CHEM 1220 Chapter 16-4: Understanding pH

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Questions and Answers

If a solution has a hydroxide ion concentration of $1 \times 10^{-3}$ M, what is the pH of the solution?

  • 11 (correct)
  • 13
  • 3
  • 1

A solution has a pH of 4. What is the hydrogen ion concentration, $[H^+]$, in moles per liter?

  • $1 \times 10^{-10}$
  • 10
  • 4
  • $1 \times 10^{-4}$ (correct)

Which of the following pH values indicates the strongest acid?

  • 6.9
  • 5
  • 7.1
  • 1 (correct)

For a solution at $25^{\circ}C$, if the hydrogen ion concentration, $[H^+]$, is $1.0 \times 10^{-5}$ M, what is the pOH of the solution?

<p>9 (B)</p> Signup and view all the answers

A solution is found to have a pH of 8.2. Which of the following statements is true regarding this solution?

<p>It is slightly basic. (D)</p> Signup and view all the answers

Which of the following statements best describes the relationship between pH and pOH in aqueous solutions at $25^{\circ}C$?

<p>pH + pOH = 14 (A)</p> Signup and view all the answers

If the $[H^+]$ concentration in a solution is increased by a factor of 100, what will be the change in pH?

<p>Decrease by 2 pH units (A)</p> Signup and view all the answers

Which of the following indicates a neutral solution at $25^{\circ}C$?

<p>$[H^+] = [OH^-]$ (B)</p> Signup and view all the answers

What is the pOH of a solution with a pH of 4.6 at $25^{\circ}C$?

<p>9.4 (C)</p> Signup and view all the answers

Which of the following solutions would have the highest concentration of hydroxide ions ($OH^−$)?

<p>Solution with pH = 9 (D)</p> Signup and view all the answers

What is the hydrogen ion concentration $[H^+]$ of a solution with a pOH of 2?

<p>$1 \times 10^{-12}$ M (C)</p> Signup and view all the answers

If a sample of lemon juice has $[H^+] = 3.8 \times 10^{-4}$ M, what is the pH?

<p>3.42 (B)</p> Signup and view all the answers

If a commonly available window-cleaning solution has $[OH^-] = 1.9 \times 10^{-6}$ M, what is the pH?

<p>8.28 (C)</p> Signup and view all the answers

A sample of freshly pressed apple juice has a pOH of 10.24. What is $[H^+]$?

<p>$1.74 \times 10^{-4}$ M (C)</p> Signup and view all the answers

Which of the following is true regarding indicators?

<p>An indicator is one color in its acid form and another color in its basic form. (A)</p> Signup and view all the answers

Flashcards

What is pH?

A method of reporting hydrogen ion concentration.

pH equation

pH = -log[H+], where [H+] is the hydrogen ion concentration.

What is neutral pH?

A solution with a pH of 7.00

What is acidic pH?

A solution with a pH below 7.00.

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What is basic pH?

A solution with a pH above 7.00.

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What is pOH?

The negative logarithm of the hydroxide ion concentration [OH-].

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What is pKw?

The negative logarithm of the ion product constant for water (Kw).

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pH + pOH = ?

The sum of pH and pOH is always 14 at 25°C.

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Acid-Base Indicators

Indicators change color depending on the pH of the solution.

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What do pH meters do?

Provide accurate pH measurements by detecting small changes in voltage.

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Study Notes

  • CHEM 1220 - Chapter 16: Acid-Base Equilibria 16-4

pH

  • pH is a method of reporting hydrogen ion concentration.
  • pH = -log[H+]
  • Neutral pH is 7.00
  • Acidic pH is below 7.00
  • Basic pH is above 7.00

pH Scale Examples

  • Stomach acid [H+] is 1x10^-1, with a pH of 1.0, and a pOH of 13.0.
  • Lemon juice [H+] is 1x10^-2, with a pH of 2.0, and a pOH of 12.0.
  • Cola and vinegar [H+] is 1x10^-3, with a pH of 3.0, and a pOH of 11.0.
  • Wine [H+] is 1x10^-4, with a pH of 4.0, and a pOH of 10.0.
  • Black coffee [H+] is 1x10^-5, with a pH of 5.0, and a pOH of 9.0.
  • Rain, Saliva, and Milk [H+] is 1x10^-6, with a pH of 6.0, and a pOH of 8.0.
  • Human blood [H+] is 1x10^-7, with a pH of 7.0, and a pOH of 7.0.
  • Seawater [H+] is 1x10^-8, with a pH of 8.0, and a pOH of 6.0.
  • Borax [H+] is 1x10^-9, with a pH of 9.0, and a pOH of 5.0.
  • Lime water [H+] is 1x10^-10, with a pH of 10.0, and a pOH of 4.0.
  • Household ammonia [H+] is 1x10^-11, with a pH of 11.0, and a pOH of 3.0.
  • Household bleach [H+] is 1x10^-12, with a pH of 12.0, and a pOH of 2.0.

Formulas

  • pH + pOH = 14
  • [H+][OH-] = 1x10^-14

Relationships among (H+), (OH-), and pH at 25 °C

  • For acidic solutions [H+] >1.0 x 10^-7, [OH-] <1.0 x 10^-7, with a pH <7.00
  • For neutral solutions [H+] =1.0 x 10^-7, [OH-] =1.0 x 10^-7, with a pH of 7.00
  • For basic solutions [H+] <1.0 x 10^-7, [OH-] >1.0 x 10^-7, with a pH >7.00

Calculating pH from [H+]

  • In a sample of lemon juice, [H+] = 3.8 x 10^-4M, the pH is 3.42
  • If a window-cleaning solution has [OH-] = 1.9 x 10^-6M, the pH is 8.28

pOH and Other "p" Scales,

  • The "p" in pH tells us to take the -log of a quantity, in this case, hydrogen ions.
  • Other "p" systems include pOH: -log[OH] , and pKw: - log Kw
  • [H3O+][OH-] = Kw = 1.0 x 10^14
  • -log[H3O+] + -log[OH-] = -log Kw = 14.00
  • This results in pH + pOH = pKw = 14.00

Calculating [H+] from pOH

  • A sample of freshly pressed apple juice has a pOH of 10.24, therefore the [H+] = 1.74 x 10^-4 M

Indicators

  • Indicators, including litmus paper, are used for less accurate measurements.
  • An indicator is one color in its acid form and another color in its basic form.
  • pH meters are used for accurate measurements of pH.
  • Electrodes indicate small changes in voltage to detect pH.
  • Most indicators have a useful range of about 2 pH units.
  • Common acid-base indicators include: methyl violet, thymol blue, methyl orange, methyl red, bromthymol blue, phenolphthalein, and alizarin yellow R.

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