Chemistry Group 15 Quiz

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Questions and Answers

What is the primary reason nitrogen behaves differently from other elements in Group 15?

  • It has the highest atomic mass.
  • It exists in a gaseous state. (correct)
  • It has the highest boiling point.
  • It has the lowest ionization energy.

What is formed when $PH_3$ reacts with HCl?

  • Phosphonium hydroxide
  • Phosphoric acid
  • Phosphonium chloride (correct)
  • Phosphonium nitrate

Which element in Group 15 has the highest electronegativity?

  • Phosphorus (P)
  • Arsenic (As)
  • Nitrogen (N) (correct)
  • Antimony (Sb)

What type of hydride is formed when arsenic reacts with hydrogen?

<p>Arsenic hydride (C)</p> Signup and view all the answers

What is the product of the reaction between PCl3 and water?

<p>Phosphorous acid (C)</p> Signup and view all the answers

Why does $NH_3$ have a higher boiling point than $PH_3$?

<p>Because of hydrogen bonding. (A)</p> Signup and view all the answers

What is the boiling point of phosphorous trichloride (PCl3)?

<p>347K (C)</p> Signup and view all the answers

What is produced when PCl5 reacts with water?

<p>Phosphoric acid (D)</p> Signup and view all the answers

When elements of Group 15 react with oxygen, what compounds are primarily formed?

<p>Trioxides and pentoxides (D)</p> Signup and view all the answers

Which of the following represents a reaction that produces phosphorous pentachloride?

<p>P4 + 10Cl2 → 4PCl5 (D)</p> Signup and view all the answers

Which of the following reactions produces hydrogen fluoride?

<p>2H2O + 2F2 → 4HF + O2 (A)</p> Signup and view all the answers

What is the electronic configuration of elements in group 18?

<p>ns^2np^6 (B)</p> Signup and view all the answers

Which compound is formed when phosphorus reacts with bromine?

<p>PBr5 (A), PBr3 (B)</p> Signup and view all the answers

Which of the following is NOT an element of group 18?

<p>Bromine (A)</p> Signup and view all the answers

Which of these compounds represents an interhalogen molecule?

<p>BrCl3 (D)</p> Signup and view all the answers

What is formed when sulphur reacts with oxygen?

<p>Sulphur dioxide ($SO_2$) (D)</p> Signup and view all the answers

What is the boiling point of sulphur dioxide ($SO_2$)?

<p>263K (D)</p> Signup and view all the answers

What compound is produced when $SO_2$ reacts with water?

<p>Sulphurous acid ($H_2SO_3$) (D)</p> Signup and view all the answers

Which catalyst is used in the contact process for producing sulphuric acid?

<p>Vanadium pentaoxide ($V_2O_5$) (B)</p> Signup and view all the answers

What is the product of the reaction between zinc and sulphuric acid ($H_2SO_4$)?

<p>Zinc sulphate ($ZnSO_4$) (D)</p> Signup and view all the answers

What is the product formed when nitric acid reacts with carbon?

<p>Carbon dioxide (C)</p> Signup and view all the answers

Which acid is produced when nitric acid reacts with sulphur?

<p>Sulphuric acid (D)</p> Signup and view all the answers

What is the final product when phosphorous reacts with nitric acid?

<p>Phosphoric acid (D)</p> Signup and view all the answers

Which of the following is a property of white phosphorus?

<p>It is a waxy solid (A)</p> Signup and view all the answers

What is the chemical formula of hypophosphorous acid?

<p>$H_3PO_2$ (A)</p> Signup and view all the answers

What gas is produced when phosphorous reacts with sodium hydroxide and water?

<p>Phosphine (C)</p> Signup and view all the answers

Which of the following statements about red phosphorus is true?

<p>It is odorless (C)</p> Signup and view all the answers

What is the result of zinc reacting with dilute nitric acid?

<p>Zinc nitrate and water (D)</p> Signup and view all the answers

What is the common oxidation state of elements in group 17?

<p>+7, -1 (A)</p> Signup and view all the answers

Which element in group 17 is a gas at room temperature?

<p>Fluorine (B)</p> Signup and view all the answers

Which of the following elements in group 17 has the highest electronegativity?

<p>Fluorine (B)</p> Signup and view all the answers

What happens when a metal of group 17 reacts with hydrogen?

<p>A hydrogen halide is formed (D)</p> Signup and view all the answers

Which of the following statements about the acidic character of hydrogen halides is correct?

<p>HI is stronger than HF (A)</p> Signup and view all the answers

Which element in group 17 is solid at room temperature?

<p>Iodine (C)</p> Signup and view all the answers

In terms of atomic size and radius, what trend occurs as you move down group 17?

<p>Atomic size increases (D)</p> Signup and view all the answers

Which statement regarding ionization energy of group 17 elements is true?

<p>Ionization energy decreases down the group (C)</p> Signup and view all the answers

Flashcards

Electronegativity trend in Group 15

Electronegativity generally decreases down Group 15.

Phosphorus electronegativity

Phosphorus has an electronegativity of 2.1 eV (electron volts).

Melting and Boiling points in Group 15

Melting and boiling points generally increase down Group 15.

Nitrogen's Anomalous Behavior

Nitrogen exhibits unique properties compared to other elements in Group 15 due to its small size and high electronegativity.

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Nitrogen state of matter

Nitrogen exists as a gas at room temperature.

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Group 15 Hydrides formation

Group 15 elements react with hydrogen to form hydrides of the type EH₃.

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Ammonia (NH₃) Hydrogen bonding

Ammonia forms hydrogen bonds due to nitrogen's high electronegativity.

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Difference in boiling points of NH₃ and PH₃

NH₃ has a higher boiling point than PH₃ because of stronger hydrogen bonding in NH₃.

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PH3 reaction with HCl

PH3 reacts with HCl to form phosphonium chloride (PH4Cl).

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PH3 reaction with H2O

PH3 reacts with water to form phosphonium hydroxide (PH4OH).

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PH3 reaction with HNO3

PH3 reacts with nitric acid (HNO3) to form phosphonium nitrate (PH4NO3).

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PCl3 preparation (reaction 1)

Phosphorus (P4) reacts with chlorine (Cl2) to produce phosphorus trichloride (PCl3).

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PCl3 preparation (reaction 2)

Phosphorus (P4) and thionyl chloride (SOCl2) react to form phosphorus trichloride (PCl3), sulfur dioxide (SO2), and disulfur dichloride (S2Cl2).

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PCl3 reaction with water

PCl3 reacts with water to form phosphorous acid (H3PO3) and hydrochloric acid (HCl).

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PCl3 reaction with oxygen

PCl3 reacts with oxygen to produce phosphorus oxychloride (POCl3).

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PCl5 preparation

Phosphorus (P4) reacts with excess chlorine (Cl2) to produce phosphorus pentachloride (PCl5).

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PCl5 reaction with water

PCl5 reacts with water to form phosphoric acid (H3PO4) and hydrochloric acid (HCl).

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PCl5 reaction with SO2

PCl5 reacts with sulfur dioxide (SO2) to form thionyl chloride (SOCl2) and phosphorus oxychloride (POCl3).

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PCl5 decomposition

Heating PCl5 results in the formation of PCl3 and chlorine gas (Cl2).

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Group 16 elements

Elements in Group 16 of the periodic table are called the oxygen family.

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Sulphur Dioxide Formation

Burning sulphur in air or reacting FeS2 with oxygen produces sulphur dioxide.

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SO2 Properties

Colorless gas with a pungent smell, soluble in water, boiling point 263K.

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SO2 Reaction with Water

SO2 reacts with water to form sulphurous acid (H2SO3).

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SO2 Reaction with Oxygen

SO2 reacts with oxygen to form sulphur trioxide (SO3).

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SO2 Reaction with Chlorine

SO2 reacts with chlorine to produce Sulphoryl Chloride (SO2Cl2).

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Contact Process

A process for manufacturing sulphuric acid, involving reactions of sulphur, oxygen, and V2O5.

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Sulphuric Acid (H2SO4) Properties

Colorless oily liquid, freezing point 283K, boiling point 611K, specific gravity 1.83.

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H2SO4 Reaction with Copper

Copper reacts with H2SO4 to form copper sulphate and hydrogen gas.

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H2SO4 Reaction with Zinc

Zinc reacts with H2SO4 to form zinc sulphate and hydrogen gas.

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Halogens

Elements of Group 17 in the periodic table.

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HNO3 reaction with carbon

Nitric acid (HNO3) reacts with carbon (C) to produce carbon dioxide (CO2), water (H2O), and nitrogen dioxide (NO2).

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HNO3 reaction with sulphur

Nitric acid (HNO3) reacts with sulfur (S) to form sulphuric acid (H2SO4), nitrogen dioxide (NO2), and water (H2O).

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HNO3 reaction with phosphorous

Nitric acid (HNO3) reacts with phosphorous (P) to form phosphoric acid (H3PO4), nitrogen dioxide (NO2), and water (H2O).

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HNO3 reaction with iodine

Nitric acid (HNO3) reacts with iodine (I2) to form iodic acid (HIO3), nitrogen dioxide (NO2), and water (H2O).

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HNO3 reaction with zinc (dilute)

Zinc (Zn) reacts with dilute nitric acid (HNO3) to produce zinc nitrate (Zn(NO3)2), water (H2O), and nitrous oxide (N2O).

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HNO3 reaction with copper (dilute)

Copper (Cu) reacts with dilute nitric acid (HNO3) to produce copper nitrate (Cu(NO3)2), water (H2O), and nitrogen monoxide (NO).

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HNO3 reaction with copper (concentrated)

Copper (Cu) reacts with concentrated nitric acid (HNO3) to produce copper nitrate (Cu(NO3)2,) nitrogen dioxide (NO2), and water (H2O).

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HNO3 reaction with zinc (concentrated)

Zinc (Zn) reacts with concentrated nitric acid (HNO3) to produce zinc nitrate (Zn(NO3)2), nitrogen dioxide (NO2), and water (H2O).

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White phosphorus

A highly reactive, waxy solid form of phosphorus, found as P4, soluble in carbon disulfide.

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Red phosphorus

A less reactive form of phosphorus, obtained by heating white phosphorus, insoluble in water.

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Black phosphorus

A form of phosphorus created by high-pressure heating of red phosphorus.

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Hypophosphorous acid

A weak acid with the formula H3PO2. It mainly contains P-H bonds.

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Phosphorous acid

A weak acid with the formula H3PO3. It has P-H bonds.

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Phosphoric acid

A weak polyprotic acid with the formula H3PO4. It contains P-OH bonds.

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Cyclometaphosphoric acid

A cyclic polymer of phosphoric acid with the formula (HPO3)3. Contains multiple P atoms in a ring.

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Phosphine preparation

Phosphorous reacts with sodium hydroxide and water to produce phosphine (PH3).

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Phosphine properties

A colorless, poisonous gas that is soluble in water, with a rotten fish odour.

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Phosphorus halides reaction

Phosphorus reacts with halogens like chlorine, fluorine, bromine, to form phosphorus trihalides (PX3) and phosphorus pentahalides (PX5).

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Group 17 elements & water reaction

Halogens react with water to produce hydrogen halide and oxygen.

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Group 17 elements & metal reaction

Halogens react with metals to form metal halides.

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Interhalogen compounds

Interhalogen compounds are formed when halogens of different sizes combine.

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Group 18 elements

Group 18 elements are also known as noble gases or inert gases.

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Group 18 electronic configuration

Group 18 elements have a full outer electron shell (ns²np⁶).

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Group 18 oxidation state

Generally, the oxidation state of group 18 elements is zero.

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Group 18 elements examples

Examples of group 18 elements include helium, neon, argon, krypton, xenon, and radon.

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Physical state of Group 18

Group 18 elements are all gases at room temperature.

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Group 17 Oxidation State

The most common oxidation state of Group 17 elements is +7 and -1.

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Group 17 Electronic Configuration

The general electronic configuration of Group 17 elements is ns²np⁵.

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Fluorine Physical State

Fluorine (F) is a gas at room temperature.

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Chlorine Physical State

Chlorine (Cl) is a liquid at room temperature.

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Bromine Physical State

Bromine (Br) is a liquid at room temperature.

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Iodine Physical State

Iodine (I) is a solid at room temperature.

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Halogen Reactivity Trend

Halogen reactivity decreases down the group.

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Atomic Size Trend (Group 17)

Atomic size generally increases down the group in Group 17.

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Ionization Energy Trend (Group 17)

Ionization energy generally decreases down the group in Group 17.

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Metallic Character Trend (Group 17)

Metallic character decreases down the group in Group 17.

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Electronegativity Trend (Group 17)

Electronegativity generally decreases down the group in Group 17.

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Reaction with Hydrogen

Halogens react with hydrogen to form hydrogen halides.

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HI vs. HF Acidity

HI is a stronger acid than HF due to bond strength differences.

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Halogen Reactivity

Reactivity of halogens decreases as you go down the group.

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Study Notes

Inorganic Chemistry - Group 15

  • Group 15 elements (nitrogen family) include nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), and bismuth (Bi).
  • General electronic configuration of group 15 elements is ns2np3.
  • Common oxidation states are +5 and -3.
  • Nitrogen exists as a diatomic gas (N2).
  • Phosphorus exists as white, red, and black allotropes.
  • Arsenic, antimony, and bismuth are solids.
  • Density increases down the group.
  • Atomic size/atomic radius increases down the group.
  • Ionisation energy decreases down the group.
  • Metallic character increases down the group.
  • Electronegativity decreases down the group.

Inorganic Chemistry - Group 16

  • Group 16 elements are known as the oxygen family.
  • Elements include oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and polonium (Po).
  • General electronic configuration of group 16 elements is ns2np4.
  • Common oxidation states are +4, +6, and -2.
  • Oxygen is a diatomic gas (O2).
  • Sulfur is a solid with several allotropes.
  • Selenium, tellurium, and polonium are solids.
  • Density increases down the group.
  • Atomic size/atomic radius increases down the group.
  • Ionisation energy decreases down the group.

Inorganic Chemistry - Group 17

  • Group 17 elements are called halogens.
  • Elements include fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At).
  • General electronic configuration of group 17 elements is ns2np5.
  • Common oxidation states are +1, +3, +5, and +7.
  • Fluorine, chlorine, bromine, and iodine are non-metals.
  • Astatine is a radioactive element.
  • Density increases down the group.
  • Atomic size/atomic radius increases down the group.
  • Ionisation energy decreases down the group.
  • Metallic character increases down the group.
  • Electronegativity decreases down the group.

Inorganic Chemistry - Group 18

  • Group 18 elements are called noble gases.
  • Elements include helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), and radon (Rn).
  • General electronic configuration of group 18 elements is ns2np6.
  • Common oxidation state is zero.
  • Mostly monoatomic gases.
  • Density increases down the group.
  • Atomic size/atomic radius increases down the group.

General Inorganic Chemistry Concepts

  • Anomalous behavior of nitrogen: Nitrogen exhibits anomalous behavior due to its small size, high electronegativity, and strong tendency to form multiple bonds.
  • Hydrides: Elements in groups 15, 16, and 17 react with hydrogen to form hydrides with varying properties.
  • Oxides: Group 15, 16, and 17 elements combine with oxygen to form a variety of oxides with different oxidation states.
  • Halogens: Halogens react with many elements.
  • Interhalogens: Interhalogen compounds are formed when halogens combine with each other.

Additional Concepts

  • Oxidation states: The positive or negative charge that an atom can take is its oxidation state.
  • Allotropes: Different forms of an element in the same physical state.
  • Metallic character: The ability of an element to lose electrons and form positive ions.
  • Electronegativity: The tendency of an atom to attract electrons towards itself in a chemical bond.
  • Oxidation/reduction: Loss of electrons is oxidation; gain of electrons is reduction.

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