Chemical and Nuclear Reactions

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Questions and Answers

What is the correct mass number for Uranium-238?

  • 234
  • 238 (correct)
  • 146
  • 92

Which particle is represented by the symbol 0 e-1?

  • beta particle (correct)
  • neutron
  • gamma ray
  • alpha particle

In the reaction 7N14 + 2He4 --> 8O17 + P4XA4, what is the total number of nucleons on the reactants' side?

  • 16
  • 20
  • 18 (correct)
  • 22

Which statement about isotopes is true?

<p>Isotopes have different mass numbers but the same number of protons. (A)</p> Signup and view all the answers

What does the notation A = P + N represent regarding isotopes?

<p>The mass number equals protons plus neutrons. (B)</p> Signup and view all the answers

What characterizes an endothermic reaction?

<p>It absorbs heat from the surroundings. (D)</p> Signup and view all the answers

Which of the following statements about isotopic abundance is correct?

<p>Isotopic abundance is expressed as a fraction in nature for stable isotopes. (D)</p> Signup and view all the answers

In the decay of uranium-238, what is emitted in an alpha decay process?

<p>alpha particle (A)</p> Signup and view all the answers

What uniquely identifies an element within the atomic nucleus?

<p>The number of protons (B)</p> Signup and view all the answers

Which of the following isotopes represents a mass number of 14?

<p>Carbon-14 (A)</p> Signup and view all the answers

Which statement best defines a nuclear isomer?

<p>A metastable state of an atomic nucleus (A)</p> Signup and view all the answers

What is the half-life range that typically characterizes a metastable state?

<p>10−9 seconds or longer (D)</p> Signup and view all the answers

What does a radioactive isotope eventually decay into?

<p>A stable nonradioactive isotope (D)</p> Signup and view all the answers

What defines a stable isotope?

<p>It does not spontaneously undergo radioactive decay (C)</p> Signup and view all the answers

What type of reaction absorbs energy and results in an increase of mass in the products?

<p>Endothermic reaction (B)</p> Signup and view all the answers

Which of the following depicts a process that releases energy?

<p>Exothermic reaction (B)</p> Signup and view all the answers

What must be satisfied to balance a nuclear reaction involving four different nuclear symbols K, L, M, and N?

<p>P1 + P2 = P3 + P4 and A1 + A2 = A3 + A4 (C)</p> Signup and view all the answers

In the reaction 13Al27 + 2He4 ---> 14Si30 + H1, what is the change in mass (∆m)?

<p>-0.0002 amu (C)</p> Signup and view all the answers

Which element is produced in the reaction 13Al27 + 2He4?

<p>Si30 (C)</p> Signup and view all the answers

What type of reaction is exemplified by the equation 226Ra → 4He + 222Rn?

<p>Radioactive decay (A)</p> Signup and view all the answers

What characterizes a nuclear fission reaction?

<p>Splitting a heavy nucleus into smaller nuclei. (B)</p> Signup and view all the answers

In a nuclear fusion reaction, which of the following occurs?

<p>Nuclei combine to form a heavier nucleus. (D)</p> Signup and view all the answers

What is the significance of a negative change in mass (∆m) in a nuclear reaction?

<p>It indicates an exothermic reaction. (C)</p> Signup and view all the answers

When balancing the nuclear reaction 13Al27 + 2He4 ---> 14Si30 + H1, what does P4 equal based on proton balance?

<p>1 (D)</p> Signup and view all the answers

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Study Notes

Chemical Reactions

  • Synthesis Reaction: Combines elements to form compounds (e.g., C + O2 → CO2).
  • Decomposition Reaction: Breaks down compounds into simpler substances (e.g., 2H2O → 2H2 + O2).
  • Simple Replacement Reaction: One element replaces another in a compound (e.g., Fe + CuSO4 → FeSO4 + Cu).
  • Double Replacement Reaction: Components of two compounds exchange places (e.g., 2KOH + H2SO4 → K2SO4 + 2H2O).

Nuclear Reactions

  • Nuclear Fission: Splitting of a heavy nucleus into smaller nuclei, releasing energy (e.g., 235U + n1 → 36Kr + 56Ba + 3(0n1) + MeV).
  • Nuclear Fusion: Combining light nuclei to form a heavier nucleus, also releasing energy (e.g., H2 + H2 → H3 + H1 + MeV).
  • Radioactive Decay: Process by which an unstable nucleus loses energy by emitting radiation (e.g., 226Ra → 4He + 222Rn).

Balancing Nuclear Reactions

  • General form for nuclear reactions: KA1 + LA2 → MA3 + NA4, where
    • P = number of protons
    • A = mass number.
  • Balancing equations requires:
    • P1 + P2 = P3 + P4
    • A1 + A2 = A3 + A4.

Sample Problem in Nuclear Reactions

  • Example: Reaction of 13Al27 + 2He4 → 14Si30 + H1.
  • Balancing yields:
    • Proton count: P4 = 13 + 2 - 14 = 1.
    • Mass number: A4 = 27 + 4 - 30 = 1.

Change in Mass Calculation

  • Reaction: 13Al27 + 2He4 → 14Si30 + H1.
  • Calculate total masses:
    • Reactants: Al27 (26.9815 amu) + He4 (4.0003 amu) = 30.9818 amu.
    • Products: Si30 (29.9738 amu) + H1 (1.0078 amu) = 30.9816 amu.
  • Change in mass (Δm) = Total MassProducts – Total MassReactants = 30.9816 - 30.9818 = -0.0002 amu, indicating an exothermic reaction.

Nuclear Periodic Table

  • Atomic identity is based on the number of protons (atomic number).
  • Mass number (nucleons) varies among isotopes; carbon has isotopes carbon-12, carbon-13, and carbon-14.
  • Nuclear isomers have metastable states with long half-lives, differing from non-metastable states.

Radioactive Isotopes

  • Radioactive isotopes (radioisotopes) have unstable nuclei that undergo decay to reach stability.
  • Example: Radium-226 decays to Lead-206.
  • Application of radioisotopes includes medical therapy and diagnostics.

Types of Reactions

  • Endothermic Reaction: Absorbs energy; mass increases in products.
  • Exothermic Reaction: Releases energy; mass decreases in products.

Isotopic Composition and Abundance

  • Elements can exist as multiple isotopes due to varying nucleon combinations.
  • Isotopic abundance represents the fraction of an isotope compared to its natural counterpart, often denoted as f.
  • Example: Sodium has only one isotope (23Na), thus its isotopic abundance is f = 1.000.
  • Hydrogen has three isotopes:
    • 1H (no neutrons),
    • 2H (one neutron, known as Deuterium),
    • 3H (two neutrons, radioactive).

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