Chemistry Chapter on Reactions
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Questions and Answers

What occurs in a reversible reaction?

  • Reactants are completely converted to products.
  • Equilibrium cannot be reached.
  • No reactions occur after initial products form.
  • Products can convert back into reactants. (correct)

Irreversible reactions can reach a state of equilibrium.

False (B)

What principle states that a change in conditions will shift the equilibrium to alleviate the stress?

Le Chatelier's Principle

An increase in temperature favors the __________ reaction.

<p>endothermic</p> Signup and view all the answers

When more reactant is added to a system at equilibrium, the reaction will shift:

<p>To the right, toward the product side. (D)</p> Signup and view all the answers

Match the following effects with their results on equilibrium:

<p>Adding more reactant = Shifts to the product side Adding more product = Shifts to the reactant side Increasing pressure = Shifts to the side with fewer moles of gas Decreasing pressure = Shifts to the side with more moles of gas</p> Signup and view all the answers

Catalysts affect the position of equilibrium in a chemical reaction.

<p>False (B)</p> Signup and view all the answers

What happens to the position of equilibrium if pressure is increased in a reaction involving gaseous reactants?

<p>Shifts to the side with fewer moles of gas</p> Signup and view all the answers

What characterizes a reversible reaction?

<p>It can establish an equilibrium. (A)</p> Signup and view all the answers

What happens to the concentration of reactants when more product is added to a system at equilibrium?

<p>The concentration of reactants increases.</p> Signup and view all the answers

Increasing pressure in a reaction with fewer gas moles on the product side will shift equilibrium to the __________.

<p>right</p> Signup and view all the answers

Match the scenarios with their effects on equilibrium:

<p>Adding more reactant = Shifts equilibrium to the right Adding more product = Shifts equilibrium to the left Increasing pressure = Shifts equilibrium toward fewer gas moles Decreasing temperature = Favors exothermic reactions</p> Signup and view all the answers

Which of the following does NOT affect the position of equilibrium?

<p>Adding a catalyst (D)</p> Signup and view all the answers

Le Chatelier's principle states that a system at equilibrium will remain unchanged unless acted upon by an outside force.

<p>True (A)</p> Signup and view all the answers

What effect does increasing temperature have on a system at equilibrium involving an endothermic reaction?

<p>It favors the endothermic reaction.</p> Signup and view all the answers

Which statement accurately describes dynamic equilibrium?

<p>The rates of the forward and reverse reactions are equal. (A)</p> Signup and view all the answers

Adding more reactants to a system in equilibrium will always cause the reaction to shift to the left.

<p>False (B)</p> Signup and view all the answers

What is indicated by a double arrow (⇌) in a chemical reaction?

<p>A reversible reaction</p> Signup and view all the answers

Irreversible reactions proceed in one direction until the reactants are completely __________.

<p>consumed</p> Signup and view all the answers

Match the factors affecting equilibrium with their effects:

<p>Adding more reactants = Favors products Adding more products = Favors reactants Increasing pressure = Favors fewer gaseous molecules Decreasing temperature = Favors exothermic reactions</p> Signup and view all the answers

Which factor does not change the position of equilibrium?

<p>Adding a catalyst (D)</p> Signup and view all the answers

Increasing the pressure in a reaction with more gaseous reactants will shift the equilibrium to the right.

<p>False (B)</p> Signup and view all the answers

In what direction does equilibrium shift when more products are added to a system?

<p>To the left</p> Signup and view all the answers

Flashcards

Dynamic Equilibrium

A state where the rates of the forward and reverse reactions are equal, resulting in no net change in the concentrations of reactants and products.

Reversible Reactions

Reactions that can proceed in both the forward and reverse directions.

Irreversible Reactions

Reactions that proceed in a single direction from reactants to products.

Le Chatelier's Principle

When a stress is applied to a system at equilibrium, the system shifts in a direction to relieve the stress.

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Adding Reactant

Adding more reactant shifts the reaction to the right (product side).

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Adding Product

Adding more product shifts the reaction to the left (reactant side).

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Effect of Pressure

Increasing pressure favors the side with fewer moles of gas. Decreasing pressure favors the side with more moles of gas.

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Effect of Temperature

Increasing temperature favors the endothermic reaction. Decreasing temperature favors the exothermic reaction.

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What is dynamic equilibrium?

A state where the rates of the forward and reverse reactions are equal, resulting in no net change in the concentrations of reactants and products.

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What are reversible reactions?

Reactions that can proceed in both the forward and reverse directions, eventually reaching a state of equilibrium.

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What are irreversible reactions?

Reactions that proceed in only one direction, from reactants to products. They do not reach equilibrium.

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Describe Le Chatelier's Principle.

If a stress is applied to a system at equilibrium, the system will shift in a direction to relieve the stress. This helps maintain equilibrium.

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How does adding more reactant affect equilibrium?

Adding more reactant will shift the reaction to the right, consuming the added reactant and forming more product.

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How does adding more product affect equilibrium?

Adding more product will shift the reaction to the left, consuming the added product and forming more reactant.

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How does changing pressure affect equilibrium?

Increasing pressure favors the side of the reaction with fewer moles of gas, while decreasing pressure favors the side with more moles of gas.

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How does changing temperature affect equilibrium?

Increasing temperature favors the endothermic (heat-absorbing) reaction, while decreasing temperature favors the exothermic (heat-releasing) reaction.

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How does adding reactants or products affect equilibrium?

Adding more reactants shifts the equilibrium to the right, favoring product formation. Adding more products shifts the equilibrium to the left, favoring reactant formation.

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How does temperature affect equilibrium?

For exothermic reactions, increasing temperature shifts equilibrium left, favoring reactants. For endothermic reactions, increasing temperature shifts equilibrium right, favoring products.

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How does pressure affect equilibrium?

Increasing pressure favors the reaction with fewer gas molecules. Decreasing pressure favors the reaction with more gas molecules.

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How do catalysts affect equilibrium?

Catalysts speed up both the forward and reverse reactions equally, so they don't change the position of equilibrium.

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What is Le Chatelier's Principle?

If a stress is applied to a system at equilibrium, the system will shift in a direction to relieve the stress.

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Study Notes

Dynamic Equilibrium

  • Dynamic equilibrium is a state where the rates of the forward and reverse reactions are equal, resulting in no net change in the concentration of reactants or products.
  • This does not mean that the forward and reverse reactions have stopped, but rather that the rates of the two processes are balanced.
  • The system is constantly changing, but the observable properties remain constant.
  • Dynamic equilibrium requires a closed system.

Reversible Reactions

  • Reversible reactions are chemical reactions that can proceed in both the forward and reverse directions.
  • A double arrow (⇌) is usually used to indicate a reversible reaction.
  • Examples of reversible reactions often form an equilibrium state rather than total consumption of reactants.

Irreversible Reactions

  • Irreversible reactions proceed in one direction until one or more of the reactants are completely consumed.
  • There is no appreciable reverse reaction in these cases.
  • The equilibrium point only exists for reversible reactions.
  • A reaction that forms a very stable product can be treated effectively as irreversible.

Factors Affecting Equilibrium

  • Adding more reactant(s):

    • Shifting the equilibrium position to the right, favoring the production of more products.
    • This increases the rate of the forward reaction, while the reverse reaction rate remains constant.
  • Adding more product(s):

    • Shifting the equilibrium position to the left, favoring the production of more reactants.
    • An increase in the concentration of products will increase the rate of the reverse reaction, while the forward reaction rate remains constant.
  • Effect of Temperature:

    • For an exothermic reaction, increasing the temperature will shift the equilibrium to the left, favoring the reactants.
    • Increasing the temperature will favor endothermic reactions shifting equilibrium towards the products.
  • Effect of Pressure:

    • Pressure changes have a large effect on equilibria involving gases.
    • Increasing the pressure generally favors the reaction that produces fewer gaseous molecules, causing a shift to reduce the pressure.
    • Decreasing the pressure generally favors the reaction that produces more gaseous molecules.
  • Effect of Catalysts:

    • Catalysts increase the rates of both the forward and reverse reactions equally.
    • Catalysts do not change the position of the equilibrium or the amount of products formed at a given temperature.
    • Catalysts help reach equilibrium faster, but don't effect the amounts of products/reactants. This is essential in industries where quick reactions are important.
  • Effect of Concentrations:

    • Changes in the concentration of reactants or products will disturb the equilibrium.
    • The system will respond to minimize the stress by shifting the position of equilibrium.

Le Chatelier's Principle

  • Le Chatelier's principle states that if a change is imposed on a system at equilibrium, the system will shift in a way that relieves the stress caused by the change.
  • The stress can involve changes in concentration, pressure, or temperature, for example.

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Description

Explore the key concepts of dynamic equilibrium, reversible, and irreversible reactions in this quiz. Understand how the rates of reactions influence chemical processes and the significance of equilibrium in chemistry. Test your knowledge on these fundamental topics and their applications.

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