Chemistry Class 11 - Reaction Types and Stoichiometry
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Questions and Answers

What does 1 nutritional calorie equal in kilojoules?

  • 4.18 kJ (correct)
  • 2.68 kJ
  • 7.2 kJ
  • 3.84 kJ
  • Which principle explains that energy cannot be created or destroyed?

  • Hess's law
  • First law of thermodynamics (correct)
  • Pauli exclusion principle
  • Heisenberg uncertainty principle
  • What is the term for the energy required to break one mole of bonds in a gaseous state?

  • Internal energy change
  • Standard enthalpy of combustion
  • Standard enthalpy of formation
  • Bond dissociation energy (correct)
  • In the Rydberg equation, which variable represents the Rydberg constant?

    <p>R_H</p> Signup and view all the answers

    What does the principal quantum number (n) indicate in quantum mechanics?

    <p>Energy level of an electron</p> Signup and view all the answers

    Which quantum number describes the shape of an electron's orbital?

    <p>Angular momentum quantum number (l)</p> Signup and view all the answers

    What phenomenon does the photoelectric effect demonstrate?

    <p>Particle nature of light</p> Signup and view all the answers

    Which principle states that no two electrons in an atom can have the same set of quantum numbers?

    <p>Pauli exclusion principle</p> Signup and view all the answers

    Which of the following statements about redox reactions is true?

    <p>Combustion reactions can be recognized as redox reactions.</p> Signup and view all the answers

    What determines the theoretical yield in a chemical reaction?

    <p>The limiting reactant.</p> Signup and view all the answers

    Which equation correctly represents the relationship between heat, specific heat, mass, and change in temperature?

    <p>q = c × m × ∆T</p> Signup and view all the answers

    In calorimetry, what does it mean when a reaction is described as exothermic?

    <p>It releases heat to the surroundings.</p> Signup and view all the answers

    To convert Celsius to Kelvin, which operation should be performed?

    <p>Add 273.15 to the Celsius temperature.</p> Signup and view all the answers

    What is the specific heat of a substance?

    <p>The amount of heat required to raise the temperature of one gram by 1°C.</p> Signup and view all the answers

    Which process is characterized by the equation qreaction = −qsolution?

    <p>The conservation of energy during a chemical reaction.</p> Signup and view all the answers

    Which of the following best describes gravimetric analysis?

    <p>A method for determining the concentration of a solute based on mass.</p> Signup and view all the answers

    Which of the following accurately describes the difference between cations and anions?

    <p>Cations are atoms that lose electrons, while anions are atoms that gain electrons.</p> Signup and view all the answers

    What is true regarding the octet rule?

    <p>Not all elements follow the octet rule, particularly electron deficient species.</p> Signup and view all the answers

    Which of the following trends do ionization energy and electron affinity share?

    <p>Both are affected by effective nuclear charge.</p> Signup and view all the answers

    What does it mean for ionic compounds to have isotropic attractive forces?

    <p>The attractive forces are equal in all three-dimensional directions.</p> Signup and view all the answers

    Which statement correctly describes a polar covalent bond?

    <p>One atom has a higher electronegativity, resulting in unequal sharing of electrons.</p> Signup and view all the answers

    When distinguishing between single, double, and triple bonds, which factor directly affects bond length?

    <p>The number of bonding pairs of electrons.</p> Signup and view all the answers

    In the context of resonance structures, which statement is accurate?

    <p>A resonance hybrid represents the average of all possible resonance structures.</p> Signup and view all the answers

    Which of the following is true about isoelectronic species?

    <p>They possess identical electron configurations.</p> Signup and view all the answers

    Study Notes

    Section 4.2 Classifying Chemical Reactions

    • Determine if a redox reaction occurred
      • Assign oxidation states
      • Identify oxidized species
      • Identify reduced species
      • Identify oxidizing agent
      • Identify reducing agent
    • Balance redox reactions in acidic and basic conditions
    • Recognize decomposition, combination, single displacement, and combustion reactions as redox reactions

    Section 4.3 Reaction Stoichiometry

    • Use stoichiometric coefficients to determine moles of reactants needed for a reaction
    • Relate masses of reactants to masses of products
    • Relate masses of reactants to each other

    Section 4.4 Reaction Yields

    • Identify the limiting reactant
    • Theoretical yield is determined by limiting reactant
    • Calculate percent yield

    Section 4.5 Quantitative Chemical Analysis

    • Explain techniques like titration, gravimetric analysis, and combustion analysis
    • Determine solution concentration from titration data
    • Determine solute concentration from gravimetric analysis data
    • Determine empirical formulas from combustion analysis data

    Chapter 5 Thermochemistry

    Section 5.1 Energy Basics

    • Define kinetic, potential, and thermal energy
    • Convert between temperature scales (Celsius, Fahrenheit, Kelvin)
    • Be familiar with energy units (calorie, joule)
    • Distinguish between heat capacity, specific heat, and molar heat capacity
    • Determine heat from q = mc(ΔT)

    Section 5.2 Calorimetry

    • Explain how calorimetry is used to measure heat transfer
    • Distinguish between endothermic and exothermic processes
    • Explain how a bomb calorimeter is used
    • Convert Calories to kcal

    Section 5.3 Enthalpy

    • State the first law of thermodynamics
    • Explain and apply concepts like internal energy, expansion work, state functions, enthalpy (H), enthalpy change (ΔH), standard state conditions, standard enthalpy of combustion (ΔH°c), and standard enthalpy of formation (ΔH°f)
    • Write and manipulate thermochemical equations
    • Calculate enthalpy of combustion
    • Determine heat of reaction from standard enthalpies of formation

    Section 6.1 Electromagnetic Energy

    • Convert between wavelength and frequency
    • Understand relationships between energy, wavelength, and frequency
    • Know the regions of the electromagnetic spectrum
    • Recognize constructive and destructive interference
    • Distinguish between continuous and line spectra

    Section 6.2 The Bohr Model

    • Describe the Bohr model of the atom
    • Distinguish between ground and excited states of an electron
    • Use the Rydberg equation to calculate energy of transitions

    Section 6.3 Development of Quantum Theory

    • Relate wave-particle duality of light to electrons
    • Understand and apply quantum numbers (principal, angular momentum, magnetic, spin)

    Section 6.4 Electronic Structure of Atoms

    • Write electron configurations for atoms and ions
    • Apply orbital diagrams for atoms and ions
    • Understand deBroglie wavelength, Heisenberg uncertainty principle, Pauli exclusion principle, Aufbau principle, Hund's rule
    • Distinguish between valence and core electrons
    • Identify main group, transition, and inner transition elements

    Section 6.5 Periodic Variations in Element Properties

    • Describe, explain, and apply periodic trends in covalent radius, effective nuclear charge, ionic radii, ionization energy, electron affinity, and metallic character
    • Recognize isoelectronic species

    Chapter 7 Chemical Bonding and Molecular Geometry

    Section 7.1 Ionic Bonding

    • Distinguish between cations, anions, atoms, and molecules
    • Explain how cations and anions form
    • Identify properties of ionic compounds
    • Compare properties of ions and atoms
    • Identify binary ionic compounds
    • Explain the formula of an ionic compound
    • Explain the inert pair effect

    Section 7.2 Covalent Bonding

    • Explain how covalent bonds differ from ionic bonds
    • Compare properties of molecular and ionic compounds
    • Explain how covalent bonds form
    • Recognize factors affecting bond length
    • Distinguish between polar and pure covalent bonds
    • Differentiate between electronegativity, effective nuclear charge, electron affinity
    • Recognize polyatomic ions as charged molecules

    Section 7.3 Lewis Symbols and Structures

    • Write Lewis symbols from valence shell electron configurations
    • Show formation of ions with Lewis symbols
    • Distinguish between lone pair and bonding electrons
    • Explain the octet rule
    • Distinguish between single, double, and triple bonds
    • Draw Lewis structures
    • Recognize exceptions to the octet rule (electron-deficient and hypervalent species)

    Section 7.4 Formal Charge and Resonance

    • Assign formal charge to atoms in molecules
    • Use formal charge to determine best Lewis structures
    • Explain resonance
    • Explain how resonance structures differ from isomers
    • Explain resonance hybrid

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    Description

    This quiz covers essential concepts from Chemistry Class 11, focusing on classifying chemical reactions, stoichiometry, reaction yields, and quantitative chemical analysis techniques. Test your understanding of redox reactions, identifying reactants, and calculating yields and concentrations. Perfect for students looking to review key topics in chemical reactions and analysis.

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