Chemistry Chapter 4: Gases
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Questions and Answers

What is the ideal gas law equation?

PV = nRT

How is the number of moles (n) related to mass (m) and molar mass?

n = mass / molar mass

What is the value of the ideal gas constant R when pressure is in atm and volume in dm³?

0.0821 atm dm³ mol⁻¹ K⁻¹

What is the value of the ideal gas constant R in SI units (N/m² for pressure and m³ for volume)? Provide both forms.

<p>8.314 Nm mol⁻¹ K⁻¹ or 8.314 J mol⁻¹ K⁻¹</p> Signup and view all the answers

What is the relationship between density (d), pressure (P), molar mass (M), and the ideal gas constant (R)?

<p><code>d = PM / RT</code></p> Signup and view all the answers

What are the characteristics of an ideal gas?

<p>An ideal gas obeys all gas laws (Boyle's, Charles's, and Avogadro's) under all conditions of temperature and pressure.</p> Signup and view all the answers

What are real gases?

<p>Real gases do not obey gas laws under all conditions of temperature and pressure.</p> Signup and view all the answers

Under what conditions do real gases deviate most from ideal behavior?

<p>At high pressure and low temperature.</p> Signup and view all the answers

According to the Kinetic Molecular Theory (KMT), what is the nature of the motion of gas molecules?

<p>Gas molecules are in continuous, random, and haphazard motion, moving in straight paths and colliding with each other and the container walls.</p> Signup and view all the answers

How does the actual volume of gas molecules compare to the volume occupied by the gas, according to the KMT?

<p>The actual volume of the gas molecules is considered negligible compared to the total volume occupied by the gas.</p> Signup and view all the answers

What is 'mean free path' in the context of gas molecules, according to KMT?

<p>Mean free path is the average distance a gas molecule travels before a successive collision.</p> Signup and view all the answers

What are the three classes of gases based on elemental composition mentioned in the text?

<p>The three classes are monoatomic, diatomic, and polyatomic gases.</p> Signup and view all the answers

Give two examples of diatomic gases.

<p>Oxygen ($O_2$) and Hydrogen ($H_2$).</p> Signup and view all the answers

What is the Greek word from which the term "gas" is derived, and what does it mean?

<p>The word is 'Khaos' and it means emptiness or gap.</p> Signup and view all the answers

List two everyday uses of gases mentioned in the text.

<p>Carbon dioxide ($CO_2$) in photosynthesis and methane (natural gas) in vehicles, power stations, and kitchens.</p> Signup and view all the answers

Who is credited with presenting the initial Kinetic Molecular Theory of gases, and who made later modifications?

<p>The theory was initially presented by Daniel Bernoulli, with later modifications by Maxwell and Boltzmann.</p> Signup and view all the answers

If a cylinder contains 2 moles of a gas at a certain volume, and more gas is added until the cylinder contains 6 moles, how does the volume of the gas change at constant temperature and pressure?

<p>The volume will triple.</p> Signup and view all the answers

A gas occupies 5 dm³ at 298 K and 760 torr. If the temperature is increased to 350 K while the pressure remains the same, will the volume increase or decrease?

<p>The volume will increase.</p> Signup and view all the answers

A container holds a gas at 2 atm and 10 liters. Assuming the temperature is held constant, what would happen to the volume if the pressure was reduced to 1 atm?

<p>The volume would double to 20 liters.</p> Signup and view all the answers

A gas is initially at 273 K and 1 atm. What is the term for these conditions?

<p>Standard Temperature and Pressure or STP</p> Signup and view all the answers

If a gas occupies 10 dm³ at 293 K and 800 torr, and is then brought to standard temperature and pressure, will the volume increase or decrease?

<p>The volume will decrease.</p> Signup and view all the answers

If you have a fixed amount of gas, and you increase its temperature, while keeping volume constant, how will the pressure change?

<p>The pressure will increase.</p> Signup and view all the answers

What variable is assumed to be constant when using the equation (V_1/n_1 = V_2/n_2)?

<p>Temperature and pressure.</p> Signup and view all the answers

A gas cylinder with a fixed volume has gas added, increasing the number of moles of gas inside. What happens to the pressure inside the cylinder, assuming the temperature remains constant?

<p>The pressure will increase.</p> Signup and view all the answers

Study Notes

Chemistry Chapter 4: Gases

  • Gases are substances with molecules that are far apart, having weak attractions compared to other states of matter.
  • "Khaos" is a Greek word that gave rise to the term "gas," meaning emptiness or gap.
  • Gas molecules move randomly in all directions, colliding with each other and container walls.
  • Gases can be classified as monoatomic, diatomic, or polyatomic, based on elemental composition.
  • Noble gases (Helium, Neon, Argon) are monoatomic, while oxygen and hydrogen are diatomic examples.
  • Gases like methane and carbon dioxide are examples of polyatomic gases.
  • Gases have various uses, such as in photosynthesis, vehicles, power plants, and kitchens.
  • The Kinetic Molecular Theory (KMT) of gases describes the behavior of gas molecules.
  • Gas molecules are in constant, random motion. The volume of gas particles is negligible.
  • There are no attractive or repulsive forces between ideal gas molecules.
  • Average kinetic energy is directly proportional to absolute temperature.
  • Pressure is force applied per unit area, measured in Pascals (Pa), atmospheres (atm), kilopascals (kPa), or torr.
  • 1 atm = 760 mmHg = 14.7 psi = 101325 Pa
  • A barometer measures atmospheric pressure, and a manometer measures gas pressure.

Postulates of Kinetic Molecular Theory

  • Molecules: Gases consist of tiny particles called molecules (e.g., monoatomic, diatomic, polyatomic).
  • Volume: The actual volume of a gas is negligible compared to its container volume.
  • Movement: Gas molecules are in continuous random motion, colliding with each other and the container walls.
  • Mean Free Path: The average distance a gas molecule travels between collisions is its mean free path.
  • Pressure: Gas molecules exert pressure on the container walls after collisions.
  • Forces: There are no attractive or repulsive forces between ideal gas molecules.
  • Energy: Average kinetic energy of gas molecules is directly proportional to absolute temperature.

Absolute Zero (Definition)

  • The temperature at which the volume of an ideal gas becomes zero.

Boyle's Law

  • At constant temperature, the volume of a gas is inversely proportional to its pressure.

Charles's Law

  • At constant pressure, the volume of a gas is directly proportional to its absolute temperature.

Avogadro's Law

  • At constant temperature and pressure, the volume of a gas is directly proportional to the number of moles of gas.

Dalton's Law of Partial Pressures

  • The total pressure of a mixture of non-reacting gases is the sum of the partial pressures of each gas.

Graham's Law of Diffusion and Effusion

  • The rate of diffusion or effusion of a gas is inversely proportional to the square root of its molar mass.

Liquefaction of Gases

  • Converting a gas into a liquid by lowering the temperature or increasing pressure (or both).
  • Linde's method uses the Joule-Thomson effect, allowing gases to cool under pressure as they expand.

Plasma (Fourth State of Matter)

  • A state of matter consisting of positive ions, electrons, and neutral particles, having equal amounts of positive and negative charges.
  • Found in stars, lightning, and fluorescent lights.
  • Useful in various applications, including electronic devices, medical processes, industrial applications, and lighting.

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Chemistry Chapter 4: Gases PDF

Description

Explore the fascinating properties of gases in Chemistry Chapter 4. Learn about the Kinetic Molecular Theory, the classification of gases, and their various uses in everyday life. This quiz covers key concepts and terminology essential for understanding gas behavior.

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