Chem1911 Sample Quiz 1

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Questions and Answers

What decay product results from the emission of an alpha particle from $^{210}_{85}At$?

  • $^{210}_{86}Rn$
  • $^{207}_{82}Pb$
  • $^{206}_{81}Tl$
  • $^{206}_{85}At$
  • $^{206}_{83}Bi$ (correct)

What nuclide is needed to balance the following nuclear reaction?

$^{235}{92}U + ^1_0n \rightarrow ? + ^{94}{39}Y + 3 ^1_0n$

  • $^{139}_{53}I$
  • $^{138}_{53}I$
  • $^{135}_{53}I$
  • $^{137}_{53}I$ (correct)
  • $^{136}_{53}I$

Which one of the following strontium isotopes undergoes radioactive decay by β⁻ emission?

  • $^{88}_{38}Sr$
  • $^{90}_{38}Sr$ (correct)
  • $^{83}_{38}Sr$
  • $^{86}_{38}Sr$
  • $^{87}_{38}Sr$

For which one of the following atoms or ions would the 2s and 2p orbitals have the same energy?

<p>H (B)</p> Signup and view all the answers

Which electron excitation of the hydrogen atom requires light of the shortest wavelength?

<p>n = 2 to n = 3 (D)</p> Signup and view all the answers

How many nodes does a 5s atomic orbital have?

<p>0 planar nodes and 4 spherical nodes (C)</p> Signup and view all the answers

The $1s^1 3p^1 \rightarrow 1s^2$ transition of He is at 54 nm. Which statement is correct?

<p>The $1s^1 2p^1 \rightarrow 1s^2$ transition of He is at a longer wavelength than 54 nm. (C)</p> Signup and view all the answers

The half-life of $^{14}C$ is 5730 years. Which of the following materials can be usefully dated using $^{14}C$ dating methods?

<p>15th-century paintings (C)</p> Signup and view all the answers

Which one of the following sets of quantum numbers is valid?

<p>n=5, l=4, $m_l$=3, $m_s$=+$\frac{1}{2}$ (D)</p> Signup and view all the answers

When computed on a calculator, the algebraic expression $\frac{0.350 kg \times 141 J}{(0.921 m + 68 m)}$ has a value of 0.716037202. Expressed to the appropriate number of significant figures, what is the result?

<p>0.72 kg J m$^{-1}$ (A)</p> Signup and view all the answers

Which of the following statements about molecular orbitals for homonuclear diatomic molecules is incorrect?

<p>Sigma orbitals have a planar node normal to the internuclear axis between the atomic nuclei. (E)</p> Signup and view all the answers

What is the hybridization of the designated atoms in the following compound?

<p>P = sp$^2$, Q = sp$^2$, R = sp$^3$ (D)</p> Signup and view all the answers

Identify the correct Lewis structure of H$_2$O$_2$. Ensure that all charges and lone pairs are shown.

<p>H-$\ddot{O}$-$\ddot{O}$-H (D)</p> Signup and view all the answers

How many non-bonding electron pairs (lone pairs) are around the Cl atom in HCl?

<p>3 (D)</p> Signup and view all the answers

Identify the functional group labeled A in the molecule below.

<p>Amine (B)</p> Signup and view all the answers

What is the decay product resulting from electron capture by the $^{144}_{61}Pm$ nuclide?

<p>$^{144}_{60}Nd$ (D)</p> Signup and view all the answers

What nuclide is needed to balance the following nuclear reaction?

$^{233}{92}U + ^1_0n \rightarrow ? + ^{101}{42}Mo + 3 ^1_0n$

<p>$^{130}_{50}Sn$ (C)</p> Signup and view all the answers

Only one of the following gallium isotopes does not undergo radioactive decay via electron capture. Which one is it?

<p>$^{64}_{31}Ga$ (C)</p> Signup and view all the answers

Which of the following electron excitations of the hydrogen atom requires light of the longest wavelength?

<p>n = 2 to n = 3 (D)</p> Signup and view all the answers

The $1s^1 3p^1 \rightarrow 1s^2$ transition of He is at 54 nm. Which of the following is correct?

<p>The $1s^1 2p^1 \rightarrow 1s^2$ transition of He is at a longer wavelength than 54 nm. (A)</p> Signup and view all the answers

The half-life of $^{14}C$ is 5730 years. Which of the following can be usefully dated using $^{14}C$ dating methods?

<p>15th-century paintings (C)</p> Signup and view all the answers

When computed on a calculator, the algebraic expression $\frac{3.69 kg \times 30. J}{(87.1 m + 98.5 m)}$ has a value of 0.596443966. Expressed to the appropriate number of significant figures, what is the result?

<p>0.60 kg J m$^{-1}$ (A)</p> Signup and view all the answers

Identify the correct Lewis structure of CN$^{-}$. Ensure that all charges and lone pairs are shown.

<p>:C$\equiv$N: (D)</p> Signup and view all the answers

How many non-bonding electron pairs (lone pairs) are around the B atom in BF$_3$?

<p>0 (B)</p> Signup and view all the answers

Consider the molecule below. What is the name of the functional group labelled B?

<p>Alcohol (B)</p> Signup and view all the answers

Let f(x) = (2x)$^x$. Calculate f'(x).

<p>(2x)$^x$(1+ln(2x)) (C)</p> Signup and view all the answers

Calculate the three-term Taylor polynomial about x = 0 for f(x) = $\frac{1}{1-2x}$.

<p>-1 -2x - 8x$^2$ (C)</p> Signup and view all the answers

Let z = 1-3i, w = 2 + i. Calculate wz.

<p>5+5i (A)</p> Signup and view all the answers

Let a, b ∈ R and let u = [1,2, 1], v = [b, a, 2] and w = [a, b, -4]. For what values of a and b do we have 6u - v + w = 0?

<p>There are no values of a and b which satisfy this. (B)</p> Signup and view all the answers

Let l represent the line in R$^2$ that passes through the point (1,1) and is perpendicular to the vector [3,2]. Which of the following is a parametric equation for l?

<p>l: [1, 1] + t[-2,3], t∈R (C)</p> Signup and view all the answers

Which of the following parametric equations represents the line l in R$^3$ that passes through the point (1,2,5) and is perpendicular to both of the vectors u = [1,1,1] and v = [2,0,0]?

<p>l: [1,2,5] + t[0,2, -2], t∈ R (A)</p> Signup and view all the answers

Flashcards

Alpha Decay Product of 210At

The decay product of 210At after emitting an alpha particle is Lead-206.

Nuclide to Balance Nuclear Reaction

The nuclide needed to balance the nuclear reaction is Iodine-137.

Radioactive Strontium Isotope

Strontium-90 undergoes radioactive decay by β- emission.

Atom with Equal 2s and 2p Energy

Hydrogen atom (H) has the same energy for 2s and 2p orbitals.

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Shortest Wavelength Excitation

The electron excitation from n = 5 to n = 100 requires the shortest wavelength.

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Nodes in 5s Orbital

A 5s atomic orbital has 0 planar nodes and 4 spherical nodes.

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He Transition Wavelength

The 1s¹2p¹ → 1s² transition of He is at a longer wavelength than 54 nm.

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14C Dating Application

15th century paintings can be usefully dated using 14C dating methods.

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Valid Quantum Numbers

The valid set of quantum numbers is n=5, l=4, ml=3, ms=+1/2.

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Value with Sig Figs

Expressed to the appropriate number of significant figures, the value is 0.72 kg J m-1.

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Incorrect Statement: Sigma Orbitals

Sigma orbitals have a planar node normal to the internuclear axis between the atomic nuclei is incorrect.

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Hybridisation of Atoms

The hybridisation is P = sp², Q = sp², R = sp³.

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Lewis Structure of H2O2

The correct Lewis structure of H₂O₂. Ensure that all charges and lone pairs are shown.

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What the non-bonding lectron pairs (lone pairs) are around the Cl atom in HCl?

There are 3 non-bonding electron pairs. (lone pairs)

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Functional group labelled A

The functional group labelled A in the molecule below is Amine.

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Electron Capture Product

The decay product resulting from electron capture by 144Pm is 144Nd.

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Balancing Nuclear Reaction

The nuclide needed to balance the nuclear reaction is 131Sn.

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Non-Electron Capture Isotope

Gallium-67 does not undergo radioactive decay via electron capture.

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Equal 2s and 2p Energy

H- has the same energy for the 2s and 2p orbitals.

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Longest Wavelength Excitation

The electron excitation from n = 2 to n = 3 requires the longest wavelength.

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Nodes in 2p Orbital

A 2p atomic orbital has 1 planar node and 0 spherical nodes.

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He Transition Statement

The 1s¹2p¹ → 1s² transition of He is at a longer wavelength than 54 nm..

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What is the halflife of 14C?

EARLY human ancestor remains (approximately 2 million years old)

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Number of Quantum

Two quantum numbers are valid, n=2, l=1, ml=0, ms=-1/2

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Reference Value

When computed on a calculator and expressed to the appropriate number of significant figures, the value is 0.59 kg J m−1

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Diatomic molecules incorrect?

Pi orbitals have a planar node normal to the internuclear axis between the atomic nuclei is incorrect.

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Hybridiation

What is the hybridisation of the designated atoms in the following compound? P = sp, Q = sp2, R = sp³

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What is the lewis structure of CN

Lewis Structure: :C≡N: is the lewis structure

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Non-bonding electron pairs

Non-bonding electron pairs (lone pairs) BF3: The answer is 0

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Functional group labelled B

Consider the molecule below. What is the name of the functional group labelled B?: alcohol

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Study Notes

Chem1911 Sample Quiz 1 (i)

  • The decay product resulting from the emission of an alpha particle from 210/85At is 206/83Bi.
  • To balance the nuclear reaction 235/92U + 1/0n → ? + 96/39Y + 3 1/0n, the needed nuclide is 137/53I.
  • 90/38Sr is the isotope of strontium that undergoes radioactive decay by β emission.
  • For hydrogen (H), the 2s and 2p orbitals have the same energy.
  • The electron excitation of the hydrogen atom that requires light of the shortest wavelength is n = 2 to n = 3.
  • A 5s atomic orbital has 0 planar nodes and 4 spherical nodes.
  • The 1s¹2p¹ → 1s² transition of He occurs at a longer wavelength than 54 nm, given that the 1s¹3p¹ → 1s² transition is at 54 nm.
  • With a half-life of 5730 years, 14C dating methods can be usefully applied to 15th-century paintings.
  • The valid set of quantum numbers is n=5, l=4, ml=3, ms=+1/2.
  • The algebraic expression (0.350 kg * 141 J) / (0.921 m + 68 m) = 0.72 kg J m-1 to the appropriate number of significant figures.
  • Sigma orbitals having a planar node normal to the internuclear axis between the atomic nuclei is an incorrect statement about molecular orbitals for homonuclear diatomic molecules.
  • In the compound represented, the hybridizations of the designated atoms are: P = sp², Q = sp², and R = sp³.
  • H-O-O-H is the correct Lewis structure of H2O2 with all charges and lone pairs shown.
  • There are 3 non-bonding electron pairs (lone pairs) around the Cl atom in HCl.
  • The functional group labelled A in the molecule is Amine.

Chem1911 Sample Quiz 1 (ii)

  • The decay product resulting from electron capture by the 144/61 Pm nuclide is 144/60Nd.
  • To balance the nuclear reaction 233/92 U + 1/0 n → ? + 99/42 Mo + 3 1/0 n, the needed nuclide is 132/50 Sn.
  • 65/31 Ga does not undergo radioactive decay via electron capture.
  • For N6+, the 2s and 2p orbitals have the same energy.
  • The electron excitation of the hydrogen atom that requires light of the longest wavelength is n = 5 to n = 100.
  • A 2p atomic orbital has 1 planar node and 0 spherical nodes.
  • The 1s¹2p¹ → 1s² transition of He occurs at a longer wavelength than 54 nm, given that the 1s¹3p¹ → 1s² transition is at 54 nm.
  • With a half-life of 5730 years, 14C dating methods can be usefully applied to 15th-century paintings.
  • The valid set of quantum numbers is n=2, l=1, ml=0, ms=-1/2.
  • The algebraic expression (3.69 kg * 30 J) / (87.1 m + 98.5 m) = 0.60 kg J m-1 to the appropriate number of significant figures.
  • Pi orbitals having a planar node normal to the internuclear axis between the atomic nuclei is an incorrect statement about molecular orbitals for homonuclear diatomic molecules.
  • In the compound represented, the hybridizations of the designated atoms are: P = sp, Q = sp², and R = sp³.
  • :C≡N: is the correct Lewis structure of CN- with all charges and lone pairs shown.
  • There are 0 non-bonding electron pairs (lone pairs) around the B atom in BF3.
  • The functional group labelled B in the molecule is Alcohol.

MATH1061: Mathematics 1A

  • R ⊂ Q is not true.
  • For f(x) = 1 – x² and g(x) = ln(x), the domain of g o f is [-1,1], and the range is (-∞,0].
  • For tanh(x) = (ex - e-x) / (ex + e-x), the limit as x→∞ of tanh(x) is 1.
  • If f(x) = x⁶ sin(x) + cosh(6x), then f'(x) = x⁶ cos(x) + 6x⁵ sin(x) + 6 sinh(6x).
  • If f(x) = (2x)x, then f'(x) = (2x)x(1+ln(2x)).
  • The three-term Taylor polynomial about x = 0 for f(x) = 1 / (1-2x) is -1 + 2x - 4x².
  • If z = 1 – 3i and w = 2 + i, then wz = 5 - 5i.
  • For lines u = [1,2,1], v = [b,a,2], and w = [a,b,-4], a = -9 and b = 3 where 6u - v + w = 0.
  • A parametric equation for the line in R² that passes through (1,1) and is perpendicular to [3,2] is l: [1, 1] + t[-2,3], t∈R.
  • A parametric equation for the line in R³ that passes through (1,2,5) and is perpendicular to both [1,1,1] and [2,0,0] is l: [1,2,5] + t[0,2, -2], t∈ R.
  • The line [x, y, z] = [1, 2, -2] + t[2, 1,2], t ∈ R intersects the plane x + 2y + 3z = 19 at (5,1,4).
  • sin(4θ) = cos⁴(θ) - 6 cos² (θ) sin²(θ) + sin⁴(θ).

PRACTICE EXAM A SEMESTER 1 2024

  • For f(x) = cosh(x) from R→ [1,∞), f is surjective but not injective.

  • The limit as x→1 of (2x - 2x-1)/(x² - 2x + 1) is 1.

  • For f(x) = 2x³ - 3x² - 12x + 4, the minimum value for f(x) is -16.

  • d/dx (x/cos(x)) = 1/cos(x) + (x tan(x))/cos(x)

  • Given g(x) = ke-x when x ≤ π and g(x) = sin(2x) when x > π, the value of k that makes this a continuous function is 1.

  • The first three nonzero terms in the Taylor series for ∫x0 e^(-s²) ds about x = 0 is x - x³/3 + x⁵/10.

  • The plot representing f(x), f'(x), and f"(x) is: f(x): Plot 3, f'(x): Plot 2, f"(x): Plot 1.

  • ∫ cos(x) / √(1 + 2sin(x)) dx = √(1+2sin(x)) + C.

  • The length of the curve y = cosh(x) from x = 0 to x = ln(2) is 3/4.

  • The volume generated by rotating the curve √x around the x-axis from 0 to 4 is 8π.

  • For the set S = {z ∈ C : Rez ≥ 0 and Im z ≤ 0}, then {iz : z ∈ S} would be represented by the 1st quadrant.

  • For v = [2, 6, -1] and w = [-3, α, 3/2], v and w are parallel if α = -9.

  • Given non-zero vectors u, v, w ∈ R² with u · v = 0, it is not necessarily true that proju(w) - projv(w) = 0.

  • The lines x = 3 + t, y = -5 + 2t, z = 5 - t and x = -3 - 2s, y = -2 - 4s, z = 1 + 2s do not intersect.

  • [2, -1, 5] is parallel to the plane 2x - y + 5z = 3.

  • Given matrix A is 3x3 and B is 3x2 and C is 2x3, A² + BC is a 3 × 3 matrix.

  • Given A = [1 1 0 \ 1 1 1 \ 0 1 1], A-1 = [0 1 -1 \ 1 -1 1 \ -1 1 0] is true.

  • If B is a square matrix with det(B) = 2 and det((-1/√2)B) = 1/2, B is a 4 x 4 matrix.

  • If A₁ = PD₁P⁻¹ and A₂ = PD₂P⁻¹, with D₁ = [1 0 \ 0 2], D₂ = [3 1 \ 0 1], and P = [1 1 \ 1 0], then (A₁A₂)⁵ = [2⁵ 3⁵-2⁵ \ 0 3⁵ ].

  • For a 3 × 3 matrix A with three distinct eigenvalues, A is invertible is not necessarily true.

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