Chemical Reactions and Heat Energy Quiz
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Questions and Answers

According to the first law of thermodynamics, what is the relationship between internal energy change (ΔE), heat (q), and work (w) for a system?

  • ΔE = w - q
  • ΔE = q - w (correct)
  • ΔE = -q - w
  • ΔE = q + w
  • Which of the following is the correct definition of enthalpy (H) in thermodynamics?

  • H = E - 2PV
  • H = PV - E
  • H = E + PV (correct)
  • H = E - PV
  • In a constant pressure process, the heat absorbed by a system is equal to the change in:

  • volume (ΔV)
  • internal energy (ΔE)
  • pressure (ΔP)
  • enthalpy (ΔH) (correct)
  • The calorific value of a fuel is defined as:

    <p>the amount of heat released when one mole of the fuel is burned completely in oxygen</p> Signup and view all the answers

    The heat of reaction (ΔH) for a chemical reaction is equal to:

    <p>the difference between the enthalpies of the reactants and products</p> Signup and view all the answers

    In an isothermal process, the change in internal energy (ΔE) of a system is:

    <p>always zero</p> Signup and view all the answers

    What is the relationship between ΔH and ΔE in a chemical reaction?

    <p>ΔH = ΔE + PΔV</p> Signup and view all the answers

    What is the significance of the heat of reaction in a chemical equation?

    <p>It represents the negative of the enthalpy change of the reaction.</p> Signup and view all the answers

    What is the unit of heat of reaction (ΔH)?

    <p>Kilocalories</p> Signup and view all the answers

    Why are the calorific values of gaseous fuels usually determined in constant volume calorimeters?

    <p>To avoid the additional energy of expansion</p> Signup and view all the answers

    What is the value of q in a constant volume calorimeter?

    <p>q = ΔE</p> Signup and view all the answers

    What is the value of ΔH for the reaction H2(g) + F2(g) → H2F2 (g) if ΔE = – 14.2 kcal/mole at 25º C?

    <p>ΔH = ΔE - RT</p> Signup and view all the answers

    According to the first law of thermodynamics, what is the change in internal energy (ΔE) for a process where a system absorbs 400 J of thermal energy from its surroundings?

    <p>906 J</p> Signup and view all the answers

    What is the maximum work done when pressure on 10 g of hydrogen is reduced from 20 to one atmosphere at a constant temperature of 273 K, given that the gas behaves ideally?

    <p>-8126.65 cals</p> Signup and view all the answers

    Will there be any change in internal energy (ΔE) when the pressure on 10 g of hydrogen is reduced from 20 to one atmosphere at a constant temperature of 273 K?

    <p>No, ΔE = 0</p> Signup and view all the answers

    What is the heat content (q) of the system in a process where the pressure on 10 g of hydrogen is reduced from 20 to one atmosphere at a constant temperature of 273 K?

    <p>-8126.65 cals</p> Signup and view all the answers

    What is the enthalpy (H) of a system at constant pressure?

    <p>The internal energy (E) plus the PV energy</p> Signup and view all the answers

    What is the difference between the heat content and enthalpy of a system?

    <p>Heat content is the same as internal energy (E) at constant volume, while enthalpy is the same as internal energy (E) plus PV energy at constant pressure</p> Signup and view all the answers

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