CHURCHLANDS 2022 CHEM SEM 2
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CHURCHLANDS 2022 CHEM SEM 2

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@ReasonableAqua5401

Questions and Answers

Which of the following statements cannot be supported by the Arrhenius theory of acids and bases?

  • (a) Hydrochloric acid is a strong acid.
  • (b) Ethanoic acid is a weak acid.
  • (c) Sodium hydroxide is a strong base.
  • (d) Calcium carbonate is a weak base. (correct)
  • state the function of a catalytic converter

    To (catalyse reactions which) reduce the amount of harmful gases (e.g. carbon monoxide, unburnt petrol and nitrogen oxides) emitted by a vehicle.

    Explain why the use of nanoparticles has greatly reduced the amount of precious metals used to construct a catalytic converter.

    Nanoparticles have a very large surface area (to mass ratio).

    This increases the frequency of collisions between the catalyst and the gases.

    Therefore less material is required (compared to the bulk) to provide an equivalent surface area / to function effectively.

    Explain, in terms of intermolecular forces, why the vapour pressure of hexane is much higher than the other two liquids.

    <p>Hexane is non-polar and exhibits only dispersion forces.</p> <p>Water and ethanol exhibit strong hydrogen bonds (in addition to dipole- dipole and dispersion forces).</p> <p>Thus the sum of intermolecular forces is lower in hexane, allowing vapour to form/evaporation to occur/molecules to escape the liquid more easily.</p> <p>hence the vapour pressure of hexane is much higher than the other two liquids</p> Signup and view all the answers

    out of water, ethanol and hexane, which has highest boiling point? Justify answer (the table says water does but justify why)

    <p>Boiling occurs when the vapour pressure equals the atmospheric pressure</p> <p>thus a lower vapour pressure indicates a larger amount is required before boiling will occur</p> Signup and view all the answers

    Explain, in terms of the kinetic theory, why the vapour pressure of water increases with increasing temperature.

    <p>An increase in temperature increases the average kinetic energy of the particles.</p> <p>This would allow a higher proportion of molecules to evaporate/increase rate of evaporation</p> <p>Resulting in increased collisions between the vapour and the container.</p> Signup and view all the answers

    Sample preparation: filtration Non-Polar Stationary phase: polymer- based matrix Polar Mobile phase: 0.0035 mol L-1 H2SO4(aq) Flow rate: 0.6 mL min-1

    Oxalic acid- lowest retention time Acetic acid- highest retention time

    Which acidulant is likely to be the most polar? Justify your answer, making reference to the role of intermolecular forces.

    <p>Oxalic acid</p> <p>the mobile phase is power</p> <p>therefore components with highest polarity will dissolve more readily in the mobile phase</p> <p>thus (they will move more quickly through the column), resulting in a lower retention time</p> Signup and view all the answers

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