Chapter 3: Propellant
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Questions and Answers

What is the primary focus of forensic ballistics?

  • Examining firearms usage in crimes and linking bullets to weapons (correct)
  • Analyzing the environmental effects of gunpowder
  • Studying the history of firearms development
  • Understanding the chemical properties of propellants
  • What historical advancement in ballistics did Henry Goddard contribute to?

  • The concept of ballistic fingerprinting based on manufacturing defects (correct)
  • The development of rifling in firearms
  • The introduction of nitrocellulose as a propellant
  • The use of magnification for ballistic evidence
  • How does cartridge case capacity affect combustion in internal ballistics?

  • A larger empty space results in slower combustion (correct)
  • A smaller volume leads to higher internal pressure
  • Case capacity has no effect on combustion rates
  • A larger volume allows for faster combustion
  • During the firing process, what happens immediately after the firing pin strikes the primer?

    <p>The primer ignites the propellant</p> Signup and view all the answers

    In what scenario is internal pressure at its highest during the firing process?

    <p>When the bullet is at rest in the barrel</p> Signup and view all the answers

    What was a significant limitation of black powder compared to modern nitro-based propellants?

    <p>It requires a larger amount for effective propulsion.</p> Signup and view all the answers

    Which component is NOT traditionally associated with black powder?

    <p>Nitrocellulose</p> Signup and view all the answers

    Which type of propellant is categorized as a double-based powder?

    <p>Cordite</p> Signup and view all the answers

    What was the main advancement introduced by Alfred Nobel in the field of propellants?

    <p>The combination of nitrocellulose with nitroglycerine.</p> Signup and view all the answers

    Which of the following is a purpose of additives in propellants?

    <p>To enhance flexibility and stability.</p> Signup and view all the answers

    Study Notes

    A Brief History of Propellants

    • Propellants combust quickly to produce gas, driving missiles down gun barrels.
    • Common modern propellants are nitrocellulose-based powders; black powder is favored by muzzle-loading firearm enthusiasts.

    Types of Propellants

    • Black Powder: The earliest gunpowder consisting of potassium nitrate, sulfur, and charcoal; largely replaced by advanced propellants.
    • Nitro Powders:
      • Single-based: Made by dissolving nitrocellulose in ether and alcohol.
      • Double-based: Formed by mixing nitrocellulose with nitroglycerine, with Cordite as a prominent example.

    Black Powder Origins

    • Early references date to Greek Fire (424 BC) and Chinese gunpowder (circa 1000 AD).
    • Roger Bacon documented gunpowder in 1250; Berthold Schwartz popularized it in early 1300s Europe.

    Nitro Powders Development

    • Smokeless Powder: Invented by Vieille in 1884, using nitrocellulose for a stable propulsion method.
    • Alfred Nobel enhanced smokeless powder by combining nitrocellulose with nitroglycerine, leading to double-based powders like Cordite for British military usage.

    Additives in Propellants

    • Additives improve performance and stability:
      • Plasticizers (e.g., Triacetin) enhance flexibility.
      • Stabilizers (e.g., Diphenylamine) prevent degradation.
      • Gelatinizers (e.g., Dinitrotoluene) slow burning rates.
      • Surface moderators (e.g., Graphite) control reaction speed.

    Priming Compounds

    • Priming compounds ignite propellant when struck, originally using unstable mercury fulminate.
    • Current trends focus on lead-free, non-toxic primers to mitigate lead exposure.

    Advantages of Nitro-Based Propellants Over Black Powder

    • Require less material for the same effect.
    • Customizable for various firearms and ammunition.
    • Produce minimal residue and exhibit reduced corrosiveness.

    Primers

    • Evolution from hazardous materials to safer, lead-free alternatives is underway, aiming for non-toxic primers in shooting environments.

    Glossary

    • Black Powder: A mixture of potassium nitrate, sulfur, and charcoal.
    • Gun Cotton: Nitrocellulose; essential in modern propellants.
    • Lesmok: An old blend of black powder and gun cotton.
    • Nitrocellulose: Nitrated cellulose, integral to contemporary propellant formulations.

    Introduction to Forensic Ballistics and Internal Ballistics

    • Ballistics examines projectiles, focusing on their behavior throughout launch, flight, and impact.
    • Forensic Ballistics: Analyzes firearm-related crimes, relates bullets to weapons, and scrutinizes firearms and tool marks.

    Objectives of Forensic Ballistics

    • Grasp projectile behavior within firearms.
    • Identify factors influencing projectile momentum during discharge.

    History of Forensic Ballistics

    • 1493-1508: Emperor Maximilian proposed rifling for accuracy; its forensic application developed later.
    • 1835: Henry Goddard introduced ballistic fingerprinting.
    • 1860: Regina v Richardson case established wadding as evidence.
    • 1902: Oliver Wendell Holmes utilized magnification in firearms identification.
    • 1912: Professor Balthazard employed photography for bullet marking comparisons.
    • 1925: Calvin Goddard co-founded the Bureau of Forensic Ballistics in New York.

    Internal Ballistics

    • Studies internal gun processes from primer ignition to bullet exit.
    • Firing Process: Primer ignition causes gas production that propels the bullet out.
    • Cartridge Case Capacity: Empty space in cartridges affects propellant burn rates; larger space slows combustion.
    • Internal Pressure: Peaks when the bullet is stationary, dropping as gas volume increases during movement.

    Recoil and Velocity Calculations

    • Recoil: The backward motion experienced during firing; example of a .45 caliber pistol at 14,000 lb per sq.in.
    • Time in Barrel: Bullet travel time is brief, often as low as 0.001 seconds for pistols.
    • Velocity Calculations: Velocity can be computed based on various internal ballistics parameters.

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    Description

    Explore the fascinating history and types of propellants used in firearms, including the transition from black powder to modern nitrocellulose-based powders. Learn how these substances create the gas needed to propel missiles through gun barrels. Ideal for enthusiasts and students of ballistics.

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