Chemistry Class: Ligands and Polymers

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Questions and Answers

What defines a bidentate ligand?

  • A ligand that can bind to anions only.
  • A ligand that forms complexes with nonmetals.
  • A ligand that can attach to a metal at two points. (correct)
  • A ligand that can only attach to a metal at one point.

What are the monomers used in the preparation of nylon 6,6?

  • Hexamethylenediamine and adipic acid. (correct)
  • Caprolactam and maleic anhydride.
  • Ethanol and acetic acid.
  • Butadiene and styrene.

How is the molar mass of a solute calculated using osmotic pressure?

  • Using the ideal gas law and temperature only.
  • Using osmotic pressure, volume, and temperature. (correct)
  • Using concentration and density of the solution.
  • Using the mass of solute and volume of solution.

What is a nucleotide composed of?

<p>A sugar, a phosphate group, and a nitrogenous base. (A)</p> Signup and view all the answers

What distinguishes a double salt from a coordinate compound?

<p>Double salts are formed from two different ionic compounds, while coordinate compounds involve coordinate bonds. (C)</p> Signup and view all the answers

Flashcards

Bidentate ligands

Ligands that bind to a central metal ion through two donor atoms.

Nylon 6,6 monomers

Hexamethylenediamine and adipic acid.

Solute molar mass

Determined using osmotic pressure (Ï€ = MRT).

Nucleotide

Building block of DNA/RNA, consisting of a base, sugar, and phosphate group.

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Double salt vs. Coordinate compound

Double salts exist as discrete entities; coordinate compounds are entities with bonded metal complexes.

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Study Notes

Bidentate Ligands

  • Bidentate ligands are ligands that bind to a central metal ion through two donor atoms.
  • Example: Ethylenediamine (en)

Nylon 6,6 Polymer

  • Monomers:
    • Adipic acid
    • Hexamethylenediamine
  • Structure: (Describe the structure of the polymer and monomers)

Molar Mass Calculation

  • Given:
    • Mass of solute = 0.822 g
    • Volume of water = 0.3 dm³ = 0.3 L
    • Osmotic pressure = 0.196 atm
    • Temperature = 298 K
  • Calculate molar mass using the osmotic pressure formula.

Nucleotide

  • Nucleotides are organic molecules that serve as the building blocks of DNA and RNA.

Polyacrylonitrile (PAN) Preparation

  • Write the reaction for the preparation of PAN.

Difference between Double Salt and Coordinate Compounds

  • Double Salt:
    • A crystalline compound which consists of two or more salts.
    • Each salt retains its own chemical properties.
    • Separates on crystallization into different components.
  • Coordinate Compound:
    • A compound formed by the combination of a central metal ion and surrounding ligands.
    • Ligands are bonded to the central metal ion through coordinate covalent bonds.
    • Ligands have lone pairs for donation.
  • Example: (Provide an example of both a double salt and a coordinate compound)

Applications of Coordinate Compounds

  • Provide two applications of coordinate compounds.

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