Chemical Substances and Reactions Quiz

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Questions and Answers

What is the primary catalyst used in alkene catalytic cracking?

  • Graphene
  • Zeolite (correct)
  • Charcoal
  • Silica

What is produced when butane undergoes cracking and the hydrogen supply is insufficient?

  • Ethine (correct)
  • Ethene only
  • Ethane only
  • Only propane

Which of the following statements about complete combustion of alcohols is correct?

  • Produces carbon monoxide and carbon
  • Produces carbon dioxide and water (correct)
  • Produces methane and water
  • Produces only water

What functional group characterizes carboxylic acids as opposed to alcohols?

<p>COOH (B)</p> Signup and view all the answers

What is the result of polymerization of ethene monomers?

<p>Polyethene (D)</p> Signup and view all the answers

What must be produced during condensation polymerization?

<p>Water (B)</p> Signup and view all the answers

Which process involves combining two monomers with two functional groups?

<p>Condensation polymerization (D)</p> Signup and view all the answers

What allows rechargeable batteries to restore their functionality?

<p>Reverse reaction through current (A)</p> Signup and view all the answers

What is the primary use of hydrogen fuel cells?

<p>To generate voltage through recombining hydrogen and oxygen (A)</p> Signup and view all the answers

What is the main outcome when alcohols oxidize with an oxidizing agent?

<p>Formation of carboxylic acids (A)</p> Signup and view all the answers

What charge does a lithium ion carry when it loses its outer electron?

<p>Li+ (C)</p> Signup and view all the answers

What is the chemical formula for beryllium chloride?

<p>BeCl2 (B)</p> Signup and view all the answers

Which type of bonding involves the sharing of electrons?

<p>Covalent bonding (D)</p> Signup and view all the answers

What must the total charge add up to in an ionic compound?

<p>Zero (A)</p> Signup and view all the answers

Which of the following can conduct electricity when melted or dissolved?

<p>Ionic compounds (C)</p> Signup and view all the answers

What is the structure of diamond primarily made up of?

<p>Giant molecular structures of carbon (D)</p> Signup and view all the answers

Which option describes the interaction in graphite that allows it to conduct electricity?

<p>Delocalized electrons (A)</p> Signup and view all the answers

What is a property of simple molecular structures?

<p>Weak intermolecular forces (B)</p> Signup and view all the answers

What causes the majority of the greenhouse effect?

<p>Water vapor (A)</p> Signup and view all the answers

What role do nanoparticles play due to their high surface to volume ratio?

<p>They can fulfill a purpose efficiently (B)</p> Signup and view all the answers

Which process is primarily used to ensure drinking water is safe by removing large particles?

<p>Filtration (D)</p> Signup and view all the answers

What type of structure is graphene considered to be?

<p>Two-dimensional sheet of carbon (A)</p> Signup and view all the answers

How is the relative formula mass calculated?

<p>By adding individual atomic masses (D)</p> Signup and view all the answers

What is produced by complete combustion of alkanes?

<p>Carbon dioxide and water (C)</p> Signup and view all the answers

Which of the following is a characteristic of longer alkanes compared to shorter ones?

<p>Higher viscosity (B)</p> Signup and view all the answers

Why are metals stronger in alloy form?

<p>Different sized atoms disrupt the lattice (C)</p> Signup and view all the answers

What type of bond exists in alkenes that distinguishes them from alkanes?

<p>Double bond (C)</p> Signup and view all the answers

What defines a mole in chemistry?

<p>A specific number of molecules (A)</p> Signup and view all the answers

What is the function of the fractionating column in the separation of crude oil?

<p>To condense the gases into liquids (A)</p> Signup and view all the answers

What happens to bromine water when it reacts with an alkene?

<p>It turns colorless (D)</p> Signup and view all the answers

What is required to convert seawater into potable water?

<p>Desalination (C)</p> Signup and view all the answers

Which fraction of crude oil is typically used as jet fuel?

<p>Kerosene (A)</p> Signup and view all the answers

What type of water is classified as potable?

<p>Water safe to drink (D)</p> Signup and view all the answers

What is the general formula for alkanes?

<p>C$n$H$2n$+2 (A)</p> Signup and view all the answers

Which method is NOT commonly used to ensure water is free from microbes?

<p>Distillation (B)</p> Signup and view all the answers

What is necessary to produce shorter alkanes from longer alkanes?

<p>Cracking (C)</p> Signup and view all the answers

What is the reason that hydrochloric acid has a lower pH than ethanoic acid at the same concentration?

<p>Hydrochloric acid is stronger than ethanoic acid. (B)</p> Signup and view all the answers

During the electrolysis of aluminum oxide, what is produced at the anode?

<p>Oxygen gas. (D)</p> Signup and view all the answers

In a neutralization reaction, what will happen to the temperature as the reaction reaches maximum energy release?

<p>Temperature will stabilize at a constant level. (B)</p> Signup and view all the answers

What is the significance of the activation energy in a chemical reaction?

<p>It is the energy required to start the reaction. (B)</p> Signup and view all the answers

Which of the following ions will be reduced at the cathode during electrolysis of a sodium chloride solution?

<p>H+ (D)</p> Signup and view all the answers

What occurs when there is a net energy release in a chemical reaction?

<p>Temperature increases. (D)</p> Signup and view all the answers

What happens to aluminum hydroxide when excess sodium hydroxide is added?

<p>It dissolves in solution. (C)</p> Signup and view all the answers

Which precipitate is formed when chloride ions are mixed with silver nitrate solution?

<p>White precipitate (A)</p> Signup and view all the answers

What happens to potential energy and kinetic energy during an exothermic reaction?

<p>Potential energy decreases while kinetic energy increases. (B)</p> Signup and view all the answers

What is the process called when an acid and alkali react together?

<p>Neutralization (B)</p> Signup and view all the answers

Which gas is known to turn lime water cloudy when bubbled through it?

<p>Carbon dioxide. (C)</p> Signup and view all the answers

How do you calculate concentration from moles and volume?

<p>Moles divided by volume (B)</p> Signup and view all the answers

What is formed at the cathode during the electrolysis of aluminum oxide?

<p>Solid aluminum. (D)</p> Signup and view all the answers

What particle in an atom has a charge of zero?

<p>Neutron (A)</p> Signup and view all the answers

Which type of acid is ethanoic acid classified as?

<p>Weak acid. (B)</p> Signup and view all the answers

Which of the following statements about isotopes is true?

<p>Isotopes of an element have the same number of protons. (A)</p> Signup and view all the answers

What is a potential consequence of a reaction being reversible?

<p>Products can revert to original reactants. (D)</p> Signup and view all the answers

What happens when an ionic compound like aluminum oxide is melted?

<p>It can conduct electricity due to free-moving ions. (D)</p> Signup and view all the answers

Which method can be used to increase the rate of a chemical reaction?

<p>Increasing surface area (A)</p> Signup and view all the answers

What does the mass number represent in an atom?

<p>The total number of protons and neutrons (A)</p> Signup and view all the answers

In a situation without halide ions, what will be oxidized at the anode during electrolysis?

<p>Oxygen ions. (C)</p> Signup and view all the answers

When conducting a titration, what indicates that neutralization has occurred?

<p>The solution turns pink. (C)</p> Signup and view all the answers

In the periodic table, which group contains elements that typically gain one electron?

<p>Group 7 (D)</p> Signup and view all the answers

What does the percentage yield represent in a chemical reaction?

<p>The amount of product made compared to theoretical amount. (C)</p> Signup and view all the answers

What is the primary characteristic of metals in relation to their electrons?

<p>They lose electrons to form positive ions. (A)</p> Signup and view all the answers

What does it indicate if the potential energy of the products is greater than the reactants?

<p>An endothermic reaction occurred. (A)</p> Signup and view all the answers

Which group in the periodic table is known for having a full outer shell?

<p>Noble Gases (D)</p> Signup and view all the answers

What observable change occurs when hydrochloric acid reacts with sodium thiosulfate?

<p>The solution turns cloudy. (A)</p> Signup and view all the answers

What feature distinguishes transition metals from other elements?

<p>They can donate varying numbers of electrons. (A)</p> Signup and view all the answers

In a gas syringe experiment, what change indicates that the reaction has completed?

<p>Constant volume over time. (A)</p> Signup and view all the answers

Which of the following correctly describes the electron configuration of magnesium?

<p>2, 8, 2 (C)</p> Signup and view all the answers

What effect does increasing temperature have on the rate of a reaction?

<p>Increases both frequency and energy of collisions. (B)</p> Signup and view all the answers

What happens when an atom gains electrons?

<p>It becomes an ion. (D)</p> Signup and view all the answers

What is the role of a catalyst in a chemical reaction?

<p>It reduces the activation energy. (C)</p> Signup and view all the answers

What occurs as you move down the group of alkali metals?

<p>The outer electron becomes easier to lose. (A)</p> Signup and view all the answers

What type of precipitate is formed when sulfate ions react with barium chloride?

<p>White precipitate (C)</p> Signup and view all the answers

To achieve greater accuracy in titration, what should one do as approaching the end point?

<p>Add the acid drop by drop. (B)</p> Signup and view all the answers

How is the average relative atomic mass of an element determined?

<p>By calculating the weighted average of all isotopes. (C)</p> Signup and view all the answers

What term describes the attraction between positively charged protons and negatively charged electrons?

<p>Electrostatic force (D)</p> Signup and view all the answers

Which electron shell can hold a maximum of eight electrons?

<p>Second shell (D)</p> Signup and view all the answers

What is unique about the electrons in a metallic bond?

<p>They are delocalized and free to move. (B)</p> Signup and view all the answers

What happens to the equilibrium position when pressure is increased in a reaction where there are more moles of reactants than products?

<p>The equilibrium shifts to the right. (B)</p> Signup and view all the answers

How does an increase in temperature affect an endothermic reaction?

<p>It favors the forward reaction. (B)</p> Signup and view all the answers

Which of the following describes the process of making ammonia in the Haber process?

<p>It takes place around 450°C and 200 atmospheres of pressure. (B)</p> Signup and view all the answers

What is the primary purpose of adding nitrogen to fertilizers?

<p>To provide nutrients for plant growth. (A)</p> Signup and view all the answers

Which characteristic differentiates thermosetting polymers from thermosoftening polymers?

<p>Thermosetting polymers have cross-linking between chains. (B)</p> Signup and view all the answers

Why are alloys generally stronger than pure metals?

<p>They disrupt the regular lattice structure. (D)</p> Signup and view all the answers

What is the role of a sacrificial metal in corrosion prevention?

<p>It reacts with oxygen preferentially. (C)</p> Signup and view all the answers

Which statement best describes the greenhouse effect?

<p>It prevents heat from escaping the earth's atmosphere. (C)</p> Signup and view all the answers

What is the significance of the position of equilibrium shifting to the right?

<p>More products are being formed. (D)</p> Signup and view all the answers

Which of the following is true regarding the composition of gases in the Earth's atmosphere?

<p>It has changed due to biological processes and geological events. (C)</p> Signup and view all the answers

What happens to carbon dioxide levels during photosynthesis?

<p>They are converted to oxygen. (B)</p> Signup and view all the answers

Which of the following is used to produce potassium in fertilizers?

<p>Mining potassium chloride and sulfate. (B)</p> Signup and view all the answers

What defines a high-density polyethylene (HDPE)?

<p>It has a tightly packed molecular structure. (C)</p> Signup and view all the answers

How many moles of water are produced when 64 g of methane reacts completely with oxygen?

<p>8 moles (C)</p> Signup and view all the answers

What is the formula to calculate the number of moles from mass?

<p>$\text{Moles} = \frac{\text{Mass}}{\text{Rams}}$ (D)</p> Signup and view all the answers

In a reaction where one mole of methane and one mole of oxygen are available, what is the limiting reactant?

<p>Oxygen (A)</p> Signup and view all the answers

What is the concentration in moles per decim cubed if one mole of HCl is dissolved in 1 decim cubed of water?

<p>1 molar (D)</p> Signup and view all the answers

What happens when a more reactive metal is placed in a compound of a less reactive metal?

<p>The more reactive metal displaces the less reactive metal. (C)</p> Signup and view all the answers

What is referred to when a substance loses oxygen in a chemical reaction?

<p>Reduction (B)</p> Signup and view all the answers

Which of the following acids is classified as a strong acid?

<p>Hydrochloric acid (A)</p> Signup and view all the answers

In an acid with a pH of 3, how does its H+ ion concentration compare to an acid with a pH of 5?

<p>100 times more concentrated (B)</p> Signup and view all the answers

What is produced when sodium hydroxide reacts with hydrochloric acid?

<p>Sodium chloride and water (A)</p> Signup and view all the answers

What will happen to the amount of copper in a solution when zinc is placed in a copper sulfate solution?

<p>Copper will decrease. (A)</p> Signup and view all the answers

What defines a neutral pH?

<p>pH of 7 (B)</p> Signup and view all the answers

What is the primary indication of an acid on the pH scale?

<p>Higher concentration of H+ ions (C)</p> Signup and view all the answers

What will the pH level be if an acid has 10 times the H+ ion concentration of an acid with pH 4?

<p>pH 2 (D)</p> Signup and view all the answers

What happens during the process of smelting?

<p>More reactive metals reduce metallic oxides. (D)</p> Signup and view all the answers

What is a compound?

<p>A substance made of two or more different types of atoms chemically bonded together. (A)</p> Signup and view all the answers

What does the chemical formula H2O indicate?

<p>There is one oxygen atom and two hydrogen atoms. (C)</p> Signup and view all the answers

When balancing chemical equations, which of the following is a recommended step?

<p>Start balancing elements that are only in compounds. (C)</p> Signup and view all the answers

Which of the following is an example of a physical change?

<p>Melting of ice to form water. (A)</p> Signup and view all the answers

How can mixtures be separated using filtration?

<p>By passing the mixture through a filter to catch solid particles. (D)</p> Signup and view all the answers

What does RF stand for in chromatography?

<p>Retention Factor. (B)</p> Signup and view all the answers

What occurs to particles in solid matter?

<p>They vibrate around fixed positions. (C)</p> Signup and view all the answers

What is the boiling point of a pure substance like water?

<p>It should be a specific temperature. (D)</p> Signup and view all the answers

Which of the following statements about distillation is true?

<p>It separates mixtures based on different boiling points. (A)</p> Signup and view all the answers

What is a formulation in chemistry?

<p>A mixture designed for a specific purpose. (D)</p> Signup and view all the answers

Which of the following correctly describes JJ Thompson's contribution to atomic theory?

<p>He proposed the plum pudding model. (C)</p> Signup and view all the answers

What happens to gases that distinguishes them from solids and liquids?

<p>Gases can be easily compressed. (C)</p> Signup and view all the answers

Which statement describes the correct way to indicate the state of a substance in a chemical equation?

<p>Use state symbols in the form of letters in brackets. (B)</p> Signup and view all the answers

Flashcards

Atomic Number

The number of protons in an atom's nucleus. It defines the element.

Isotopes

Atoms of the same element with different numbers of neutrons. This means they have different masses.

Average Relative Atomic Mass

The average mass of all isotopes of an element found in nature.

Outer Shell

The outermost shell or energy level of an atom.

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Mass Number

The number of protons and neutrons in an atom's nucleus. It indicates the atom's mass.

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Ion

An atom that has gained or lost electrons, giving it a net positive or negative charge.

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Metals

Elements that easily donate electrons to achieve a full outer shell. They are highly reactive.

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Non-metals

Elements that easily accept electrons to achieve a full outer shell. They are also highly reactive.

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Group

A group of elements that have similar chemical properties due to having the same number of valence electrons.

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Alkali Metals

Elements in Group 1 of the periodic table. They readily lose one electron, forming 1+ ions.

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Halogens

Elements in Group 7 of the periodic table. They readily gain one electron, forming 1- ions.

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Noble Gases

Elements in Group 0 (or 8) of the periodic table. They have a full outermost shell and are extremely unreactive.

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Metallic Bonding

A type of bonding that occurs between metal atoms. Electrons are delocalized, allowing for conductivity.

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Ionic Bonding

A type of bonding that occurs between a metal and a non-metal. Electrons are transferred, forming oppositely charged ions.

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Transition Metals

They can donate a variable number of electrons, resulting in multiple possible ion charges (e.g., Fe2+ and Fe3+).

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Covalent bonding

A bond formed by the sharing of electrons between two atoms.

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Molecular ions

Groups of atoms that have a net electrical charge.

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Ionic compound

A substance formed by the attraction between positively charged metal ions and negatively charged nonmetal ions.

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Salt

A type of ionic compound that consists of a metal cation and a nonmetal anion.

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Molecule

A group of atoms held together by covalent bonds.

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Single covalent bond

A bond where two atoms share one pair of electrons.

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Double covalent bond

A bond where two atoms share two pairs of electrons.

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Triple covalent bond

A bond where two atoms share three pairs of electrons.

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Giant covalent structure

A giant structure where many atoms are bonded together by covalent bonds.

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Allotrope

A substance with the same type of atoms but arranged differently (e.g., diamond and graphite).

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Electrolyte

A substance that can conduct electricity, usually in liquid form (molten) or dissolved in water.

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Avogadro's constant

The number of particles (atoms or molecules) in one mole of a substance.

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Compound

A substance made up of two or more different types of atoms chemically bonded together.

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Chemical Equation

A representation of a chemical reaction using symbols.

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Mixture

Any combination of elements and/or compounds that are not chemically bonded together.

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Solution

A mixture where one substance is dissolved into another, usually a liquid.

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Filtration

The process of separating insoluble solid particles from a liquid.

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Crystallization

The process of separating a dissolved solid from a solution by evaporating the solvent.

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Distillation

The process of separating a mixture of liquids by heating and condensing the vapors, based on their different boiling points.

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Formulation

A specific mixture designed for a particular purpose with carefully measured amounts of substances.

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Chromatography

A technique used to separate components of a mixture, often based on their different attractions to a stationary phase.

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Retention Factor (Rf)

The ratio of the distance a substance travels in chromatography compared to the distance the solvent travels.

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Liquid

The state of matter with a fixed volume but not a fixed shape. Particles are free to move past each other.

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Melting or Evaporation

Adding energy, usually heat, to overcome forces of attraction between particles and change a solid to a liquid or a liquid to a gas.

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Plum Pudding Model

A model of the atom that proposed a sphere of positive charge with electrons embedded within.

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What is a mole?

The mass of a substance containing 6.022 x 10^23 particles (atoms or molecules).

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How do you calculate the number of moles?

The number of moles of a substance is equal to its mass in grams divided by its relative atomic or formula mass.

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What is stoichiometry?

The ratio of moles of one substance to another in a chemical reaction.

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What is a limiting reactant?

The reactant that is completely consumed first in a chemical reaction, limiting the amount of product that can be formed.

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What is molarity?

A solution's concentration expressed as the number of moles of solute per liter of solution.

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What is the reactivity series?

A measure of a substance's ability to donate electrons in a chemical reaction. Metals higher on the reactivity series are more reactive.

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What is displacement reaction?

When a more reactive metal displaces a less reactive metal from a compound, like Zinc displacing Copper from Copper Sulfate.

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Precipitate

A solid substance formed when two solutions are mixed together.

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What is smelting?

The process of extracting metals from their ores by heating them with carbon. It's used for metals less reactive than carbon.

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Reversible Reaction

A chemical reaction where the products can turn back into the original reactants.

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What is reduction?

A chemical reaction that involves the gain of electrons. The opposite of oxidation.

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Percentage Yield

The amount of product formed compared to the maximum theoretical amount possible.

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What is oxidation?

A chemical reaction that involves the loss of electrons. The opposite of reduction.

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Rate of Reaction

The speed at which a reaction happens.

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What is an acid?

A substance that releases H+ ions when dissolved in water, having a pH less than 7.

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Catalyst

A substance that speeds up a reaction but isn't used up in the process.

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Activation Energy

The minimum energy needed for a reaction to occur.

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What is an alkali?

A substance that releases OH- ions when dissolved in water, having a pH greater than 7.

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What is a neutralization reaction?

A neutralization reaction is where an acid and alkali react to produce salt and water. The resultant solution has a pH of 7.

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Indicator

A substance that changes color depending on the acidity or alkalinity of a solution.

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What is a salt?

A chemical compound formed when the hydrogen of an acid is replaced by a metal.

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What is the pH scale?

A logarithmic scale that measures the concentration of H+ ions in a solution. A pH of 3 has 10 times the concentration of H+ ions compared to a pH of 4.

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Methyl Orange

A substance that turns pink in acidic solutions.

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Neutralization Point

The point in a titration where the acid and base have completely reacted.

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Concentration

A measure of the amount of a substance in a given volume of solution.

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Exothermic Reaction

A chemical reaction that involves the release of heat energy.

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Endothermic Reaction

A chemical reaction that absorbs heat energy from the surroundings.

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Yield

The amount of product formed in a chemical reaction.

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Dynamic Equilibrium

A state where the rates of the forward and reverse reactions are equal, resulting in no overall change in the amounts of reactants and products.

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Le Chatelier's Principle

A principle stating that a system at equilibrium will shift to counteract any changes in conditions.

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Pressure and Equilibrium

Increasing the pressure on a system at equilibrium will favor the reaction that produces fewer moles of gas.

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Concentration and Equilibrium

Increasing the concentration of a reactant will shift the equilibrium to the right, favoring the forward reaction.

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Temperature and Equilibrium

Increasing the temperature will favor the endothermic reaction, while decreasing the temperature will favor the exothermic reaction.

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Haber Process

A process used to produce ammonia (NH3) from nitrogen (N2) and hydrogen (H2) gases.

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Bronze

An alloy of copper and tin.

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Brass

An alloy of copper and zinc.

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Steel

An alloy of iron and carbon, often containing chromium or nickel to resist corrosion.

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Corrosion

The slow destruction of a material due to chemical reactions.

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Sacrificial Metal

A protective coating of a more reactive metal applied to another metal to prevent corrosion.

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Galvanizing

The process of coating a metal with zinc to prevent corrosion.

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Greenhouse Gases

Gases that trap heat in the Earth's atmosphere, causing a warming effect.

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Global Warming

The gradual increase in Earth's average temperature due to the enhanced greenhouse effect.

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Cracking

A chemical reaction where larger molecules are broken down into smaller molecules, often by heat and a catalyst.

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Alkane

A saturated hydrocarbon with only single bonds between carbon atoms. The general formula is CnH2n+2.

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Alkene

An unsaturated hydrocarbon with at least one double bond between carbon atoms. The general formula is CnH2n.

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Polymerization

The process of joining monomers together to form a long chain polymer, often triggered by heat or a catalyst.

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Addition polymerization

A type of polymerization where monomers with a double bond are joined together, breaking the double bond and forming single bonds.

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Condensation polymerization

A type of polymerization where two monomers with functional groups react to form a polymer, releasing a small molecule (often water) in the process.

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Alcohol

A type of organic compound containing an -OH functional group attached to a carbon atom. Their names always end in 'ol'.

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Carboxylic acid

A type of organic compound containing a -COOH functional group attached to a carbon atom. Their names always end in 'oic acid'.

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Polyester

A type of polymer formed by the condensation polymerization of bifunctional monomers, containing ester linkages within its chain structure.

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Acid Strength

The strength of an acid refers to its ability to donate hydrogen ions (H+). A strong acid fully dissociates in solution, meaning all its molecules release H+ ions. A weak acid only partially dissociates, with only a small fraction of molecules releasing H+ ions.

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Acid Concentration

The concentration of an acid is the amount of acid dissolved in a given volume of solution. A higher concentration means more acid molecules per unit volume, resulting in a higher concentration of H+ ions.

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Electrolysis of Ionic Compounds

Ionic compounds, when melted, can conduct electricity because their ions are free to move. The positive ions (cations) move towards the negatively charged electrode (cathode), while the negative ions (anions) move towards the positively charged electrode (anode).

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Reduction at the Cathode

In electrolysis, the process of gaining electrons is called reduction, and it always occurs at the cathode. Cations, being positively charged, attract electrons and are reduced.

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Oxidation at the Anode

In electrolysis, the process of losing electrons is called oxidation, and it always occurs at the anode. Anions, being negatively charged, lose electrons and are oxidized.

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Electrolysis for Metal Extraction or Purification

Electrolysis can be used to extract metals from their compounds or purify them. In the case of aluminum oxide, the oxygen produced at the anode reacts with the carbon anode, requiring its replacement.

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Cryolite in Aluminum Extraction

Cryolite is added to molten aluminum oxide to lower its melting point, making the extraction process more efficient and cost-effective.

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Electrolysis of Ionic Solutions

In electrolysis of ionic solutions, the less reactive ion will be attracted to the electrodes and undergo reduction or oxidation. For example, in the case of sodium chloride solution, H+ ions are less reactive than Na+ ions and will be reduced at the cathode, producing hydrogen gas.

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Energy Profile

An energy profile diagram visually represents the energy changes that occur during a chemical reaction. The Y-axis represents potential energy, while the X-axis represents the progress of the reaction.

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Bond Energy

The breaking of a chemical bond requires energy, while the formation of a new chemical bond releases energy. The net energy change during a reaction is determined by the difference between the energy required for bond breaking and the energy released by bond formation.

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Bond Energies in Chemical Reactions

Each type of covalent bond requires a specific amount of energy to break it. For example, a carbon-hydrogen bond requires 413 kJ/mol to break.

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Carbon Monoxide

A colorless, odorless, and toxic gas. It binds to red blood cells preventing oxygen transport, leading to fatal consequences.

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Sulfur Dioxide

A type of atmospheric pollution caused by the burning of fossil fuels. It dissolves in water forming acid rain.

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Potable Water

Water that has low levels of salt and microbes, making it safe to drink. It's a crucial resource around the world.

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Desalination

The process of removing salt from seawater to make it drinkable. Requires significant energy input.

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Osmosis

When water moves from a high concentration area to a low concentration area through a semi-permeable membrane. This can occur in living organisms.

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Organic Compounds

Molecules that contain carbon as the backbone of their structure. They are found in many natural and man-made materials, including crude oil.

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Crude Oil

A mixture of hydrocarbons found underground, mainly made up of alkanes. It is a valuable source of energy and raw materials.

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Fractional Distillation

A process that separates hydrocarbons in crude oil based on their boiling points. It's crucial for producing useful fuels like gasoline.

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Intermolecular Forces

The attraction between molecules. Stronger intermolecular forces lead to higher boiling points and greater viscosity.

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Petrol

A fraction of hydrocarbons used as fuel in cars. It's a flammable mixture of short-chain alkanes.

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Functional Group

A functional group that breaks the double bond in alkenes. It is commonly used in chemical reactions.

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Study Notes

Chemical Substances and Reactions

  • Substances: Substances are made of atoms. Elements are different types of atoms, represented in the periodic table. A compound contains two or more different types of atoms bonded together.
  • Chemical Formulas: Chemical formulas, like H₂O for water, show the type and number of atoms in a compound. If no number follows an element symbol, it's implied to be one.
  • Chemical Reactions: In chemical reactions, atoms rearrange, but are not created or destroyed. Equations must be balanced to have the same number and type of atoms on both sides. Balance atoms within compounds first, then multiply elements/compounds with coefficients.
  • Mixtures: Mixtures are combinations of elements and compounds that are not chemically bonded. Examples include air and salt water.
  • Separating Mixtures: Different methods exist to separate mixtures:
    • Filtration: Separates large, insoluble particles from a liquid.
    • Crystallization: Separates a dissolved solid (solute) from a liquid (solvent) by evaporating the solvent.
    • Distillation: Separates different liquids in a mixture based on their different boiling points. Fractional distillation further refines this process.
  • Purity: Testing melting/boiling points helps determine substance purity. A pure substance has a very specific and constant melting/boiling point.
  • Formulations: Formulations are specially designed mixtures used in specific ways (e.g. paints, fuels, alloys).
  • Chromatography: Separates substances in a mixture, like pigments, drugs, etc. using a stationary and mobile phase. The retention factor (Rf) value aids in identification.

States of Matter and Atomic Structure

  • States of Matter: The three main states are solid, liquid, and gas. The difference lies in particle arrangement and energy. Gases are compressible, while solids and liquids are not.
  • Energy Changes: Melting and evaporation require energy input to overcome attractive forces between particles.
  • State Symbols: State symbols in equations (s, l, g, aq).
  • Atomic Models:
    • Plum Pudding Model: Atoms have positive and negative charges embedded within.
    • Nuclear Model: Atoms have a tiny, positively charged nucleus with electrons orbiting.
    • Shell Model: Electrons exist in shells or orbitals.
    • Neutron Discovery: The nucleus also contains neutrally charged neutrons.
  • Atoms vs. Ions: Ions are atoms that have gained or lost electrons, thus having a charge.
  • Periodic Table:
    • Atomic Number: The number of protons in the nucleus.
    • Mass Number (RAM/Relative Atomic Mass): The number of protons and neutrons in the nucleus. Isotopes are atoms of the same element with different numbers of neutrons. The periodic table often shows the average mass for all isotopes in the world.
    • Electron Configuration: Electrons fill shells sequentially (2, 8, 8, 2).
      • Metal atoms tend to lose electrons to gain a full outer shell.
      • Nonmetal atoms tend to gain electrons.

Periodic Table and Bonding

  • Metals, Nonmetals, Metalloids: The periodic table is categorized by various properties, including these general groups.
  • Groups: The vertical columns of the periodic table, denoting the number of electrons in the outermost shell.
    • Group 1 (Alkali Metals): Donate 1 electron when bonding, increasing reactivity down the group.
    • Group 7 (Halogens): Accept 1 electron, decreasing reactivity down the group.
    • Group 0 or 8 (Noble Gases): Full outer shell, unreactive.
  • Ions (Charges):
    • Group 1: +1
    • Group 2: +2
    • Group 6: -2
    • Group 7: -1
    • Some transition metals can have variable charges (e.g., Fe²⁺, Fe³⁺).
  • Metallic Bonding: A lattice of positive ions with delocalized electrons holding it together. Metals are typically good conductors of heat and electricity.
  • Ionic Bonding: A metal loses electrons to a nonmetal, forming oppositely charged ions that are attracted to each other in a lattice. Ionic compounds have high melting/boiling points and are usually crystalline.
  • Dot and Cross Diagrams: Visual representations of electrons in ionic bonds.
  • Molecular Ions: Ions formed from multiple atoms (e.g., OH⁻).
  • Covalent Bonding: Nonmetals share electrons to gain a full outer shell.

Types of Formulas and Chemical Equations

  • Molecular/Covalent Structures, simple covalent: Consisting of individual molecules, they have relatively low boiling points.
  • Giant Covalent Bonding: Atoms are covalently bonded in a continuous network (e.g. diamond, graphite).
  • Allotropes Different forms of the same element with different structures/properties.
  • Alloys A mixture of different metals bonded together. Alloy properties are often superior to pure metal properties.
  • Compounds: The names of compounds (e.g., salts) are derived from the ion names of their constituent parts.
  • Ionic compound Names are derived from the names of their constituent ions, the metal cation followed by the non-metal anion.

Moles calculations

  • Moles: A way to compare quantities of substances. Number of moles relates to mass, formula mass and volume, and is found using g/RAM = Moles
  • Stoichiometry: Using the ratios of moles in a balanced chemical equation to predict or calculate quantities of reactants and products.
  • Reactions with Gas Production If a gas is produced and leaves the reaction vessel, the mass change is considered the loss of gas, rather than an error in calculations.
  • Limiting Reactant: The reactant that runs out first, limiting the maximum amount of product that can be formed.

Thermochemistry

  • Exothermic Reactions: Net energy is released to the surroundings; ΔH = negative, temperature increase of surroundings.
  • Endothermic Reactions: Net energy is absorbed from the surroundings; ΔH = positive, temperature decrease of surroundings.
  • Energy Profiles: Visual representations of the energy changes in a reaction, showing activation energy.
  • Activation Energy (Ea): Energy needed to start a chemical reaction.
  • Bond Energy: Energy required to break a bond.

Identifying Reactions

  • Flame Tests: Using different metal salt flames to identify metals.
  • Testing Solutions: Identifying ions by reactions.
  • Precipitation Reactions: Forming a solid precipitate when reacting solutions of different ions.
  • Titration: Determining the concentration of a solution by gradually adding a solution of known concentration until neutralization occurs.
  • Neutralization Reactions: Reaction between an acid and a base to produce salt and water.
  • Reversibility: Some processes can be reversed by adjusting conditions.
  • Haber Process: Industrial process for producing ammonia from nitrogen and hydrogen, showing the importance of yield and reaction rate.
  • Fertilizers & their Materials

Solutions and Electrolysis

  • Concentration: Given as g/dm³ or mol/dm³ (molar).
  • Dissolution: Substances dissolving and their ions dissociating in water.
  • Electrolysis: Using an electric current to drive a non-spontaneous reaction. Separating elements, purifying metals using inert electrodes.
  • pH scale: A logarithmic scale measuring acidity or alkalinity based on H+ ions concentration (strong vs. weak acids), and the concentration of OH- ions for bases.
  • Oxidation and Reduction: Loss and gain of electrons (OIL RIG).

Organic Chemistry Basics (and some more detail for triple)

  • Hydrocarbons: Compounds consisting of only carbon and hydrogen.
  • Alkanes: Single-bonded hydrocarbons (general formula CₙH₂ₙ₊₂).
  • Alkenes: Double-bonded hydrocarbons (contain a C=C double bond; unsaturated).
  • Alcohols: Organic compounds with -OH (hydroxyl) functional groups.
    • Oxidation of alcohols form acids.
  • Polymerization: Joining monomers to make polymers.
    • Addition polymerization: Alkenes form polymers by adding monomers to existing chains.
    • Condensation polymerization: Two monomers react to produce a polymer and a small molecule (water).
  • Crude Oil Fractions: Separated by fractional distillation based on differences in boiling points.
    • Petrol (gasoline), kerosene, diesel, heavy fuel oil, LPG.
  • Cracking: Breaking down long-chain hydrocarbons into shorter, more useful alkenes and alkanes.
  • Esters: Formed from the condensation reaction of an alcohol and a carboxylic acid.

Atmosphere & Environmental Chemistry

  • Changing Atmosphere: Historical data points are used to model or extrapolate the atmosphere's composition over time.
  • Greenhouse Effect: Gases trap heat in the atmosphere, preventing it from escaping into space. Water vapor is the significant greenhouse gas.
  • Fossil Fuels: Combustion releases CO₂ and other pollutants.
  • Acid Rain: Burning fossil fuels releases sulfur dioxide and nitrogen oxides.
  • Air Pollutants: CO, SO₂, NOx, pollutants.

Water Treatment and Potable Water

  • Potable Water: Water safe for consumption, with low levels of microbes and salts.
  • Desalination: Removing salt from seawater (distillation, reverse osmosis).
  • Water Treatment: Removing impurities like microbes and sediment.

Corrosion & Alloys

  • Corrosion: Chemical deterioration of materials by reactions with the environment (e.g. rusting of iron).
  • Sacrificial Protection: Using a more reactive metal to protect another metal.
  • Alloys: Mixtures of metals that often have improved properties.

Reaction Rates

  • Rate of Reactions: The speed of a chemical reaction (change in quantity/time).
  • Factors Affecting Rate (experiment design elements):
    • Concentration (solution, gas): More frequent collisions.
    • Pressure (gas): More frequent collisions.
    • Surface Area (solid): More surface area for collisions.
    • Temperature: Increased kinetic energy, more energetic collisions.
    • Catalyst: Lowering activation energy means more collisions become successful, but the catalyst is unchanged.
  • Reversible Reactions & Equilibrium: Rates become equal and no observable change occurs, equilibrium reached, but conditions can affect the position of equilibrium.
  • Le Chatelier's Principle: How changes in pressure, concentration, and temperature shift the equilibrium.

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