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Chemical Bonding and Molecular Structure
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Chemical Bonding and Molecular Structure

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@ImmaculateSchrodinger

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Questions and Answers

Ionic bonds are formed between two atoms that share one or more pairs of electrons.

False

Covalent bonds are typically polar.

True

Hydrogen bonds are a type of intermolecular force.

True

VSEPR theory predicts the shape of molecules based on the arrangement of electron pairs around the central atom.

<p>True</p> Signup and view all the answers

Bond length is the energy required to break a bond.

<p>False</p> Signup and view all the answers

Pi bonds occur when orbitals overlap end-to-end.

<p>False</p> Signup and view all the answers

Study Notes

Types of Chemical Bonds

  • Ionic Bond: formed between two atoms that have a large difference in electronegativity, resulting in the transfer of electrons
    • One atom loses an electron (becomes a cation) and the other atom gains an electron (becomes an anion)
    • Electrostatic attraction between oppositely charged ions holds them together
  • Covalent Bond: formed between two atoms that share one or more pairs of electrons
    • Atoms share electrons to achieve a full outer energy level
    • Can be polar or nonpolar depending on the difference in electronegativity between atoms
  • Hydrogen Bond: a type of intermolecular force that arises between molecules with a hydrogen atom bonded to a highly electronegative atom (e.g. oxygen, nitrogen, or fluorine)
    • Weak electrostatic attraction between the hydrogen atom and another electronegative atom

Bonding Theories

  • Electrostatic Theory: explains the formation of ionic bonds based on the electrostatic attraction between oppositely charged ions
  • Valence Shell Electron Pair Repulsion (VSEPR) Theory: predicts the shape of molecules based on the arrangement of electron pairs around the central atom
  • Molecular Orbital (MO) Theory: explains the formation of covalent bonds in terms of the overlap of atomic orbitals to form molecular orbitals

Bond Characteristics

  • Bond Length: the average distance between the nuclei of two bonded atoms
  • Bond Angle: the angle between two bonded atoms and the central atom
  • Bond Strength: the energy required to break a bond
  • Polarity: the distribution of electrons within a bond, resulting in a partial positive and partial negative charge

Bonding in Molecules

  • Sigma (σ) Bond: a type of covalent bond that occurs when orbitals overlap end-to-end
  • Pi (Ï€) Bond: a type of covalent bond that occurs when orbitals overlap side-by-side
  • Multiple Bonds: bonds that involve more than one pair of electrons between two atoms, resulting in a stronger bond

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Description

Learn about the different types of chemical bonds, bonding theories, and characteristics of bonds in molecules. Understand the formation of ionic, covalent, and hydrogen bonds, and how they affect molecular structure.

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