Chemistry Concepts Overview
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Questions and Answers

What is the pH of the solution after 50.0 mL of NaOH was added to a 200.0 mL solution of 0.40 M ammonium chloride?

  • 9.25 (correct)
  • 4.75
  • 5.02
  • 8.98
  • What is the oxidation number of chromium in ammonium dichromate, (NH4)2Cr2O7?

  • +4
  • +6 (correct)
  • +3
  • +5
  • Which statement accurately describes reduction in a chemical context?

  • Gain of protons
  • Loss of mass
  • Gain of electrons (correct)
  • Loss of electrons
  • Which cell diagram accurately represents the voltaic cell generated by the reaction of zinc with lead ions?

    <p>Zn(s) | Zn2+(aq) || Pb2+(aq) | Pb(s)</p> Signup and view all the answers

    In the construction of a voltaic cell with Ag(CN)2- and Cr, which of the following cell diagrams is correct?

    <p>Ag(CN)2-(aq) | Ag(s) || Cr(s) | Cr3+(aq)</p> Signup and view all the answers

    Which half-reaction indicates that Pb is a stronger oxidizing agent than Au?

    <p>Pb + 2 e- Pb2+</p> Signup and view all the answers

    Which of the following species can act as a better reducing agent than Al?

    <p>K+</p> Signup and view all the answers

    Which statement is correct based on the half-reactions provided?

    <p>Mg will oxidize I2.</p> Signup and view all the answers

    Which half-reaction shows a species that can be readily reduced?

    <p>Au3+ + 3 e- Au</p> Signup and view all the answers

    Which of the following species is a better oxidizing agent than I2?

    <p>Br2</p> Signup and view all the answers

    Which sodium salt solution will exhibit the highest pH and therefore be the most basic?

    <p>NaD</p> Signup and view all the answers

    What is the pH of coffee with a hydroxide ion concentration of $1 imes 10^{-10}$ M?

    <p>4.0</p> Signup and view all the answers

    What is the hydronium ion concentration of a $0.010$ M acetic acid solution?

    <p>$4.2 imes 10^{-4}$</p> Signup and view all the answers

    What is the concentration of [OH–] in a $0.20$ M ammonia solution?

    <p>$1.9 imes 10^{-3}$ M</p> Signup and view all the answers

    Which expression can be used to calculate the hydronium ion concentration for weak acids with small Ka values?

    <p>[H+] = (Ka [HA])^{1/2}</p> Signup and view all the answers

    Which salt forms an aqueous solution with a pH = 7?

    <p>NaBr</p> Signup and view all the answers

    What mole ratio of Na2HPO4/NaH2PO4 is necessary to produce a buffer solution with a pH of 7.4?

    <p>1.6</p> Signup and view all the answers

    What relationship holds at the halfway point to the equivalence point in a titration curve of a weak acid with a strong base?

    <p>The pH is equal to the pKa.</p> Signup and view all the answers

    What is defined as the energy transferred due to a temperature difference?

    <p>Heat</p> Signup and view all the answers

    If ΔSsys is negative during a spontaneous chemical reaction, what does this imply about ΔSsurr?

    <p>ΔSsurr is greater than 0 and its magnitude is greater than ΔSsys.</p> Signup and view all the answers

    What can be inferred about the entropy change when sodium hydroxide dissolves in water, resulting in a temperature rise?

    <p>ΔSsys is greater than 0 and ΔSsurr is greater than 0.</p> Signup and view all the answers

    Which of the following statements about reaction rates and kinetic molecular theory is false?

    <p>Collisions between product molecules do not impact overall reaction rates.</p> Signup and view all the answers

    What is the nature of the steps that make up a reaction mechanism?

    <p>Elementary steps</p> Signup and view all the answers

    In a proposed mechanism for ozone decomposition, which species is classified as an intermediate?

    <p>ClO</p> Signup and view all the answers

    What is likely to happen to the reaction rate as the concentration of reactants decreases over time?

    <p>The reaction rate will decrease.</p> Signup and view all the answers

    What does it mean if the entropy change of the system is greater than zero?

    <p>The overall process may still be spontaneous.</p> Signup and view all the answers

    What is the value of $ riangle G^{ heta}$ for the reaction forming ammonia at 298 K?

    <p>-33.32 kJ/mol</p> Signup and view all the answers

    What is the overall order of the reaction 2 NO(g) + Cl2(g) → 2 NOCl(g) based on experimental data?

    <p>3</p> Signup and view all the answers

    What is the half-life of a first-order reaction with a rate constant of 3.45 x 10^-3 s^-1?

    <p>200 s</p> Signup and view all the answers

    In the acid-base reaction CH3NH2 + HSO4– ⇄ CH3NH3+ + SO42–, identify the acid reactant.

    <p>HSO4–</p> Signup and view all the answers

    What is the pH of a buffer solution where [HA] = [A–]?

    <p>pKa</p> Signup and view all the answers

    What is the rate of reaction of nitrogen monoxide and hydrogen in mols/s?

    <p>$7.01 \times 10^{-5}$</p> Signup and view all the answers

    Which reaction path indicates the effect of a catalyst?

    <p>Dotted line</p> Signup and view all the answers

    What is the value of Ecell for a concentration cell with silver electrodes at 0.10 M and 0.00003 M silver nitrate?

    <p>+0.21 V</p> Signup and view all the answers

    How many seconds does it take for the concentration of formic acid to decrease by 87.5%?

    <p>4.6 s</p> Signup and view all the answers

    Determine the rate expression for the reaction A + B → C based on the provided initial rate data.

    <p>Rate = 24[A][B]^2</p> Signup and view all the answers

    Which reaction pathway shows the effect of a catalyst on an uncatalyzed reaction?

    <p>Pathway B</p> Signup and view all the answers

    What is the rate constant for a second-order reaction if the concentration decreases from 1.00 M to 0.43 M in 75 seconds?

    <p>$1.8 \times 10^{-2}$ L/mol⋅s</p> Signup and view all the answers

    What happens to concentrations at equilibrium when K >> 1?

    <p>The concentrations of products drastically increase.</p> Signup and view all the answers

    Which statement is true regarding the concentration of products at equilibrium?

    <p>They remain constant as forward and reverse rates are equal.</p> Signup and view all the answers

    What must be true if the forward and reverse rate constants are unequal?

    <p>The rates will remain unequal despite concentration changes.</p> Signup and view all the answers

    What is the effect of an increase in temperature on the equilibrium constant K?

    <p>It depends on the enthalpy change of the reaction.</p> Signup and view all the answers

    Study Notes

    Summary of Chemistry Concepts

    • Reduction: The gain of electrons in a chemical reaction.
    • Oxidation: The loss of electrons in a chemical reaction.
    • Voltaic Cell: A galvanic cell producing electricity from a spontaneous redox reaction.
    • Cell Diagram: A shorthand notation representing a voltaic cell.
    • Standard Reduction Potential (E°): The tendency of a species to be reduced in a half-reaction under standard conditions.
    • Nernst Equation: Used to calculate the cell potential under non-standard conditions.
    • Reaction Quotient (Q): A measure of the relative amounts of products and reactants present in a reaction at any given time.
    • Equilibrium Constant (K): A value that represents the ratio of products to reactants at equilibrium.
    • Equilibrium: The state where the rates of the forward and reverse reactions are equal, and the concentrations of reactants and products no longer change significantly.
    • pH: A measure of the hydrogen ion concentration in a solution, signifying acidity or basicity. A measure for the acidity of the solution.
    • Reaction Order: The dependence of a reaction rate on the concentration of reactants.
    • Rate constant(k): A proportionality constant that relates the rate of a reaction to the concentrations of reactants
    • Half-life (t1/2): The time required for the concentration of a reactant to decrease to half its initial value in a chemical reaction.
    • Buffer Solution: A solution that resists changes in pH upon addition of small amounts of acid or alkali.
    • Solubility Product Constant (Ksp): Measure of solubility of a solid ionic compound.

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    Description

    This quiz covers essential chemistry concepts such as oxidation and reduction reactions, voltaic cells, standard reduction potentials, and equilibrium. It also delves into important equations like the Nernst Equation and the calculation of pH. Understanding these key topics is crucial for mastering chemistry.

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