Calorimetry Quiz - Bomb Calorimeters
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Questions and Answers

What is the primary purpose of a bomb calorimeter?

  • To measure the energy of large-scale reactions (correct)
  • To convert chemical energy into electrical energy
  • To measure pressure changes in reactions
  • To measure the temperature changes of gases
  • Heat loss is significant in a bomb calorimeter.

    False (B)

    What constant is used in the formulas to calculate enthalpy change in a bomb calorimeter?

    C

    The enthalpy change ($ ext{ΔH}$) can be calculated using the formula $\text{ΔH} = -C \Delta ______$.

    <p>T</p> Signup and view all the answers

    Match the components of a bomb calorimeter with their functions:

    <p>Reaction Chamber = Houses the sample during combustion Thermometer = Monitors temperature change O₂ Inlet = Provides oxygen for the reaction Motorized Stirrer = Ensures uniform temperature in water bath</p> Signup and view all the answers

    Which of the following is NOT a requirement for calorimetry?

    <p>Color of the substance (D)</p> Signup and view all the answers

    The specific heat capacity is the amount of heat required to change the temperature of a substance by one degree Celsius.

    <p>True (A)</p> Signup and view all the answers

    What does ΔH represent in a chemical reaction?

    <p>Enthalpy change</p> Signup and view all the answers

    In calorimetry, the formula to calculate the heat absorbed or released is Q = mass × specific heat capacity × Δ______.

    <p>T</p> Signup and view all the answers

    What is the main purpose of a calorimeter?

    <p>To measure the heat changes associated with chemical reactions (D)</p> Signup and view all the answers

    A flame calorimeter is used to measure the heat changes during combustion reactions.

    <p>True (A)</p> Signup and view all the answers

    Match the following terms with their definitions:

    <p>Specific heat capacity = The amount of heat needed to change the temperature of a substance by 1°C ΔH = Enthalpy change of a reaction Calorimetry = The measurement of heat changes in physical and chemical processes Kinetic energy = Energy of motion that can lead to temperature change</p> Signup and view all the answers

    What component in a simple calorimeter helps to minimize heat loss?

    <p>Lid</p> Signup and view all the answers

    A bomb calorimeter consists of a cylindrical metal vessel that contains the sample being tested and is surrounded by _______ to absorb heat.

    <p>water</p> Signup and view all the answers

    Match the following types of calorimeters with their main features:

    <p>Simple Calorimeter = Uses a styrofoam cup and a lid Flame Calorimeter = Uses a burner and a copper calorimeter Bomb Calorimeter = Includes ignition wires and a steel container All Calorimeters = Measure heat changes in reactions</p> Signup and view all the answers

    What does the enthalpy change of a reaction (${ΔH}$) represent?

    <p>The heat released or absorbed by the system (D)</p> Signup and view all the answers

    In simple calorimetry, it is assumed that Styrofoam is a perfect insulator.

    <p>True (A)</p> Signup and view all the answers

    What is the relationship between the heat absorbed or released (Q) and the enthalpy change ($ΔH$) in an exothermic reaction?

    <p>ΔH = -Q</p> Signup and view all the answers

    In calorimetry, 1.0 mL of water is equivalent to _____ grams.

    <p>1.0</p> Signup and view all the answers

    Match the calorimetry variables with their definitions:

    <p>Q = Heat absorbed or released by the system c = Specific heat capacity of water m = Mass of water ΔT = Change in temperature of the water</p> Signup and view all the answers

    What is the primary purpose of a calorimeter in cooking?

    <p>To compare quantities of different fuels (B)</p> Signup and view all the answers

    A calorimeter is 100% efficient in measuring heat energy.

    <p>False (B)</p> Signup and view all the answers

    What does ΔH represent in calorimetry?

    <p>Enthalpy change</p> Signup and view all the answers

    The formula for calculating enthalpy change is ΔH = - (Q_{pot} + Q_{____}).

    <p>water</p> Signup and view all the answers

    What does the Zeroth Law of Thermodynamics state?

    <p>Heat lost equals heat gained. (C)</p> Signup and view all the answers

    The First Law of Thermodynamics states that energy can be created as long as it is transferred to another form.

    <p>False (B)</p> Signup and view all the answers

    In calorimetry, a _____ system is used, meaning matter and energy cannot leave or enter.

    <p>closed</p> Signup and view all the answers

    Match the laws of thermodynamics to their definitions:

    <p>Zeroth Law = Heat flows from hot to cold. First Law = Energy cannot be created or destroyed. Calorimetry = Process of measuring energy change indirectly. Thermochemistry = Study of energy change in chemical reactions.</p> Signup and view all the answers

    What does the efficiency formula use as input?

    <p>Theoretical value of the reaction (C)</p> Signup and view all the answers

    Efficiency is calculated by dividing output by input and multiplying by 100%.

    <p>True (A)</p> Signup and view all the answers

    What is the symbol for efficiency in the efficiency formula?

    <p>Eff</p> Signup and view all the answers

    The variable Q represents the output, which can be calculated using the ________ of the material being heated.

    <p>change in temperature</p> Signup and view all the answers

    Match the variable with its description in the efficiency formulas:

    <p>Eff = Efficiency Q = Output from heating $ ext{ΔH}$ = Input of reaction $m$ = Mass of the material</p> Signup and view all the answers

    Flashcards

    Zeroth Law of Thermodynamics

    Heat always moves from a hotter object to a colder object.

    First Law of Thermodynamics

    Energy cannot be created or destroyed, it can only change forms.

    Thermochemistry

    The study of energy changes in chemical reactions.

    Calorimeter

    A device used to measure the heat changes in a chemical reaction.

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    Calorimetry

    The process of measuring heat changes using a calorimeter.

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    Calorimetry Assumption 1

    In calorimetry experiments, we assume no heat escapes the system because the styrofoam container is considered a perfect insulator.

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    Calorimetry Assumption 2

    We disregard the energy absorbed or released by the calorimeter itself.

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    Calorimetry Assumption 3

    We only consider the heat absorbed or released by water, ignoring any other components present.

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    Calorimetry Assumption 4

    We assume that 1 milliliter of water has a mass of 1 gram.

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    What is the relationship between enthalpy change and heat change?

    The heat change of a reaction is represented by the enthalpy change ('Delta H') and is equal to the heat absorbed or released by the system ('Q').

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    Specific heat capacity

    The amount of energy needed to raise the temperature of 1 gram of a substance by 1 degree Celsius.

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    Temperature change (ΔT)

    The change in temperature of a substance or system during a reaction, measured in degrees Celsius or Fahrenheit.

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    Enthalpy (ΔH)

    The total amount of energy contained within a system, including its potential and kinetic energy.

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    Heat energy (ΔQ)

    The amount of heat energy transferred between a system and its surroundings, measured in Joules (J).

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    Simple calorimeter: What is it?

    A simple calorimeter measures the heat changes in a chemical reaction using a styrofoam cup, thermometer, stirrer, and lid to minimize heat loss. The cup is often surrounded by an insulating outer container filled with water.

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    Flame calorimeter: What is it?

    A flame calorimeter uses a burner to heat a copper calorimeter containing water. The temperature change of the water measures the heat produced by the flame.

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    Bomb calorimeter: What is it?

    A bomb calorimeter is used to measure the heat of combustion of a sample. The sample is ignited inside a steel container (the bomb) surrounded by water. The temperature change in the water is measured.

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    Why is a styrofoam cup used in a simple calorimeter?

    The styrofoam cup in a simple calorimeter is useful because it is a good insulator and minimizes heat loss to the surroundings. This allows for a more accurate measurement of the heat change in the reaction.

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    Why is water used in a bomb calorimeter?

    The water surrounding the bomb in a bomb calorimeter absorbs the heat released by the combustion of the sample. The temperature change of the water is directly proportional to the heat released by the reaction.

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    Bomb Calorimeter

    A sealed, insulated container used to measure the energy released or absorbed in a chemical reaction, especially those involving explosions or implosions.

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    Ignition Wire

    A fine wire submerged in the reaction chamber of a bomb calorimeter that ignites the sample for the reaction.

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    Bomb Calorimeter Constant (C)

    The specific heat capacity of the bomb calorimeter, representing the amount of energy needed to raise its temperature by 1 degree Celsius.

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    Enthalpy Change (ΔH)

    The change in enthalpy of a reaction measured using a bomb calorimeter, symbolized as ΔH. This value is negative for exothermic reactions and positive for endothermic reactions.

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    Molar Enthalpy Change (nHm)

    The enthalpy change per mole of reactant in a reaction, symbolized as nHm, calculated using the bomb calorimeter constant and temperature change.

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    Enthalpy change

    The amount of heat energy absorbed or released during a chemical reaction.

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    Heat absorbed by the pot ($Q_{pot}$)

    The heat energy absorbed by the pot, calculated using the mass of the pot, its specific heat capacity, and the change in its temperature.

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    Heat absorbed by the water ($Q_{water}$)

    The heat energy absorbed by the water, calculated using the mass of the water, its specific heat capacity, and the change in its temperature.

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    Efficiency

    A measure of how much energy is transferred from the input to the output in a process.

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    Input (Energy)

    The energy released in a chemical reaction, usually calculated using the enthalpy of combustion.

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    Output (Energy)

    The energy gained by the material being heated, calculated using the change in temperature of the material.

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    Specific Heat Capacity (c)

    The amount of energy required to raise the temperature of 1 gram of a substance by 1 degree Celsius.

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    Molar Enthalpy (Hm)

    The amount of heat released by a chemical reaction, typically expressed in joules per mole.

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