Chemistry 1022 Midterm 3

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Questions and Answers

Please assign curves A, B, and C to each of the three chemicals of the decomposition of N2O (g) into O2 (g) and N2 (g).

Curve A = O2 Curve B = N2 Curve C = N2O

Given that the half-life of 14C is 5730 years, calculate the number of half-lives that have passed for a mummy whose concentration of 14C is measured to be 0.40 ppt.

  • 1.5 half-lives
  • < 1 half-life
  • 1.3 half-lives
  • 1.2 half-lives
  • 2 half-lives

Which of the following ligands will provide the greatest increase in solubility of CuS?

  • Ligand D
  • Ligand A
  • Ligand C
  • Ligand B

Which of the following systems in equimolar quantities would be ideal for stabilizing sucrase at pH = 6.0?

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Acid: ____________________________

<p>A</p> Signup and view all the answers

Base: ____________________________

<p>B</p> Signup and view all the answers

Which of the following is the correct molar solubility of the salt A2B3 given that the Ksp is 1.00x10-15 at 298 K?

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What is the order of the reaction based on data collected for the decomposition of sucrose using the sucrase enzyme?

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How many steps does the reaction occur in? __________________________

<p>2</p> Signup and view all the answers

Which step is the rate limiting step? _________________________________

<p>Step 1</p> Signup and view all the answers

By introducing a catalyst to the reaction, which of the following is expected to change? Circle all that apply.

<p>Ea of the forward reaction (D), Ea of the reverse reaction (F)</p> Signup and view all the answers

Estimate the values of all pKa(s) and equivalence point pH(s) based on a titration curve.

<p>pKa(s): _____, Equivalence point pH(s): _____</p> Signup and view all the answers

Flashcards

What is Carbon dating?

The concentration of radioactive 14C in organic matter to measure the amount in parts per trillion (ppt).

What is Sucrase?

Digestive enzyme that catalyzes the hydrolysis of sucrose into glucose and fructose.

What are Titration curves?

A series of titrations to determine the amount of acid or base in a solution.

What is a Reaction Coordinate Diagram?

A diagram that shows the energy changes in a chemical reaction

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What is a Hydrogen Fuel Cell?

A device that converts the chemical energy of a fuel into electricity through a redox reaction.

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What is Ka?

Ka is the acid dissociation constant, measuring the strength of an acid in solution.

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What is Ocean Acidification?

Ocean acidification is a consequence of excess CO2 in the atmosphere dissolving in the ocean. This forms carbonic acid and can harm marine life.

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Determine Activation energy.

Using the plot of the graph provided, the activation energy can be determined during a kinetic study of the reaction.

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Cyclic Voltammetry

Determines what the anode(oxidation) and reduction(cathode) half reactions consist of in a cyclic voltammogram.

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Study Notes

  • It is a Chemistry 1022, 3rd mid-term exam and has a 90-minute time limit
  • There are 5 questions on 12 pages worth 100 points total
  • The last 4 pages includes constants, equations, thermochemical data, and a Periodic Table

Exam Instructions

  • All work must be shown in the spaces provided for full credit
  • When asked to briefly explain, answers should be limited to 2-3 sentences
  • Keep answers to 3-4 significant figures
  • Include units with all numerical answers
  • The exam is closed book and closed notebook
  • No cell phones or internet-enabled devices are permitted

Multiple-Choice Question Instructions

  • Multiple-choice questions with the phrase "Select All" have more than one correct answer
  • Darken the letter of your choice on all multiple-choice responses

Academic Integrity Statement

  • By signing, the student agrees to abide by the provisions of the Code of Academic Integrity
  • Compliance includes using a calculator ONLY as a calculation aid
  • No other electronic or wireless devices including network-accessible calculators are allowed

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