covalent Bond: Bond formed by sharing electrons.
  • Polar Covalent Bond: Covalent bond where electrons are shared unevenly.
  • Non-Polar Covalent Bond: Covalent bond where electrons are shared equally.
  • Hydrogen Bond: Weak bond between a hydrogen atom and an electronegative atom.
  • Metallic Bond: Bond formed by the attraction between metal ions and delocalized electrons.

Functional Groups

  • Hydroxyl group (-OH): Found in alcohols.
  • Carbonyl group (C=O): Found in ketones and aldehydes.
  • Carboxyl group (-COOH): Found in carboxylic acids.
  • Amino group (-NH2): Found in amines.
  • Sulfhydryl group (-SH): Found in thiols.
  • Phosphate group (-OPO32-): Found in organic phosphates.
  • Methyl group (-CH3): Modifies the function of molecules.

Acids and Bases

  • Acid: A proton donor.
  • Base: A proton acceptor.
  • pH: A measure of the concentration of H+ ions in a solution.
    • pH = -log[H+]
    • Higher H+ concentration, lower pH (more acidic)
  • Buffer: A solution that resists changes in pH when small amounts of acid or base are added.
  • Buffers are composed of a weak acid/base and its conjugate.
  • Ka: Dissociation constant of weak acids.
  • pKa: The negative logarithm of Ka. Indicates the acidity of a weak acid. Weak acids have a pKa value.

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