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Questions and Answers
What is the primary reason nitrogen behaves differently from other elements in Group 15?
What is the primary reason nitrogen behaves differently from other elements in Group 15?
- It has the highest atomic mass.
- It exists in a gaseous state. (correct)
- It has the highest boiling point.
- It has the lowest ionization energy.
What is formed when $PH_3$ reacts with HCl?
What is formed when $PH_3$ reacts with HCl?
- Phosphonium hydroxide
- Phosphoric acid
- Phosphonium chloride (correct)
- Phosphonium nitrate
Which element in Group 15 has the highest electronegativity?
Which element in Group 15 has the highest electronegativity?
- Phosphorus (P)
- Arsenic (As)
- Nitrogen (N) (correct)
- Antimony (Sb)
What type of hydride is formed when arsenic reacts with hydrogen?
What type of hydride is formed when arsenic reacts with hydrogen?
What is the product of the reaction between PCl3 and water?
What is the product of the reaction between PCl3 and water?
Why does $NH_3$ have a higher boiling point than $PH_3$?
Why does $NH_3$ have a higher boiling point than $PH_3$?
What is the boiling point of phosphorous trichloride (PCl3)?
What is the boiling point of phosphorous trichloride (PCl3)?
What is produced when PCl5 reacts with water?
What is produced when PCl5 reacts with water?
When elements of Group 15 react with oxygen, what compounds are primarily formed?
When elements of Group 15 react with oxygen, what compounds are primarily formed?
Which of the following represents a reaction that produces phosphorous pentachloride?
Which of the following represents a reaction that produces phosphorous pentachloride?
Which of the following reactions produces hydrogen fluoride?
Which of the following reactions produces hydrogen fluoride?
What is the electronic configuration of elements in group 18?
What is the electronic configuration of elements in group 18?
Which compound is formed when phosphorus reacts with bromine?
Which compound is formed when phosphorus reacts with bromine?
Which of the following is NOT an element of group 18?
Which of the following is NOT an element of group 18?
Which of these compounds represents an interhalogen molecule?
Which of these compounds represents an interhalogen molecule?
What is formed when sulphur reacts with oxygen?
What is formed when sulphur reacts with oxygen?
What is the boiling point of sulphur dioxide ($SO_2$)?
What is the boiling point of sulphur dioxide ($SO_2$)?
What compound is produced when $SO_2$ reacts with water?
What compound is produced when $SO_2$ reacts with water?
Which catalyst is used in the contact process for producing sulphuric acid?
Which catalyst is used in the contact process for producing sulphuric acid?
What is the product of the reaction between zinc and sulphuric acid ($H_2SO_4$)?
What is the product of the reaction between zinc and sulphuric acid ($H_2SO_4$)?
What is the product formed when nitric acid reacts with carbon?
What is the product formed when nitric acid reacts with carbon?
Which acid is produced when nitric acid reacts with sulphur?
Which acid is produced when nitric acid reacts with sulphur?
What is the final product when phosphorous reacts with nitric acid?
What is the final product when phosphorous reacts with nitric acid?
Which of the following is a property of white phosphorus?
Which of the following is a property of white phosphorus?
What is the chemical formula of hypophosphorous acid?
What is the chemical formula of hypophosphorous acid?
What gas is produced when phosphorous reacts with sodium hydroxide and water?
What gas is produced when phosphorous reacts with sodium hydroxide and water?
Which of the following statements about red phosphorus is true?
Which of the following statements about red phosphorus is true?
What is the result of zinc reacting with dilute nitric acid?
What is the result of zinc reacting with dilute nitric acid?
What is the common oxidation state of elements in group 17?
What is the common oxidation state of elements in group 17?
Which element in group 17 is a gas at room temperature?
Which element in group 17 is a gas at room temperature?
Which of the following elements in group 17 has the highest electronegativity?
Which of the following elements in group 17 has the highest electronegativity?
What happens when a metal of group 17 reacts with hydrogen?
What happens when a metal of group 17 reacts with hydrogen?
Which of the following statements about the acidic character of hydrogen halides is correct?
Which of the following statements about the acidic character of hydrogen halides is correct?
Which element in group 17 is solid at room temperature?
Which element in group 17 is solid at room temperature?
In terms of atomic size and radius, what trend occurs as you move down group 17?
In terms of atomic size and radius, what trend occurs as you move down group 17?
Which statement regarding ionization energy of group 17 elements is true?
Which statement regarding ionization energy of group 17 elements is true?
Flashcards
Electronegativity trend in Group 15
Electronegativity trend in Group 15
Electronegativity generally decreases down Group 15.
Phosphorus electronegativity
Phosphorus electronegativity
Phosphorus has an electronegativity of 2.1 eV (electron volts).
Melting and Boiling points in Group 15
Melting and Boiling points in Group 15
Melting and boiling points generally increase down Group 15.
Nitrogen's Anomalous Behavior
Nitrogen's Anomalous Behavior
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Nitrogen state of matter
Nitrogen state of matter
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Group 15 Hydrides formation
Group 15 Hydrides formation
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Ammonia (NH₃) Hydrogen bonding
Ammonia (NH₃) Hydrogen bonding
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Difference in boiling points of NH₃ and PH₃
Difference in boiling points of NH₃ and PH₃
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PH3 reaction with HCl
PH3 reaction with HCl
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PH3 reaction with H2O
PH3 reaction with H2O
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PH3 reaction with HNO3
PH3 reaction with HNO3
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PCl3 preparation (reaction 1)
PCl3 preparation (reaction 1)
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PCl3 preparation (reaction 2)
PCl3 preparation (reaction 2)
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PCl3 reaction with water
PCl3 reaction with water
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PCl3 reaction with oxygen
PCl3 reaction with oxygen
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PCl5 preparation
PCl5 preparation
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PCl5 reaction with water
PCl5 reaction with water
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PCl5 reaction with SO2
PCl5 reaction with SO2
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PCl5 decomposition
PCl5 decomposition
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Group 16 elements
Group 16 elements
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Sulphur Dioxide Formation
Sulphur Dioxide Formation
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SO2 Properties
SO2 Properties
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SO2 Reaction with Water
SO2 Reaction with Water
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SO2 Reaction with Oxygen
SO2 Reaction with Oxygen
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SO2 Reaction with Chlorine
SO2 Reaction with Chlorine
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Contact Process
Contact Process
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Sulphuric Acid (H2SO4) Properties
Sulphuric Acid (H2SO4) Properties
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H2SO4 Reaction with Copper
H2SO4 Reaction with Copper
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H2SO4 Reaction with Zinc
H2SO4 Reaction with Zinc
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Halogens
Halogens
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HNO3 reaction with carbon
HNO3 reaction with carbon
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HNO3 reaction with sulphur
HNO3 reaction with sulphur
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HNO3 reaction with phosphorous
HNO3 reaction with phosphorous
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HNO3 reaction with iodine
HNO3 reaction with iodine
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HNO3 reaction with zinc (dilute)
HNO3 reaction with zinc (dilute)
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HNO3 reaction with copper (dilute)
HNO3 reaction with copper (dilute)
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HNO3 reaction with copper (concentrated)
HNO3 reaction with copper (concentrated)
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HNO3 reaction with zinc (concentrated)
HNO3 reaction with zinc (concentrated)
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White phosphorus
White phosphorus
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Red phosphorus
Red phosphorus
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Black phosphorus
Black phosphorus
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Hypophosphorous acid
Hypophosphorous acid
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Phosphorous acid
Phosphorous acid
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Phosphoric acid
Phosphoric acid
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Cyclometaphosphoric acid
Cyclometaphosphoric acid
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Phosphine preparation
Phosphine preparation
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Phosphine properties
Phosphine properties
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Phosphorus halides reaction
Phosphorus halides reaction
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Group 17 elements & water reaction
Group 17 elements & water reaction
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Group 17 elements & metal reaction
Group 17 elements & metal reaction
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Interhalogen compounds
Interhalogen compounds
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Group 18 elements
Group 18 elements
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Group 18 electronic configuration
Group 18 electronic configuration
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Group 18 oxidation state
Group 18 oxidation state
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Group 18 elements examples
Group 18 elements examples
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Physical state of Group 18
Physical state of Group 18
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Group 17 Oxidation State
Group 17 Oxidation State
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Group 17 Electronic Configuration
Group 17 Electronic Configuration
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Fluorine Physical State
Fluorine Physical State
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Chlorine Physical State
Chlorine Physical State
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Bromine Physical State
Bromine Physical State
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Iodine Physical State
Iodine Physical State
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Halogen Reactivity Trend
Halogen Reactivity Trend
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Atomic Size Trend (Group 17)
Atomic Size Trend (Group 17)
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Ionization Energy Trend (Group 17)
Ionization Energy Trend (Group 17)
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Metallic Character Trend (Group 17)
Metallic Character Trend (Group 17)
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Electronegativity Trend (Group 17)
Electronegativity Trend (Group 17)
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Reaction with Hydrogen
Reaction with Hydrogen
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HI vs. HF Acidity
HI vs. HF Acidity
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Halogen Reactivity
Halogen Reactivity
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Study Notes
Inorganic Chemistry - Group 15
- Group 15 elements (nitrogen family) include nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), and bismuth (Bi).
- General electronic configuration of group 15 elements is ns2np3.
- Common oxidation states are +5 and -3.
- Nitrogen exists as a diatomic gas (N2).
- Phosphorus exists as white, red, and black allotropes.
- Arsenic, antimony, and bismuth are solids.
- Density increases down the group.
- Atomic size/atomic radius increases down the group.
- Ionisation energy decreases down the group.
- Metallic character increases down the group.
- Electronegativity decreases down the group.
Inorganic Chemistry - Group 16
- Group 16 elements are known as the oxygen family.
- Elements include oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and polonium (Po).
- General electronic configuration of group 16 elements is ns2np4.
- Common oxidation states are +4, +6, and -2.
- Oxygen is a diatomic gas (O2).
- Sulfur is a solid with several allotropes.
- Selenium, tellurium, and polonium are solids.
- Density increases down the group.
- Atomic size/atomic radius increases down the group.
- Ionisation energy decreases down the group.
Inorganic Chemistry - Group 17
- Group 17 elements are called halogens.
- Elements include fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At).
- General electronic configuration of group 17 elements is ns2np5.
- Common oxidation states are +1, +3, +5, and +7.
- Fluorine, chlorine, bromine, and iodine are non-metals.
- Astatine is a radioactive element.
- Density increases down the group.
- Atomic size/atomic radius increases down the group.
- Ionisation energy decreases down the group.
- Metallic character increases down the group.
- Electronegativity decreases down the group.
Inorganic Chemistry - Group 18
- Group 18 elements are called noble gases.
- Elements include helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), and radon (Rn).
- General electronic configuration of group 18 elements is ns2np6.
- Common oxidation state is zero.
- Mostly monoatomic gases.
- Density increases down the group.
- Atomic size/atomic radius increases down the group.
General Inorganic Chemistry Concepts
- Anomalous behavior of nitrogen: Nitrogen exhibits anomalous behavior due to its small size, high electronegativity, and strong tendency to form multiple bonds.
- Hydrides: Elements in groups 15, 16, and 17 react with hydrogen to form hydrides with varying properties.
- Oxides: Group 15, 16, and 17 elements combine with oxygen to form a variety of oxides with different oxidation states.
- Halogens: Halogens react with many elements.
- Interhalogens: Interhalogen compounds are formed when halogens combine with each other.
Additional Concepts
- Oxidation states: The positive or negative charge that an atom can take is its oxidation state.
- Allotropes: Different forms of an element in the same physical state.
- Metallic character: The ability of an element to lose electrons and form positive ions.
- Electronegativity: The tendency of an atom to attract electrons towards itself in a chemical bond.
- Oxidation/reduction: Loss of electrons is oxidation; gain of electrons is reduction.
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