Chemistry: Ionic and Covalent Bonding

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

Which type of intermolecular force is the weakest?

  • Lattice Forces
  • Hydrogen Bonding
  • Permanent Dipole
  • Van der Waals Forces (correct)

Hydrogen bonds can only form between hydrogen and the most electronegative atoms: nitrogen, oxygen, and fluorine.

True (A)

What causes induced dipoles to form?

Influence of another charged particle on the electron orbitals of a molecule.

Molecules with straight chains experience stronger van der Waals forces than __________ chain molecules.

<p>branched</p> Signup and view all the answers

Match the intermolecular force with its description:

<p>Van der Waals Forces = Weakest intermolecular force, induced dipole Permanent Dipole = Acts between molecules with polar bonds Hydrogen Bonding = Strongest intermolecular force involving H and electronegative atoms</p> Signup and view all the answers

What is the effect of hydrogen bonding on the physical properties of a substance?

<p>Higher melting and boiling points (B)</p> Signup and view all the answers

The strength of Van der Waals forces does not depend on the molecular weight (Mr) of the molecule.

<p>False (B)</p> Signup and view all the answers

What type of structure do polar molecules with permanent dipoles form?

<p>Lattice-like structure</p> Signup and view all the answers

What is the bond angle for a linear molecule?

<p>180° (B)</p> Signup and view all the answers

Lone pairs increase the bond angle between covalent bonds.

<p>False (B)</p> Signup and view all the answers

How many lone pairs are present in a trigonal pyramid shape?

<p>1</p> Signup and view all the answers

Electronegativity increases along a ______ as atomic radius decreases.

<p>period</p> Signup and view all the answers

Match the molecular shape with the number of bonding pairs and bond angle:

<p>Tetrahedral = 4 bonding pairs, 109.5° V-Shaped = 2 bonding pairs, 104.5° Trigonal Planar = 3 bonding pairs, 120° Octahedral = 6 bonding pairs, 90°</p> Signup and view all the answers

What is the bonded shape and bond angle for a molecule with 5 bonding pairs?

<p>Trigonal Bipyramid, 90° and 120° (C)</p> Signup and view all the answers

A permanent dipole is formed when two atoms have identical electronegativities.

<p>False (B)</p> Signup and view all the answers

What power does an atom have to attract negative charge towards itself within a covalent bond?

<p>Electronegativity</p> Signup and view all the answers

What type of bonding occurs between a metal and a non-metal?

<p>Ionic bonding (D)</p> Signup and view all the answers

Electrons in ionic bonding are shared between atoms.

<p>False (B)</p> Signup and view all the answers

What is produced when sodium loses an electron?

<p>Sodium ion (Na+)</p> Signup and view all the answers

The charged particles produced in ionic bonding are called _____ .

<p>ions</p> Signup and view all the answers

Which of the following is an example of a common compound ion?

<p>Sulfate (SO4^2-) (B)</p> Signup and view all the answers

Match the type of bond with its description:

<p>Ionic Bonding = Electrons are transferred from one atom to another Covalent Bonding = Electrons are shared between two non-metals Dative Bonding = Electrons in the shared pair come from one atom Metallic Bonding = Positive metal ions are surrounded by a sea of electrons</p> Signup and view all the answers

Dative bonding involves both electrons in a shared pair coming from two different atoms.

<p>False (B)</p> Signup and view all the answers

What does nitrogen in ammonia (NH3) contribute to form an ammonium ion (NH4+)?

<p>A lone electron pair</p> Signup and view all the answers

Which of the following statements about simple molecular substances is true?

<p>They are poor conductors because they contain no charged particles. (D)</p> Signup and view all the answers

Graphite is a macromolecular structure with flat sheets of carbon atoms that can conduct electricity.

<p>True (A)</p> Signup and view all the answers

What type of bonding primarily takes place in diamond?

<p>Covalent bonding</p> Signup and view all the answers

Mercury is the only liquid metal at __________ temperature.

<p>room</p> Signup and view all the answers

Match the following structures with their characteristics:

<p>Simple Molecular = Low melting and boiling points Macromolecular = Rigid and high melting point Diamond = Hardest material known Graphite = Conducts electricity</p> Signup and view all the answers

What is the effect of lone pairs on molecular shape?

<p>They decrease the bond angle. (D)</p> Signup and view all the answers

Water has a low boiling point due to its simple molecular structure.

<p>False (B)</p> Signup and view all the answers

What type of intermolecular force exists between molecules in simple molecular substances?

<p>Van der Waals forces</p> Signup and view all the answers

Larger ions, such as Barium, produce a stronger attractive force in metallic bonding.

<p>False (B)</p> Signup and view all the answers

What are two physical properties of substances with ionic structures?

<p>High melting point and brittleness</p> Signup and view all the answers

Substances with a ________ structure can conduct electricity when molten or in solution.

<p>ionic</p> Signup and view all the answers

Match the following properties with the type of bonding:

<p>Metallic = Good conductor of electricity Ionic = High melting and boiling points Simple molecular = Low boiling points Macromolecular = High melting points and hard materials</p> Signup and view all the answers

When the layers of alternating charges in ionic structures are distorted, they tend to break apart into fragments.

<p>True (A)</p> Signup and view all the answers

What is the effect of delocalised electrons in metallic bonding?

<p>They allow the material to conduct electricity and provide malleability.</p> Signup and view all the answers

The electrostatic forces between positively charged ions and ________ electrons in metallic bonding are very strong.

<p>delocalised</p> Signup and view all the answers

Flashcards

Covalent Bonding

A chemical bond formed between two non-metals by the sharing of electrons.

Dative Bonding

A type of covalent bond where both electrons in the shared pair come from the same atom.

Ionic Bonding

A chemical bond formed between a metal and a non-metal by the transfer of electrons.

Ion

A charged particle formed when an atom gains or loses electrons.

Signup and view all the flashcards

Giant Ionic Lattice

A large, repeating three-dimensional structure held together by electrostatic forces between oppositely charged ions.

Signup and view all the flashcards

Dot and Cross Diagram

A diagram that shows the arrangement of electrons in an atom or molecule.

Signup and view all the flashcards

Covalency

The number of covalent bonds an atom forms, which depends on the number of electrons it needs to share to achieve a full outer shell.

Signup and view all the flashcards

Polyatomic Ion Compound

A chemical compound with a distinct formula that consists of a single type of ion and another polyatomic ion.

Signup and view all the flashcards

Metallic bonding model

A model of metallic bonding where positively charged ions are arranged in a lattice and surrounded by a sea of delocalized electrons.

Signup and view all the flashcards

Electrostatic force in metallic bonding

The strength of the electrostatic attraction between the positive ions and the delocalised electrons in a metallic lattice. This force is determined by the charge on the ions and their size.

Signup and view all the flashcards

Electrical conductivity in metals

Metals are good conductors of electricity due to the movement of delocalised electrons, which carry charge.

Signup and view all the flashcards

Malleability of metals

Metals are malleable because the layers of positive ions can slide over each other without breaking the metallic bond. Delocalised electrons allow for this movement.

Signup and view all the flashcards

Melting point of metals

Metals have high melting points due to the strong electrostatic forces of attraction between the positive ions and delocalised electrons.

Signup and view all the flashcards

Metallic crystal structure

A type of crystal structure characterized by a lattice of positively charged ions surrounded by a sea of delocalised electrons.

Signup and view all the flashcards

Physical properties

Physical properties of a substance are characteristics that can be observed without changing the substance's chemical composition. Examples include melting point, boiling point, and conductivity.

Signup and view all the flashcards

Bonding and crystal structures

Different types of bonding, such as ionic, metallic, covalent, and van der Waals, create different crystal structures, leading to varying physical properties.

Signup and view all the flashcards

Van der Waals forces

A type of intermolecular force that acts between molecules, holding them together in a structure. They are much weaker than covalent bonds.

Signup and view all the flashcards

Simple Molecular Substances

Substances with a simple molecular structure consist of molecules held together by weak van der Waals forces. These substances have low melting and boiling points and are poor conductors of electricity.

Signup and view all the flashcards

Macromolecular Substances

Substances with a macromolecular structure are covalently bonded into a giant lattice structure. Each atom has multiple strong covalent bonds, resulting in high melting points and rigidity.

Signup and view all the flashcards

Diamond

A giant lattice structure made up of carbon atoms, each bonded to four other carbon atoms. Its strong covalent bonds make it one of the hardest and strongest materials known.

Signup and view all the flashcards

Graphite

Another macromolecular structure made up of carbon atoms, but with a layered structure. Each carbon atom is bonded to three others in flat sheets, with free electrons moving between these layers, allowing it to conduct electricity.

Signup and view all the flashcards

Molecular Shape

The shape of a molecule is determined by the number of electron pairs around the central atom. Electron pairs repel each other, resulting in the largest possible bond angles between covalent bonds.

Signup and view all the flashcards

Lone Pair Repulsion

Lone pairs of electrons around the central atom create additional repulsive forces, which changes the bond angles between covalent bonds.

Signup and view all the flashcards

Mercury

Mercury is the only metal that is liquid at room temperature.

Signup and view all the flashcards

Electronegativity

The tendency of an atom to attract electrons towards itself when forming a covalent bond.

Signup and view all the flashcards

Lone Pair Effect

The reduction in the angle between covalent bonds caused by the presence of lone pairs.

Signup and view all the flashcards

Polar Molecule

A molecule with two bonded atoms having different electronegativities, resulting in an uneven distribution of charge.

Signup and view all the flashcards

Polar Covalent Bond

A covalent bond where the electrons are not shared equally, creating a separation of charge due to differences in electronegativity.

Signup and view all the flashcards

Permanent Dipole

A molecule with a permanent separation of charge due to a difference in electronegativity between the bonded atoms.

Signup and view all the flashcards

Molecular Geometry

The arrangement of atoms and lone pairs in a molecule, determining its shape and properties.

Signup and view all the flashcards

Electronegativity Trend: Down a Group

A decrease in electronegativity as you move down a group in the periodic table.

Signup and view all the flashcards

Electronegativity Trend: Across a Period

An increase in electronegativity as you move across a period in the periodic table.

Signup and view all the flashcards

Permanent dipole-dipole Interactions

Interaction between molecules with permanent dipoles, where the positive and negative ends of one molecule attract opposite ends of another molecule, creating a lattice structure.

Signup and view all the flashcards

Hydrogen Bonding

The strongest type of intermolecular force. It arises from a special dipole-dipole interaction between a hydrogen atom bonded to a highly electronegative atom (N, O or F) and a lone pair of electrons on an adjacent molecule.

Signup and view all the flashcards

Induced Dipole

A temporary dipole induced in a molecule due to the presence of an external charged particle or a nearby permanent dipole. This induces a temporary uneven charge distribution within the molecule.

Signup and view all the flashcards

Intermolecular Forces

The forces acting between molecules, holding them together in a substance. They are weaker than intramolecular forces (like covalent bonds) within a molecule.

Signup and view all the flashcards

Impact of Hydrogen Bonding on Physical Properties

Higher melting and boiling points for substances with hydrogen bonding compared to non-hydrogen bonded molecules. This is because stronger intermolecular forces require more energy to break.

Signup and view all the flashcards

Study Notes

Ionic Bonding

  • Ionic bonding occurs between a metal and a non-metal.
  • Electrons are transferred from the metal to the non-metal to achieve full outer shells.
  • This creates charged particles called ions.
  • Oppositely charged ions attract through electrostatic forces to form a giant ionic lattice.
  • Example: Sodium chloride (NaCl) forms sodium ions (Na⁺) and chloride ions (Cl⁻).

Covalent Bonding

  • Covalent bonds form between two non-metals.
  • Electrons are shared between the two outer shells to achieve full outer shells.
  • Multiple electron pairs can be shared to form multiple covalent bonds.
  • Shared electron pairs are represented using dot-and-cross diagrams or with a straight line.
  • Example: Chlorine gas (Cl₂) shares a pair of electrons to form a single covalent bond.

Dative (Coordinate) Bonding

  • This occurs when both electrons in the shared pair are supplied by a single atom.
  • It is shown as an arrow from lone electron pair to the atom accepting the pair.
  • Example: In ammonium ion (NH₄⁺), a lone electron pair on nitrogen forms a dative bond with a hydrogen ion (H⁺).

Metallic Bonding

  • Metallic bonding involves a lattice of positively charged ions surrounded by a "sea" of delocalised electrons.
  • The electrostatic force of attraction between the oppositely charged particles is very strong.
  • Example: Metals like Aluminium (Al) have a metallic structure.
  • The greater the charge on the positive ion, the stronger the attractive force.
  • Larger ions (e.g., Barium) create weaker attractions due to their larger size.

Types of Crystal Structures

  • There are four main types: ionic, metallic, simple molecular, and macromolecular.
  • Each type has different physical properties, including melting point, boiling point, conductivity, and solubility.

Ionic Substances

  • Ionic substances have high melting and boiling points due to strong electrostatic forces.
  • They are brittle because of repulsion between like charges when layers are disturbed.
  • They conduct electricity when molten or dissolved in water because the ions are free to move and carry charge.

Metallic Substances

  • Metallic substances are often good conductors due to the mobile sea of delocalised electrons.
  • They are malleable because layers of positive ions can slide past each other.
  • They generally have high melting and boiling points.

Simple Molecular Substances

  • Simple molecular substances have low melting and boiling points due to weak intermolecular forces (van der Waals forces).
  • They are poor conductors due to the lack of charged species.
  • Example: Iodine (I₂).

Macromolecular Substances

  • Macromolecular substances have very high melting and boiling points due to strong covalent bonds in a giant lattice.
  • They are generally rigid and strong.
  • Example: Diamond (carbon) and graphite (carbon).

Molecular Shape

  • Molecular shape is determined by the number and arrangement of electron pairs around the central atom.
  • Lone pairs repel bonding pairs more strongly, which affects the bond angles.
  • Common shapes include linear, V-shaped, trigonal planar, trigonal pyramidal, tetrahedral, trigonal bipyramidal, and octahedral.
  • The table shows examples of each shape.

Bond Polarity

  • Electronegativity is the power of an atom to attract a shared pair of electrons in a covalent bond.
  • Differences in electronegativity create polar bonds, with the more electronegative atom having a partial negative charge.
  • Polar molecules can form lattices of molecules.
  • Example: Hydrogen fluoride (HF).

Intermolecular Forces

  • These forces act between molecules.
  • Intermolecular forces include van der Waals forces, permanent dipole-dipole interactions, and hydrogen bonds.
  • Hydrogen bonds are the strongest, and they are responsible for the relatively high boiling point of water.

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

Related Documents

More Like This

Ionic and Covalent Bonding Quiz
10 questions
Ionic vs Covalent Bonding Properties
12 questions
Ionic, Covalent & Metallic Bonding
18 questions
Use Quizgecko on...
Browser
Browser