Chemical Kinetics: Reaction Rates and Rate Laws
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Questions and Answers

Which of the following factors most significantly contributes to the desertification process in regions like the Sahel?

  • Increased tectonic activity causing shifts in land elevation and drainage patterns.
  • The cyclical shifts in global ocean currents leading to decreased rainfall.
  • The natural expansion and contraction of desert ecosystems over centuries.
  • Deforestation and unsustainable agricultural practices that degrade soil quality. (correct)

How does the Aswan High Dam exemplify a trade-off between economic development and ecological consequences?

  • It promotes tourism and recreational activities but increases water salinity harmful to aquatic life.
  • It facilitates navigation and transportation but reduces water availability for downstream communities.
  • It supports industrial growth and urbanization but accelerates soil erosion in surrounding areas.
  • It provides hydroelectric power and controls flooding but disrupts the natural silt deposition vital for agriculture. (correct)

How do rift valleys typically influence regional climate patterns and biodiversity?

  • By isolating populations and promoting speciation due to varied microclimates and habitats. (correct)
  • By channeling prevailing winds, resulting in uniform temperature and precipitation distribution.
  • By creating rain shadows that lead to desertification on one side and lush vegetation on the other.
  • By promoting the formation of large, shallow lakes that support unique aquatic ecosystems.

What is the most significant long-term challenge posed by the expansion of the Sahara Desert?

<p>Displacement of human populations and increased competition for dwindling resources. (C)</p> Signup and view all the answers

In what way do oases impact human settlement patterns and economic activities in arid regions?

<p>They provide essential water and agricultural resources, enabling localized agriculture and trade. (D)</p> Signup and view all the answers

Which of the following best explains the ecological importance of the Serengeti?

<p>It functions as a biodiversity hotspot with one of the largest remaining intact large mammal migrations. (C)</p> Signup and view all the answers

How does the formation of the Niger Delta influence regional biodiversity and economic activities?

<p>It forms a unique estuarine environment supporting diverse aquatic species and significant oil reserves. (D)</p> Signup and view all the answers

What is a key distinction between a desert and a desertified area?

<p>Deserts are naturally arid environments, while desertified areas are regions where fertile land has turned into desert due to human actions or climate change. (D)</p> Signup and view all the answers

How do escarpments impact transportation networks and settlement patterns?

<p>Escarpments create natural barriers, often limiting road and railway construction and influencing settlement locations. (A)</p> Signup and view all the answers

Which factor poses the greatest challenge to the long-term sustainability of aquifer-dependent communities?

<p>Over-extraction of groundwater leading to depletion and land subsidence. (B)</p> Signup and view all the answers

Flashcards

Mount Kilimanjaro

Africa's highest peak.

Escarpment

A steep slope with a nearly flat plateau on top.

Oasis

Supports vegetation and wildlife in the desert and is a critical resource for people living in this area.

Canopy

Refers to the top of trees, about 150 feet above the ground.

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Sahel

A narrow band of dry grassland that runs east to west on the southern edge of the Sahara.

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Nile River

The world's longest river.

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Serengeti

Grasslands in Tanzania.

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Sahara

The largest desert in the world.

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Aquifer

Huge stores of underground water.

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Desertification

An expansion of dry conditions to moist areas that are next to deserts.

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Study Notes

  • Chemical kinetics, also called reaction kinetics, concerns the investigation of reaction rates.
  • Reaction rate refers to the change in reactant or product concentration per unit time.
  • Rate is expressed as Rate = -Δ[A]/Δt = Δ[B]/Δt, where A is a reactant and B is a product.
  • The negative sign indicates the rate of disappearance of the reactant.
  • For a reaction aA + bB → cC + dD, the rate is expressed as Rate = -1/a Δ[A]/Δt = -1/b Δ[B]/Δt = 1/c Δ[C]/Δt = 1/d Δ[D]/Δt.

Factors Affecting Reaction Rate

  • Reactant concentration influences reaction rate
  • Temperature influences reaction rate
  • Surface area influences reaction rate
  • Catalysts influence reaction rate

Rate Law

  • The rate law correlates reaction rate with the rate constant and reactant concentrations raised to certain powers.
  • For a reaction aA + bB → cC + dD, the rate law is Rate = k[A]^m[B]^n, where k is the rate constant.
  • m represents the reaction order with respect to A and n represents the reaction order with respect to B; m + n indicates the overall reaction order.
  • Crucially, the values of m and n must be determined experimentally and are not derived from the coefficients in the balanced equation.

Reaction Order

Order Rate law Rate constant unit [A]t vs time plot Half-life ($t_{1/2}$)
0 Rate = k Ms$^{-1}$ linear $t_{1/2} = \frac{[A]_0}{2k}$
1 Rate = k[A] s$^{-1}$ non-linear $t_{1/2} = \frac{0.693}{k}$
2 Rate = k$[A]^2$ M$^{-1}$s$^{-1}$ non-linear $t_{1/2} = \frac{1}{k[A]_0}$

Activation Energy

  • Activation energy (Ea) denotes the minimum energy needed to start a chemical reaction.
  • The rate constant k relies on activation energy (Ea) and temperature, as described by the Arrhenius equation: k = Ae^(-Ea/RT).
  • A represents the frequency factor and R is the gas constant (8.314 J/mol â‹… K), while T is absolute temperature.
  • The natural logarithm of the Arrhenius equation is: ln(k) = -Ea/RT + ln(A).
  • The two-point form of the equation is: ln(k2/k1) = Ea/R (1/T1 - 1/T2).

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Explore chemical kinetics, focusing on reaction rates, rate laws, and factors affecting reaction rates. Understand how reactant concentration, temperature, surface area, and catalysts influence reaction rates. Learn about rate constants and reaction orders.

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